环烷基咪唑啉衍生物多功能水处理剂的研究
收稿日期: 2004-07-22
修回日期: 2004-07-22
网络出版日期: 2010-10-01
Study on naphthenic imidazoline derivative as multifunction water treatment agent
Received date: 2004-07-22
Revised date: 2004-07-22
Online published: 2010-10-01
针对环烷基咪唑啉衍生物,分别探讨了其在盐酸酸性介质及油田污水中的缓蚀性能,并对其杀菌性能进行了评价。结果表明:(1)在质量分数约为10%的盐酸溶液中,能够获得比LAN-826缓蚀剂更好的缓蚀效果,在60℃、5h,投加质量分数仅为0.2%时,即可将碳钢挂片腐蚀率控制在1.5g/(m2·h)以下,缓蚀率可达94%以上;常温下,投加质量分数仅为0.1%~0.2%时,其对铝挂片缓蚀率可高达99%以上,且对铜挂片具有一定的缓蚀效果,可任意比例溶于水或盐酸中,热稳定性好;(2)在碳钢腐蚀速率为1.411mm/a的某油田污水中,投加质量浓度0.03mg/L时,其缓蚀率可达95%以上,且可将油田污水腐蚀速率控制在石油天然气行业标准规定的0.076mm/a以下;(3)在油田污水中,还具有一定的杀菌效果,与膦系阻垢剂及季铵盐类杀菌剂相容性好。因此,所开发的咪唑啉衍生物,既是优异高效的盐酸酸洗缓蚀剂,又是油田污水中一种良好的水处理剂。
石顺存, 易平贵, 周秀林, 郭万鸿, 陈金文 . 环烷基咪唑啉衍生物多功能水处理剂的研究[J]. 工业水处理, 2005 , 25(1) : 29 -32 . DOI: 10.11894/1005-829x.2005.25(1).29
The corrosion inhibition effects of naphthenic imidazoline derivative on HCl - H2O media and oilfield sewage and the sterilization performance are separately studied. It is indicated that:(1)It has better corrosion inhibition effect than LAN - 826 inhibitor in about 10% (mass fraction) HCl - H2O media. When the mass fraction on corrosion inhibitor is 0.2%, the corrosion inhibition rate on mild steel is above 94% and the corrosion rate is less than 1.5 g/(m2·h) at 60 ℃, 5 h. When the mass fraction is 0.1% ~ 0.2%, the corrosion inhibition rate on aluminum coupon test is above 99% and its corrosion inhibition effect on copper coupon test is also evident at normal temperature. It is soluble in water or HCl - H2O media and has good thermal stability;(2)When the mass concentration of corrosion inhibitor is 0.03 mg/L in oilfield wastewater the corrosion rate on mild steel is 1.411 mm/a, the corrosion inhibition rate is up to 95% and the corrosion rate of oilfield wastewater could be controlled at less than 0.076 mm/a which is regulated in petroleum and natural gas industry standard;(3)It also has evident sterilization effect on oilfield wastewater and is compatible with phosphine scaling inhibitor and quaternary-ammonium-salt biocide. Therefore, the naphthenic imidazoline derivative is both pickling inhibitor which has excellent inhibition efficiency for hydrochloric acid and a good kind of water treatment agent for oilfield wastewater.
[1] 石顺存,张红.高纯环烷酸的制备[J].湘潭矿业学院学报,2001,16(3):47-50
[2] 孟祥胜,牛春革.NS-3油溶性缓蚀剂的合成研究[J].精细石油化工,1999,(5):17-20
[3] 石顺存,等.咪唑啉季胺盐互变异构体稳定性研究[J].石油学报(石油加工),2003,19(6):52-57
[4] 吴宇峰,等.咪唑啉季胺盐水溶性缓蚀剂NH-1的合成及其性能研究[J].精细石油化工,2001,(5):39-42
[5] 石顺存.新型杀菌剂的制备方法及其性能测试[J].湖南化工1999,29(3):27-28
[6] Martin J A, Valone F W. Spectroscopic techniques for quality assurance of oil field corrosion inhibitors [J]. Corrosion, 1985, 41 (5):465 - 473
[7] Edwards A, et al. Mechanistic studies of the corrosion inhibitor oleic imidazoline[J]. Corros. Sci., 1994,36(2):315-325
[8] 陆柱,等.油田污水回注缓蚀剂的研制及机理[J].石油学报,1995,16(4):161-165
[9] Ramachandran S, Jovancicevic V. Molecular modeling of the inhibition of mild steel carbon dioxide corrosion by imidazolines [J].Corrosion, 1999,55 (3): 259 - 267
[10] 王大喜,王明俊.取代基咪唑啉分子结构与缓蚀性能的理论研究[J].石油学报(石油加工),2000,16(6):74-77
[11] 杨怀玉,等.H2S水溶液中的腐蚀与缓蚀作用机理的研究Ⅷ.咪唑啉衍生物在H2S溶液中的吸附作用行为[J].中国腐蚀与防护学报,2003,23(2):75-78
[12] 郑家燊,吕战鹏,彭芳明.新型咪唑啉类缓蚀剂的合成、结构表征及缓蚀性能研究[J].油田化学,1994,11(2):163-167
[13] 石顺存.酸性黑油咪唑啉的合成[J].精细石油化工,1998,(4):34-36
[14] 黎新,等.脂肪族氨基酸对铝缓蚀机理的研究[J].材料保护,2000,33(5):3-4
[15] 胡耿源,周黎芳.咪唑啉表面活性剂水解机理研究[J].日用化学工业,1989,(3):1-4
[16] 郭祥峰,贾丽华.阳离子表面活性剂及应用[M].北京:化学工业出版社,2002.146-147
/
〈 | 〉 |