试验研究

有机絮凝剂聚环氧氯丙烷胺的脱色性能研究

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  • 山东大学环境科学与工程学院, 山东济南 250100
高宝玉(1961- ),1999 年毕业于清华大学环境科学与工程系,博士,山东大学教授,博士生导师。电话:0531 -88364832,E-mail:bygao@sdu.edu.cn

收稿日期: 2005-01-10

  网络出版日期: 2010-10-01

基金资助

山东省科技攻关项目,项目号030306

Study of the decolorization property of polyamine flocculants

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  • School of Environmental Science and Engineering,Shandong University, Jinan 250100, China

Received date: 2005-01-10

  Online published: 2010-10-01

摘要

以环氧氯丙烷和二甲胺为原料,加入交联剂合成了一系列有机絮凝剂。研究了这一系列絮凝剂对活性染料废水和分散染料废水的脱色效果。考察了交联剂种类、絮凝剂黏度、阳离子度及交联剂的加入量等因素对脱色效果的影响,探讨了其脱色机理。实验结果表明,交联剂的加入改变了聚合物的结构使其更容易脱色。一般来说,聚合物黏度越高,阳离子度越大,脱色效果越好。对于活性染料废水,分子质量和阳离子度都是关键因素;对于分散染料废水,最主要的影响因素是分子质量。

本文引用格式

高宝玉, 张华, 岳钦艳, 王曙光 . 有机絮凝剂聚环氧氯丙烷胺的脱色性能研究[J]. 工业水处理, 2005 , 25(10) : 39 -41 . DOI: 10.11894/1005-829x.2005.25(10).39

Abstract

Polyamine flocculants are synthesized by polycondensation of dimethylamine and epichlorohydrin with cross linking agents. The decolorization efficiencies of polyamine flocculants have been studied on the treatment of simulative water containing activated dye and disperse dye respectively. The influences of kinds of cross linking agents,viscosity,cationicity and the amount of cross linking agents on the decolorization efficiency have been investigated and the decolorization mechanism are discussed. The results show that polyamine flocculants have excellent decolorization efficiency. Introducing cross linking agents to the flocculants can enhance the decolorization efficiency of the flocculants. Generally, the greater the viscosity and cationicity, the better the decolorization efficiency.

参考文献

[1]黎载波,王国庆,邹龙生. 有机高分子絮凝剂在印染废水处理中的 应用[J]. 工业水处理,2003,23(4):14 - 17
[2]高宝玉,滕素玲.氯化镁用于染料废水的脱色研究[J]. 山东大学学报,1993,28(3):328 - 335
[3]舒型武,郑怀礼.阳离子有机絮凝剂研究进展[J]. 现代化工,2001,21(10):13 - 16
[4]Choi Jeong-Hak,Shin Won-Sik,Lee Seok-Hun,et al. Application of synthetic polyamine flocculants for dye wastewater treatment[J]. Separation Science and Technology,2001,36(13):2 945 - 2 968
[5]Mark H F,Gaylord N G,Bikaales NM. Encyclopedia of Polymer Science and Engineering[M]. 2nd. John Wiley and Sons,New York,1989,11. 489 - 498

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