专论与综述

多功能水处理剂高铁酸钾的制备与应用

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  • 哈尔滨工业大学环境科学与工程系, 黑龙江 哈尔滨 150001
姜洪泉(1970- ),现为哈尔滨工业大学环境科学与工程系硕士研究生

收稿日期: 2000-10-07

  网络出版日期: 2010-10-01

Preparation of potassium ferrate and its applications in water treatment

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  • Department of Environmental Science and Engineering, Harbin Institute of Technology, Harbin 150001, China

Received date: 2000-10-07

  Online published: 2010-10-01

摘要

高铁酸钾是一种集氧化、吸附、絮凝、助凝、杀菌、除臭为一体的新型高效多功能水处理剂。作者综述了国内外有关高铁酸钾的制备方法、性质及应用领域的研究进展, 讨论了高铁酸钾在制备与纯化工艺以及在实现大规模工业化生产方面所面临的若干技术问题。指出, 随着人们对高铁酸钾独特的水处理功能认识的不断深化及其应用领域的逐步拓宽, 研究其高效、低耗、减污的清洁生产工艺具有十分广阔的开发前景。文中引用了近年相关文献26篇

本文引用格式

姜洪泉, 金世洲, 王鹏 . 多功能水处理剂高铁酸钾的制备与应用[J]. 工业水处理, 2001 , 21(2) : 4 -6 . DOI: 10.11894/1005-829X.2001.21(2).4

Abstract

Potassium ferrate is a efficient multipurpose water treatment agent with the novel properties of oxidation, adsorption, flocculation, coagulation, disinfection, and deodorization.In this paper, a review of the preparation methods and characteristics of potassium ferrate, and its applicat ions in water treatment is presented, the technique conditions for the preparation and purification process, and the difficult position of industrial production are discussed.Also, the suggestions and prospects are proposed for study on the practical and cleaner production of the chemicals.26 references are cited

参考文献

[1] William S M, James R C, Michael D J.Removal of Radionuclides in Waste waters Utilizing Potassium Ferrate(Ⅵ)[J].Water Environment Research, 1995, 67(6):1007-1008.
[2] 秦玉楠.新型高效水处理剂---高铁酸钾生产工艺简介[J].工业水处理, 1994, 14(3):29-30.
[3] Luca D S J, Cantelli M, Luca D M A.Ferrate vs traditional coagulants in the treatment of combined industrial wastes[J].Wat.Sci.Tech., 1992,26(9-11):2077-2080.
[4] 覃长森, 刘玉莲.非氯型消毒剂高铁酸钾的合成[J].精细化工,1997, 14(5):1-3.
DeLuca S J, Idle C N, C hao A C.Quality Improvement of Biosolidsby Ferrate(Ⅵ)Oxidation of Offensive Odour Compounds[J].Wat.Sci.Tech., 1996, 33(3):119-130.
[5] 严瑞王宣, 胡宇, 纪永亮. 我国水处理剂的现状及发展战略[J].现代化工, 1999, 19(2):3-7.
[7] Stahl G E. Opusculum Chymico Physico Medicum[M].Halae-Magdeburgiae, 1715:742.
[6] 田宝珍, 曲久辉.化学氧化法制备高铁酸钾循环生产可能性的试验[J].环境化学, 1999, 18(2):173-177.
[7] Hrostow ski H J and Scott A B.The Magnetic Suscept ibility ofPotassium[J].J.Chem.Phys., 1950, 18:105-107.
[8] Thompson G W, Ockerm an L T, Schreyer J M. Preparation andPurification of Potassium Ferrate[J].J.Am.Chem.Soc., 1951,73:1379-1381.
[9] 王善杨, 吴黎平.新型高效水处理剂---高铁酸钾[J].河南化工, 1994, (2):22-23.
张军, 时清量, 杨国明.高铁酸钾的合成及其应用研究[J].无机盐工业, 1999, 31(6):26-28.
[10] Lionel D, pierrel.ANovelOxidizing Reagent Based on Potassium Ferrate(Ⅵ)[J].J.OrgChem., 1996, 61:63606370.
[11] Cici M and Cuci Y.Production of Some Coagulant Materials from Galvanizing Workshop Waste[J].Waste Management, 1997, 17(7):407410.
[12] Bouzek K, RousarI, Bergmann H, etal.The Cyclic Voltammetric Study of Ferrate(Ⅵ)Production[J].J.Elect roanal Chem., 199, 425:125-137.
[13] 雷鹏举, 曲久辉, 王佳音.多功能复合高铁水处理药剂的电解制备研究[J].环境科学学报, 1998, 18(4):380-384.
[14] HoppeML,etal.Structure of Dipotassium Ferrat(Ⅵ)[J].ActaCrystallogr, 1982, B38:2237-2239.
[15] Goff H, Murmann R K.Studies on the Mechanism of IsotopicOxygen Exchange and Reduction of Ferrate Ion (FeO42-)[J].J.Am.Chem.Soc., 1971, 93:6058-6065.
Wagner W F, Gump J R, Hart E N.Factors Affecting the Stability of Aqueous Potassium Ferrate(Ⅵ)Solutions [J].Anal.Chem.1952, 24:1497-1498.
[16] Lee D G, Gai H.Oxidation of Secondary Alcohols by Pot assiumTet raoxof errate(Ⅵ)[J].Can.J.Chem., 1993, 71:1394-1400.
Read J R, Boucher K D, Mehlman S A, etal.The Kinetics and Mechanism of the Oxidation of 1, 4-Thioxane [J].Inorganica Chim.Acta., 1998, 267:159-163.
[17] 曲久辉, 林谡, 田宝珍.高铁酸盐氧化絮凝去除水中腐殖质的研究[J].环境科学学报, 1999, 19(9):510-514.
Waite T D and Gibert M.Oxidative Destruction of Phenol and Other Organic Water Residuals by Iron(Ⅵ)Ferrate[J].Journal of Water Pollution Control Federation, 1978, 50(3):543551.
[18] Virender K S, etal.Ferrate(Ⅵ)Oxidation of Aqueous Cyanide[J].Environ Sci.Technol., 1998, 32:2608-2613.
[19] Virender KS,etal.Oxidation of Ammonia by Ferrate(Ⅵ)[J].J.Environ.Sci.Health, 1998, A33(4):635-650.
[20] 罗耀宗.水处理剂高铁酸钾[J].化学世界, 1992, (12):544

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