TiO2·SiO2/beads降解有机磷农药的研究
收稿日期: 2000-11-04
网络出版日期: 2010-10-01
基金资助
国家科委重点科学攻关项目(920-05-02)
Research on photocatalytic degradation of organophosphorous pesticides using TiO2· SiO2 /beads
Received date: 2000-11-04
Online published: 2010-10-01
张新荣, 杨平, 赵梦月 . TiO2·SiO2/beads降解有机磷农药的研究[J]. 工业水处理, 2001 , 21(3) : 13 -39 . DOI: 11894/1005-829x.2001.21(3).13
This paper introduces the preparation of composite photocatalyst TiO2·SiO2attached to the hollow glass microbeads by the dip-coating technique using TiCl4 and tetraethoxysilane as raw materials. The photocatalytic degradation of organophosphorous pesticides is studied. The results show that the photoactivity of TiO2·SiO2 /beads is improved,and the best photocatalyst produces1. 35 times of Degussa P - 25 TiO2. Moreover,the adsorption and the surface area are also introduced in this paper, and the surface condition and particle size of the composite photocatalysts are characterized by TEM and SEM.
Key words: photocatalyst; pesticides; wastewater treatment
[1] Hoffmann M R, et al. Environment application of semiconductor photocatalysis[J]. Chem. Rev., 1995, 95: 69~ 96.
[2] Ollis D F, Pelizzetti E,Serpone N. Destruction of water contaminants[J]. Environ. Sci. Technol., 1991, 9: 1 523~ 1 529.
[3] Muneer M, Philip R, Das S. Photocatalytic degradation of wastewater pollutants titanium dioxide-mediated oxidation of a textile acid blue 40# [J]. Res. Chem. Intermed., 1997, 23(3) : 233~ 246.
[4] Luis J A, et al. Photodegradation of phenol in water using silica -supported titania catalyst[J]. Applied. Catal., 1997, 13: 289~ 297.
[5] 张彭义, 余刚, 蒋展鹏.半导体光催化剂及其改性技术进展[J].环境科学进展, 1997, 5(3) : 1~ 10.
[6] Chen S F, Zhao M Y. Photocatalytic degradation of organophosphorous pesticides using TiO2 supported on fiber glass[J]. J. Microchem., 1996, 54(2) : 54~ 58.
[7] Zhao M Y, Chen S F. Photocatalytic degradation of organophosphorous pesticides using TiO2thin film [J]. Chem.Technol.Biotechnol., 1995, 64: 339~ 344.
[8] 陈士夫, 程丽雪.空心玻璃微球负载 TiO2清除水面漂浮的油层[J].环境科学学报, 1999, 19(4) : 40~ 42.
[9] 胡春, 王怡中.有机物多相光催化降解反应中催化剂固定化技术研究[J].环境科学, 1998, 19(4) : 40~ 42.
[10] Harada K, Hisanage T. Photocataly tic degradation of organophosphorous insecticides inaqueous semiconductor suspension[J]. Wat.Res., 1994, 4(11) : 1 415~ 1 417.
/
〈 |
|
〉 |