PBTCA及马—丙共聚物对碳酸钙垢阻垢机理的动力学研究
收稿日期: 1999-08-20
网络出版日期: 2010-10-01
Kinetic study of inhibition mechanism of PBTCA and AA-MA copolymer on CaCO3 scale
Received date: 1999-08-20
Online published: 2010-10-01
朱志良, 张冰如, 苏耀东, 倪亚明 . PBTCA及马—丙共聚物对碳酸钙垢阻垢机理的动力学研究[J]. 工业水处理, 2000 , 20(2) : 20 -23 . DOI: 10.11894/1005-829x.2000.20(2).20
The growing dynamic process of CaCO3crystal is studied with the method of adding crystal seed to the supersaturated solution.The speed constants of crystal growing are determined under the condition of no scale inhibitors or adding scale inhibitors.It is found that the growing of crystal CaCO3 in the solution is remarkably inhibited by PBTCA or the co-polymer AA-MA.The results indicates that the possible inhibition mechanism is the adsorption of inhibitors on the surfaces of crystal CaCO3.The adsorption of PBTCA on the crystal surfaces accords with the characters of Langmuir model,which is a kind of single molecule layer sorption.The adsorption of PBTCA on the active site of cry stal surfaces inhibites the growing of the crystal CaCO3 effectively.
Key words： inhibition mechanism; CaCO3; PBTCA; AA-MA copolymer,kinetic study
[1] 何铁林.国外碱性冷却水处理技术的发展与现状[J].工业水处理,1992,12(5):3 ～ 9.
[2] 纪永亮,林明鹤.工业循环冷却水处理技术进展[J].工业水处理,1990,10(1):3 ～ 7.
[3] 赵彦生.异丙烯膦酸—丙烯酸共聚物的阻垢效果[J].水处理技术,1998,24(1):43 ～ 46.
[4] 林芸,李万杰,沈敬之.马来酸—丙烯酸—丙烯酰胺共聚物的阻垢效果[J].水处理技术,1995,21(2):117 ～ 119.
[5] 郭德济,曾月香.马来酸酐—丙烯酰胺共聚物阻垢效果的研究[J].工业水处理,1996,16(2):16 ～ 17.
[6] 郑承超,李海风.水为溶剂合成的马—丙共聚物的阻垢性能研究[J].工业水处理,1994,14(5):17 ～ 19.
[7] 林保平,王国力,顾叙元.AA/ HAPS 共聚物阻垢性能研究[J].水处理技术,1996,22(1):44 ～ 47.
[8] F D Todd et al.…[P].EP 674022,1995-09-27.
[9] 天津大学物理化学教研室.物理化学[M].北京:人民教育出版社,1979.
[10] B R Smith,F Sw eet.The Crystallization of Calcium SulfateDihydrate[J].J.Coll.and Interfac.Sci.,1971,(37):612 ～618.
[11] M M Reddy,G H Nancollas.T he Crystallization of CalciumCarbonate I,Isotopic Exchange and Kinetics [J].J.Coll.andInterf ac.Sci.,1971,(36):166 ～ 172.
[12] G H Nancollas,M M Reedy.The Crystallization of CalciumCarbonate Ⅱ,Calcite Grow th Mechanism[J]. J.Coll.andInterfac.Sci.,1971,(37):824 ～ 830.
[13] G H Nancollas,M M Reedy.The Kinetics of Crystalli zation ofScale-Forming Minerals[J].Pet rol.Eng.J.,1974,(4):117 ～126.
[14] 黄兵.炼铁高炉净环水高pH 碱性运行的阻垢与缓蚀机理初探[J].工业水处理,1998,18(4):234 ～ 236.
[15] 郑邦乾,朱邦清.顺丁烯二酐共聚物的阻垢作用[J].工业水处理,1987,7(3):29 ～ 34.
[16] 汪祖膜,蔡兰坤.有机磷酸羧酸型水质稳定剂的研究[J].华东化工学院学报,1989,15(5):605 ～ 613.
[17] 黄伯芬,王刚.ZG—93 丙烯酸共聚物阻垢分散剂的研制及阻垢机理探讨[J].化学世界,1996,(2):88.
[18] 闵乃本.晶体生长的物理基础[M].上海:上海科学技术出版社,1980.
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