专论与综述

炼厂外排污水回用于循环冷却水腐蚀影响因素初探

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  • 石油大学化工学院环境中心 北京 102249;
黄洁(1978-),2000年毕业于石油大学化工学院,现为石油大学化工学院2001级硕士研究生。E-mail:bluesky3333@fm365.com。

收稿日期: 2001-08-03

  网络出版日期: 2010-10-01

Investigation on the affecting factors on corrosion using wastewater fromrefinery plant as circulating cooling water

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  • Development Center of Environmental Science and Engineering, Faculty of Chemical Engineering, the University of Petroleum, Beijing 102249,China

Received date: 2001-08-03

  Online published: 2010-10-01

摘要

从单因素、多因素和复杂水系考察了炼厂外排污水回用于循环冷却水腐蚀的影响因素,结果表明,碳钢腐蚀的主要影响因素取决于离子特性、氧化膜的形成和溶解氧的扩散等综合协同作用,其中以离子特性的影响为最大 (如 :Cl-、Ca2+ 、CO32- 的腐蚀性较强 )。碳钢腐蚀反应又可由以上三种主要影响因素分为三个反应控制区,而当电导率在 0 .1~ 2 .0mS/cm范围时,其水质属于腐蚀危险高发区。从而也进一步说明水质的低电导率处理,其防腐效果并不理想,相反在高电导率情况下却表现出相对较好的低腐蚀性能。

本文引用格式

黄洁, 张忠智, 季凌, 吴芳云 . 炼厂外排污水回用于循环冷却水腐蚀影响因素初探[J]. 工业水处理, 2002 , 22(2) : 9 -11 . DOI: 10.11894/1005-829x.2002.22(2).9

Abstract

The investigations of the corrosion under three conditions of sing le ion, multiple ions and complicatedwater system using wastewater from refinery plant as circulating cooling water have reached some conclusions.The major af fecting factors on co rrosion are the characteristics of ions, the fo rmation of coating and the diffusionrate of dissolved oxy gen.The rate of corrosion st rongly depends on the to tal ef fects of thei r cooperation and competition.And the characteristics of ions have the strongest ef fect among of the three factors, for example thecorrosions of Cl,Ca2+and CO32-are stronger than any o ther ions.The range of conductivity in w hich the corrosionreadily occurs is 0.1 ~ 2.0 mS/cm.Under the condit ions of low conductivity, the corrosion rate of steel alway s displays higher value, contradictorily under the conditions of high conductivity

参考文献

[1] 刘士永.石化污水回用于循环冷却水细菌控制的研究[C] .中石化总公司第六届水处理技术研讨会论文集, 1997 :288-295 .
[2] 中石化总公司生产部、发展部.冷却水分析、实验方法[M] .北京:石油大学环境中心, 1997 :383-389.
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