专论与综述

新型多功能低膦阻垢分散剂在结垢型水中的研究和应用

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  • 1. 天津市自来水集团有限公司, 天津 300040;
    2. 天津化工研究设计院, 天津 300131
周衡(1975- ), 1997年毕业于天津大学腐蚀与防护专业, 助理工程师。

收稿日期: 2002-02-05

  网络出版日期: 2010-10-01

Researches on and application of multifunctional and low phosphonic scale inhibitor to scaling-typed water

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  • 1. Tianjin Water Works Group Co.,Ltd., Tianjin 300040,China;
    2. Tianjin Research and Design Institute of Chemical Industry, Tianjin 300131, China

Received date: 2002-02-05

  Online published: 2010-10-01

摘要

针对石家庄医药化工厂严重结垢型水质及工况条件,通过静态阻垢试验和腐蚀试验,对原有配方进行了改进,研制出新型多功能低膦阻垢分散剂TS - 2 71,该药剂中加入了新研制的膦磺羧酸多元共聚物,由于药剂中含羧基、醛基、磺酸基、膦酸基等特效基团,对分散水中的CaCO3 、Ca3 (PO4)2 、CaSO4及Fe(OH)3 、Zn(OH)2 等效果良好,与其他水处理剂混溶性较好,并能与锌盐很好复配,达到优良的缓蚀性能。该药剂经过 3a的实际应用,证明其具有优良的阻垢性能,特别对CaCO3 垢有特效。

本文引用格式

周衡, 王润宇, 李冰 . 新型多功能低膦阻垢分散剂在结垢型水中的研究和应用[J]. 工业水处理, 2002 , 22(8) : 56 -57 . DOI: 11894/1005-829x.2002.22(8).56

Abstract

Aiming at the quality of the most serious scaling-typed water and working conditioins in Shijiazhuang Medical Chemistry Plant, the multifunctional and low phosphonic scale inhibitor TS -271 is chosen through stat- ic and corrosion tests.Oligomers-containing phosphonic acid, sulphonic acid and carboxylic acid which have ac- tive functional radicals of carboxy,aldehyde,sulpho,phospho, etc.are added to the scale inhibitor.It can effec- tively control the depositions of scale such asCaCO3, Ca3(PO4)2,CaSO4and Fe(OH)3,Zn(OH)2in water.It is a good corrosion inhibitor as well,when it is accompanied well with other agents particularly with zinc.The tests and applications show that TS -271 has excellent scale inhibition performance for scaling-typed water.

参考文献

[1] 周本省.工业水处理技术[M].北京:化学工业出版社,1997: 40—50.
[2] 路长青.磺酸共聚物的合成及阻垢分散性能的研究[J].工业水 处理,1995,15(3):14—17.
[3] 何铁林.水处理化学品手册[M].北京:化学工业出版社,2000: 213—217.
[4] James F Kneller.Oligomer-containing phosphate scale inhibitors[P].US 5 023 000,1991.

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