分析与监测

络合滴定法测定废水中铅离子的浓度

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  • 湖南大学环境科学与工程系, 湖南长沙 410082
李方文(1970- ),1993年毕业于湖南高等医学专科学校工业卫生与环境卫生专业.讲师,现为湖南大学在读硕士研究生.E-mail:lifangweng1@sohu.com.电话:0731- 8821462.

收稿日期: 2002-06-28

  网络出版日期: 2010-10-01

Determination of the concentration of lead ions in wastewater by chelatometric titration

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  • Department of Environmental Science and Engineering, Hunan University, Changsha 410082, China

Received date: 2002-06-28

  Online published: 2010-10-01

摘要

介绍了一种测定铅离子浓度的新方法,克服了常用方法 (双硫腙比色法、原子吸收分光光度法 )要使用剧毒物质KCN、绘制标准曲线、操作过程复杂及仅适合低浓度测定等局限性。该方法测定过程简单,测定结果准确(相对误差为 0.0 18%,相对标准偏差为 0.4 1% ),适合高浓度铅的测定

关键词: 络合滴定; 废水; 铅离子

本文引用格式

李方文, 魏先勋, 李彩亭, 张德见, 翟云波 . 络合滴定法测定废水中铅离子的浓度[J]. 工业水处理, 2002 , 22(10) : 38 -39 . DOI: 10.11894/1005-829x.2002.22(10).38

Abstract

A new method of determining the concentration of lead ions.This methods makes up the limitation which the common ways (e.g.dithizone colorimetry and atomic absorption spectrophotometry)have if virudent poison KCN is used, the standard curve is protracted, the operation process is too complicated, and is only suitable for the determination of matter with low concentration.The operation process of the new method is simple and the determination result is accurate (the relative error is 0.01 %and the relative standard deflectivity is 0.41 %).It is suitable for the determination of lead with high concentration.

参考文献

[1] 中南矿冶学院分析化学教研室,等.化学分析手册[M].北京:科学出版社,1984:22-25.
[2] 武汉大学三校.分析化学试验[M].北京:高等教育出版社,1978:58-65.

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