工业水处理 ›› 2017, Vol. 37 ›› Issue (3): 92-95. doi: 10.11894/1005-829x.2017.37(3).022

• 分析与监测 • 上一篇    下一篇

流场形全固态电极和3D打印流通池测定铁含量

贺小云1,2, 王济奎1, 金栋3, 洪颖1,4, 吕丹丹1, 杨晓露1, 张建枚5, 陈国松1   

  1. 1. 南京工业大学化学与分子工程学院, 江苏南京 210009;
    2. 常州亚邦制药有限公司, 江苏常州 213200;
    3. 中国特种设备检测研究院, 北京 100029;
    4. 南京出入境检验检疫局, 江苏南京 210046;
    5. 中石化水处理药剂评定中心, 北京 102500
  • 收稿日期:2016-11-22 出版日期:2017-03-20 发布日期:2017-03-30
  • 通讯作者: 陈国松,教授,E-mail:gschen3303@sina.com E-mail:gschen3303@sina.com
  • 作者简介:贺小云(1990—),硕士。电话:15961169616,E-mail:hexiaoyun0527@hotmail.com。
  • 基金资助:

    973国家重点基础研究发展计划资助项目（2013CB733504）；国家质检总局科研项目(2015IK129，2016IK138，2016KJ24)

Determination of iron content by means of flow-field shaped solid electrode and 3D-printed flow cell

He Xiaoyun1,2, Wang Jikui1, Jin Dong3, Hong Ying1,4, Lü Dandan1, Yang Xiaolu1, Zhang Jianmei5, Chen Guosong1   

  1. 1. College of Chemistry and Molecular Engineering, Nanjing Technology University, Nanjing 210009, China;
    2. Changzhou Yabang Pharmaceutical Co., Ltd., Changzhou 213200, China;
    3. China Special Equipment Inspection and Research Institute, Beijing 100029, China;
    4. Nanjing Entry-Exit Inspection and Quarantine Bureau, Nanjing 210046, China;
    5. Water Treatment Reagent Assessment Center of China National Petroleum Corporation, Beijing 102500, China
  • Received:2016-11-22 Online:2017-03-20 Published:2017-03-30

摘要：

首次提出流场形全固态（FFSS）电极的概念，设计并制备了FFSS丝网印刷电极，结合3D打印薄层流通池（TLFC），在流动状态下对邻菲啰啉-二价铁络合物进行循环伏安法（CV）扫描。结果表明，该体系对铁的测量灵敏度高、重现性好，线性范围为0.02~2.0 mg/L，检出限0.006 mg/L，比邻菲啰啉分光光度法更适用于水质的日常监测。该方法成功用于对循环冷却水中总铁的测定，加标回收率为97%~102%。

关键词: 流场形全固态电极, 3D打印薄层流通池, 流动循环伏安法, 循环冷却水, 总铁

Abstract:

The concept of flow field shaped solid(FFSS)electrode is put forward for the first time. The FFSS screen-printed electrode has been designed and prepared,combining with a 3D-printed thin-layer flow cell(TLFC). Under flow state,the Fe[(phen)3]2+ complex is scanned by cyclic voltammetry(CV). The results show that the developed system shows high measuring sensitivity and good reproducibility for iron. Its linear range is 0.02 to 2.0 mg/L and detection limit is 0.006 mg/L. Compared with Phenanthroline spectrophotometry,it is more suitable for daily monitoring of water quality. This method has successfully been used for the determination of the total iron in circulating cooling water. Its tagged recovery rate is in the range of 97% to 102%.

Key words: flow-field shaped solid electrode, 3D-printed thin-layer flow cell, flow cyclic voltammetry, circulating cooling water, total iron

中图分类号: 

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    出版单位：《工业水处理》编辑部
    ISSN　1005-829X
    CN　12-1087/TQ
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