工业水处理 ›› 2020, Vol. 40 ›› Issue (6): 64-67. doi: 10.11894/iwt.2019-0552

• 试验研究 • 上一篇    下一篇

改性活性炭吸附湿法冶金高盐废水中有机物的研究

王倩雯(),张丽,刘东方,朱妍,薛诚   

  1. 南开大学环境科学与工程学院, 天津 300350
  • 收稿日期:2020-03-16 出版日期:2020-06-20 发布日期:2020-06-20
  • 作者简介:王倩雯(1995—), 硕士。E-mail:1361650969@qq.com

Study on adsorption of organic matter in hydrometallurgical high-salt wastewater by modified activated carbon

Qianwen Wang(),Li Zhang,Dongfang Liu,Yan Zhu,Cheng Xue   

  1. College of Environmental Science and Engineering, Nankai University, Tianjin 300350, China
  • Received:2020-03-16 Online:2020-06-20 Published:2020-06-20

摘要:

针对湿法冶金高盐废水有机物去除难的问题,通过浸渍法对活性炭进行改性,研究了改性活性炭对湿法冶金高盐废水中有机物的去除效果,并探讨了改性活性炭的吸附机理。结果表明,在温度为25℃,改性活性炭投加量为50 g/L,不调节pH,吸附时间为36 h的条件下,COD去除率为65%,较改性前提高了25%。吸附过程符合准二级动力学方程,吸附等温线服从Langmuir方程,饱和吸附量为40.49 mg/g。

关键词: 湿法冶金废水, 高盐, 改性活性炭

Abstract:

The activated carbon is modified by impregnation method to study the problem of difficult removal of organic matter in hydrometallurgical high-salt wastewater. The removal effect of organic matter by modified activated carbon and its adsorption mechanism are discussed. The results show that under conditions of temperature of 25℃, modified activated carbon dosage of 50 g/L, no adjustment pH, and adsorption time of 36 h, the COD removal rate by modified activated carbon is 65%, which is 25% higher than that by unmodified activated carbon. The adsorption kinetics by modified activated carbon follows the pseudo-second-order model. The adsorption equilibrium follows Langmuir isotherm model. The maximum adsorption capacity is 40.49 mg/g.

Key words: hydrometallurgy wastewater, high-salt, modified activated carbon

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