工业水处理 ›› 2002, Vol. 22 ›› Issue (4): 37-39. doi: 10.11894/1005-829x.2002.22(4).37

• 试验研究 • 上一篇    下一篇

高浓度络合态铜离子废水的预处理研究

胡惠康, 赵国华   

  1. 同济大学化学系, 上海 200092
  • 收稿日期:2001-09-13 出版日期:2002-04-20 发布日期:2010-10-01
  • 作者简介:胡惠康(1957- ),毕业于华东理工大学,工程师。电话:021-65983695,E-mail:xxh01@mail.tongji.edu.cn。

Researches on the pretreatment of wastewater with highly concentrated copper in complex state

HU Huikang, ZHAO Guohua   

  1. Department of Chemistry, Tongji University, Shanghai 200092, China
  • Received:2001-09-13 Online:2002-04-20 Published:2010-10-01

摘要:

采用络合解离-中和共沉淀法对高浓度络合态铜离子废水进行了处理。通过电化学氧化还原反应、置换还原反应、物理吸附以及絮凝共沉淀等诸多因素的协同作用,将络合态铜离子解离去除,铜总去除率可达99.6%。铁粉粒度、铁粉投加量、反应停留时间以及中和pH值等是该预处理方法的主要影响因素

关键词: 络合态铜离子, 络合解离, 中和共沉淀

Abstract:

Wastewater with highly concentrated copper in complex state has been treated by dissociating the complex structure -neutralization and flocculation method.The dissociation and removal of complex copper ion could be a cooperation of various factors,including electrochemical oxidation and reduction,displacementreaction,phy sical adsorption and flocculation,etc.The total removal rate could reach 99.6 %.The main influential factors of this pretreatment are the granularity and quanti ty of iron powder,retention period of the reaction and the pH v alue of neutralization.

Key words: copper in complex state, dissociation of complex structure, neutralization and flocculation

中图分类号: