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壳聚糖-双氰胺脱色剂的合成和应用

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  • 1. 浙江大学环境科学研究所, 浙江杭州 310027;
    2. 浙江省环境保护科学研究院, 浙江杭州 310007
安忠军(1980- ),2002级浙江大学硕士研究生,电话: 0571-87951510.

收稿日期: 2004-11-09

  网络出版日期: 2010-10-01

基金资助

浙江省科技计划重点科研项目,编号:2003C23018

Synthesis and application of chitosan - dicyandiamine decolouriser

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  • 1. Research Institute of Environmental Science, Zhejiang University,Hangzhou 310027, China;
    2. Zhejiang Research Institute of Environmental Protection, Hangzhou 310007, China

Received date: 2004-11-09

  Online published: 2010-10-01

摘要

以壳聚糖、双氰胺为主要原料合成了一种新型、高效的脱色剂处理染料废水,该脱色剂对4种典型的染料的脱色率都>90%。实验表明:当合成温度控制在约50℃、n(壳聚糖结构单元)∶n(双氰胺)∶n(硫酸铝)=1∶4∶1.5、反应时间为2.5h时,合成的脱色剂对染料废水的脱色效果为最佳。实验发现该脱色剂对染料废水的脱色率要远远高于壳聚糖与硫酸铝的复配溶液。对上虞污水厂废水的处理效果,其COD去除率比使用PAC提高20%以上。

本文引用格式

安忠军, 黄克玲, 鲁航, 文岳中, 刘维屏 . 壳聚糖-双氰胺脱色剂的合成和应用[J]. 工业水处理, 2005 , 25(6) : 46 -49 . DOI: 10.11894/1005-829x.2005.25(6).46

Abstract

A new kind of highly efficient decolouriser has been synthesiz ed with chitosan- dicyandiamine as main raw material to treat the dye wastewater. The decolorization rates of the 4 typical types of dye-stuff (500 mg/L)unde r the tests are all over 90%. The results of experiments show that under the con ditions of the reaction temperature is 50 ℃, n(chitosan) ∶ n(dicyandiamine ) ∶ n(aluminum sulfate) = 1 ∶ 4 ∶ 1.5, reaction time is 2.5 h, the decol orization rates are the best. The results show that the decolorization rates of chitosan - dicyandiamine decolouriser are much higher than chitosan, which is u sed in combination with aluminum sulfate. The treatment effect to wastewater of Shangyu Wastewater Factory has been studied. The result indicates that the COD r emoval rate is 20% higher than PAC, which was used in the past in this factory.

参考文献

[1] 柴平海,张文青,金鑫荣.甲壳素/壳聚糖开发与研究新动向[J],化学通报,1999,(7):8-11
[2] 蒋挺大.壳聚糖[M].北京:化学工业出版社,2001.34-35
[3] 陈亮,陈东辉.壳聚糖絮凝剂在水处理中的应用[J].工业水处理,2000,20(9):4-8
[4] 董银卯,等.双氰胺-甲醛系列阳离子絮凝剂的合成研究[J].北京轻工业学院学报,1995,(6):64-67
[5] 汤继军,高枫.双氰胺-甲醛缩聚物脱色剂的研究及应用[J].工业水处理,2002,22(4):27-28
[6] 徐肖邢,曾小君,陆雪良,等.采用高效脱色剂处理染料废水的研究[J].工业用水与废水,2003,34(1):39-42
[7] 陈天,等.壳聚糖对酸性染料的吸附作用[J].江苏农学院学报,1996,18(3):93-96

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