试验研究

超声波辅助TiO2光催化降解印染废水的研究

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  • 广州暨南大学生命科学技术学院化学系 广东广州510632
王桂华(1978- ),暨南大学化学系,在读硕士研究生,从事环境分析与治理技术的研究,E-mail:wgh9741@163.com

收稿日期: 2003-04-26

  网络出版日期: 2010-10-01

基金资助

国家自然科学基金资助项目,编号:20277016;广东省自然科学基金资助项目,编号:000727

Researches on the application of ultrasonic wave assisting TiO2 photocatalysis to the degradation of printing and dyeing wastewater

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  • Department of Chemistry, College of Life Science and Technology, Jinan Universi ty, Guangzhou 510632, China

Received date: 2003-04-26

  Online published: 2010-10-01

摘要

探讨了超声波辅助TiO2提高光催化降解印染废水速度的原因,研究了超声波辅助,H2O2以及溶液初始pH值对TiO2光催化降解印染废水速率的影响;用均匀试验设计方法确定了降解印染废水的最佳条件:TiO2的投加量0.52g/L,溶液的初始pH值3.5,n(金红石型)∶n(锐钛型TiO2)=1∶3,质量分数为30%的H2O2的投加量3mL/L。

关键词: TiO2; 超声波; 印染废水

本文引用格式

王桂华, 尹平河, 赵玲, 唐浩亮 . 超声波辅助TiO2光催化降解印染废水的研究[J]. 工业水处理, 2004 , 24(4) : 42 -45 . DOI: 10.11894/1005-829x.2004.24(4).42

Abstract

The reason of ultrasonic wave assisting titanium dioxide to increase the speed of photocatalytic degradation of printing and dyeing wastewater is discussed.The effects of ultrasonic wave assistance,H2O2 and the initial pH value o f the solution on TiO2 photocatalytic degradation have been studied.The best co nditions of the degradation of printing and dyeing wastewater are determined by the equality experimentation design as follows:the mass concentration of TiO2 added is 0.52 g/L, the initial pH value of the solution is 3.5,the ratio of rutile-typed TiO2 and anatase-typed TiO2 is 1∶3,and the feeding amount of 30% of H2O2 is 3 mL/L.

参考文献

[1] 李春喜,王京刚,王子镐,等.超声波技术在污水中的应用与研究进展[J].环境污染治理技术与设备,2001,2(2):64-69
[2] 王建龙,柳萍,施汉昌,等.声化学在水污染控制中的应用研究现状[J].化学通报,1997,7(1):34-37
[3] 蒋建华,许春建,周明.超声降解水体中化学污染物的研究进展[J].化工进展,2001,2(1):11-15
[4] Mason T J,Cordemand E D.Ultrasonic intensification of chemical processing and operations[J].A Review,Trans. I.Chem. E.,1996,(74A) :511-516
[5] Muller T S,Zhuolian Sun,Kumar M P,et al.The combination of photocatalysis and ozonolysis as a new approach for cleaning 2,4-dichlorophenoxyaceticacid polluted water [J].Chemosphere,1998,36(9):2043-2055
[6] Fox M A,Dulay M T.Heterogenous photocatalysis[J].Chem.Rev.,1993,93(1):341-357
[7] Yoshifumi Kado,Mahito Atobe,Tsutomu Nonake.Ultrasonic effects on electroorganic processes- Part 20.Photocatalytic oxidation of aliphatic alcohols in aqueous suspension of TiO2powder [J ].Ultrasonic Sonochemistry,2001,8(2):69-74
[8] Mason T J.Current trend in Sonochemistry [M].Cambridge:The Society of Chemical Industry,1992.171-175
[9] Compton R G,Akkermans R P,Coles B A,et al.Ultrasound in photoelectrochemistry [J].Ultrsason.Sono.-Chem.,1997,4 (3):223-228
[10] Shirgoankar I Z,Pandit A B.Sonophotochemical destruction of aqueous solution suspension of TiO2 powder [J].Ultrason. Sonochem.,1998,5(2):53-61
[11] 李太友.有机污染物的半导体光催化氧化研究进展综述[J].武汉大学学报,2001,16(3):12-16
[12] 许文林,王雅琼,高明国.功率超声在有机废水处理中的应用[J].水处理技术,2001,27(2):70-73
[13] Lakshim K,Renganathan R,Fujita S.Study on TiO2-mediated photocatalytic degradation of methylene blue[J].Journal of Photochemistry and Photobiology,1995,88(3):163-167
[14] 冯良荣,谢卫国,吕绍解,等.二氧化钛光催化氧化十二烷基苯磺酸钠[J].环境污染治理技术与设备,2001,2(2):14-20
[15] 贺北平,王占生,张锡辉.半导体光催化氧化有机物的研究现状及发展趋势[J]环境科学,1993,15(3):80-83
[16] 刘树深,易忠胜.基础化学计量学[M].北京:科学出版社出版,1999.16-23

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