实验研究

过硼酸钠制备的稳定性二氧化氯存在形态的研究

展开
  • 南京理工大学化工学院, 江苏南京 210094
贺启环(1943- ),南京理工大学环境科学与工程系,教授,研究方向为废水、废气处理新技术新工艺新设备和二氧化氯系列产品开发和应用,电话:025-84315532.

收稿日期: 2004-01-11

  网络出版日期: 2014-09-30

Study on the existence form of chlorine dioxide in stabilized chlorine dioxide solution prepared by sodium perborate

Expand
  • School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Received date: 2004-01-11

  Online published: 2014-09-30

摘要

以过硼酸钠为稳定剂制备稳定性二氧化氯溶液(稳定液)。通过对稳定液性质的测定、溶液稳定性试验、纸色谱分析和红外光谱分析,以及在与以过碳酸钠为稳定剂的稳定液作对比分析的基础上,结合配位化学理论,提出在以过硼酸钠为稳定剂的稳定性二氧化氯溶液中ClO2是以活性配位化合物的形式存在,并推测了其可能的分子结构。

本文引用格式

贺启环, 潘慧云, 谢慧芳 . 过硼酸钠制备的稳定性二氧化氯存在形态的研究[J]. 工业水处理, 2004 , 24(5) : 46 -49 . DOI: 10.11894/1005-829x.2004.24(5)..46

Abstract

The stabilized chlorine dioxide solution(stabilized solution) is prepared by adding sodium perborate. By the determination of the characters of the stabilized solution, tests of solution stability, paper chromatography and infrared spectrometry, and on the basis of the comparison between the stabilized solution using sodium perb-orate and sodium percarbonate, and according to the coordination chemistry theory, it is put forward that chlorine dioxide may be retained in the solution as a coordination compound and the molecule structure is presumed.

参考文献

[1] 贺启环.稳定性二氧化氯溶液中二氧化氯存在形态的研究[J].工业水处理,2001,21(4):8-10
[2] Moises L de Guerara. Aqueous Chlorine Dioxide Antiseptic Compositions and Production Thereof[P]. US 2701781, 1955
[3] Thomas P, et al. Stable Chlorine Dioxide Antiseptic Composition and Method of Making Same[P]. US 3271242, 1966
[4] 徐瑞群.二氧化氯分析方法研究与二氧化氯消毒制剂测试[D].南京:南京理工大学,2000
[5] 杨宗芬,等.比色法测定二氧化氯含量[J].消毒与杀菌,1989,6(4):196-198
[6] 谢慧芳.稳定性二氧化氯溶液中二氧化氯存在形态和稳定机理的研究[D].南京:南京理工大学,1997
[7] 潘慧云.有机稳定性二氧化氯的初步研究[D].南京:南京理工大学,2002
[8] 吕希伦.无机过氧化合物化学[M].北京:科学出版社,1987.353-354
[9] 孟庆珍,等.无机化学(下册)[M].北京:北京师范大学出版社,1988.1088-1089

文章导航

/