摘要：

以过硼酸钠为稳定剂制备稳定性二氧化氯溶液(稳定液)。通过对稳定液性质的测定、溶液稳定性试验、纸色谱分析和红外光谱分析,以及在与以过碳酸钠为稳定剂的稳定液作对比分析的基础上,结合配位化学理论,提出在以过硼酸钠为稳定剂的稳定性二氧化氯溶液中ClO₂是以活性配位化合物的形式存在,并推测了其可能的分子结构。

关键词: 二氧化氯, 稳定性二氧化氯, 二氧化氯存在形态

Abstract:

The stabilized chlorine dioxide solution(stabilized solution) is prepared by adding sodium perborate. By the determination of the characters of the stabilized solution, tests of solution stability, paper chromatography and infrared spectrometry, and on the basis of the comparison between the stabilized solution using sodium perb-orate and sodium percarbonate, and according to the coordination chemistry theory, it is put forward that chlorine dioxide may be retained in the solution as a coordination compound and the molecule structure is presumed.

Key words: chlorine dioxide, stabilized chlorine dioxide, chlorine dioxide existence form

中图分类号: 

• TQ124.4+3