工业水处理 ›› 2008, Vol. 28 ›› Issue (8): 60-69. doi: 10.11894/1005-829x.2008.28(8).60

• 试验研究 • 上一篇    下一篇

油田注入水中二氧化氯杀菌试验研究

舒志明1,2, 张照韩1, 陈忠喜2, 马放1   

  1. 1. 哈尔滨工业大学市政环境工程学院, 黑龙江哈尔滨 150090;
    2. 大庆油田建设设计研究院, 黑龙江大庆 163712
  • 收稿日期:2008-04-16 修回日期:2008-04-16 出版日期:2008-08-20 发布日期:2010-10-01
  • 作者简介:舒志明(1971- ),哈尔滨工业大学硕士研究生,大庆油田建设设计研究院高级工程师,主要研究方向油田水处理,电话:0459-5902081,E-mail:shuzhiming@petrochina.com.cn。
  • 基金资助:

    国家高技术研究发展(863)计划(2002AA601310);大庆油田有限责任公司科技发展项目(030143)

Sterilizing tes ts on refilling water in oil field by chlorine dioxide

Shu Zhiming1,2, Zhang Zhaohan1, Chen Zhongxi2, Ma Fang1   

  1. 1. School of Municipal and Environmental Engineering, Harbin University of Technology, Harbin 150090, China;
    2. Design and Research Institute of Daqing Oil-field, Daqing 163712, China
  • Received:2008-04-16 Revised:2008-04-16 Online:2008-08-20 Published:2010-10-01

摘要:

为控制大庆油田注入水中细菌的数量和减少硫化物的危害,作者在油田污水注入站进行了二氧化氯杀菌试验,确定了二氧化氯的最佳投加浓度。结果表明,当储水罐内回注水中投加的二氧化氯质量浓度在40mg/L以上时,对污水中硫酸盐还原菌、腐生菌和铁细菌的灭菌率可达90%,回注水中的硫化物含量也明显减少,细菌与硫化物指标达到油田注水标准。腐蚀率却随着二氧化氯浓度的增大而逐渐增加,最高达到0.069mm/a。在回注水中二氧化氯质量浓度为40mg/L时,腐蚀率达到Q/SYDQ0605-2006企业标准。

关键词: 二氧化氯, 油田注水, 杀菌, 硫化物, 腐蚀率

Abstract:

For the sterilization of the bacteria in oil field refilling water and reducing the harm of sulfides, the refilling water in oil field has been treated by chlorine dioxide at the wastewater refilling station of daqing oilfield. The results show that when the optimal concentration of chlorine dioxide in the water-storing tank is above 40 mg/L, the sterilization rates of sulphate reduction bacteria, saprophyte bacteria and iron bacteria could reach 90%. The sulfide content in the wastewater is decreased obviously, and the indexes of bacteria and sulfide reach the standard of oil field refilling water. But the erodibility increases gradually with the increase of chlorine dioxide concentration, by lab and field experiments. The highest erodibility reaches 0.069 mm/a. When the concentration of chlorine dioxide in the refilling water is 40 mg/L, the erodibility reaches the demand of Standard Q/SYDQ 0605-2006.

Key words: chlorine dioxide, oil field refilling water, sterilization, sulfide, erodibility

中图分类号: