工业水处理 ›› 2015, Vol. 35 ›› Issue (10): 84-87. doi: 10.11894/1005-829x.2015.35(10).084

• 分析与监测 • 上一篇    下一篇

水中二氧化氯浓度的分光光度法测定

于坤1,2, 唐利红2, 于宏兵2, 李多2, 王启山2   

  1. 1. 喀什大学研究生处, 新疆 喀什 844006;
    2. 南开大学环境科学与工程学院, 天津 300071
  • 收稿日期:2015-08-17 出版日期:2015-10-20 发布日期:2015-10-22
  • 通讯作者: 于宏兵,E-mail:hongbingyu1130@sina.com E-mail:hongbingyu1130@sina.com
  • 作者简介:于坤(1978—),南开大学在读博士研究生,讲师.电话:18920260396,E-mail:yukun0720@mail.nankai.edu.cn
  • 基金资助:

    国家水体污染控制与治理科技重大专项(2013ZX07315-003);"重点流域城市污水处理厂污泥处理处置技术优化应用研究"课题(2013ZX07315-003-06)

UV-spectrophotometry determination of chlorine dioxide in drinking water

Yu Kun1,2, Tang Lihong2, Yu Hongbing2, Li Duo2, Wang Qishan2   

  1. 1. Graduate Affairs Office, Kashi University, Kashi 844006, China;
    2. College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China
  • Received:2015-08-17 Online:2015-10-20 Published:2015-10-22

摘要:

二氧化氯在360 nm处有最大吸收峰,可以作为紫外分光光度法定量测定的依据.通过实验对分光光度法测定生活饮用水中二氧化氯的干扰因素、波长的选择、测定范围及精确度进行了研究.结果表明,该方法能快速准确地测定生活饮用水中低浓度的二氧化氯;低浓度二氧化氯回收率在91.4%以上,中高浓度二氧化氯回收率在89.8%~91.1%之间.

关键词: 二氧化氯, 紫外分光光度法, 饮用水, 定量测定

Abstract:

The maximum adsorption peak of ClO2 is at 360 nm,which could be used as the basis for quantitative determination of ClO2. Interference factors,wavelength selection,measuring range and accuracy of spectrophotometric determination of chlorine dioxide in drinking water have been studied by experiments. Results indicate that this method can rapidly and accurately determine ClO2 in drinking water with low concentrations. The average recovery rate of low concentration ClO2 in water is more than 91.4%,and the average recovery rate of ClO2 with medium or high concentration in water is between 89.8%-91.1%.

Key words: chlorine dioxide, UV-spectrophotometry, drinking water, quantitative determination

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