Research of the application of Fenton oxidation to the treatment of wastewater containing urotropine

Expand
  • 1. Shanghai Construction Engineering Administration Co., Ltd., Shanghai 200031, China;
    2. School of Environment Science and Engineering, Tongji University, Shanghai 200092, China

Online published: 2010-10-01

Abstract

The reaction condition has been optimized through experiments for the oxidation of wastewater containing urotropine by Fenton reagent. It is indicated that when ρ(H2O2) = 8.25 g/L, n(H2O2) ∶ n(Fe) = 20 ∶ 1, pH = 3.0, CODCr may be decreased from 1 250 mg/L to lower than 100 mg /L after 5 h reaction under 35 ℃. But it is difficult for CODCr to reach 100 mg /L when the temperature dropped to 15 ℃. It is also suggested that CODCr of the effluent from CSTR(continuous-flow stirred tank reactor) is significantly higher than that from SBR(sequnencing batch reactor) under the same condition.

Cite this article

Li Ju, Chen Heqian, Huang Youyi, Wu Zhichao . Research of the application of Fenton oxidation to the treatment of wastewater containing urotropine[J]. Industrial Water Treatment, 2004 , 24(6) : 39 -41 . DOI: 10.11894/1005-829x.2004.24(6).39

References

[l] 李广林. 乌洛托品及其生产方法[J]. 化肥工业, 1997, 24(4):51-53
[2] Neyens E, Bacyens J. A review of classic Fenton's peroxidation as an advanced oxidation technique[J]. Journal of Hazardous Materials, 2003, 98(2):33-50
[3] 韦朝海, 等. Fenton试剂催化氧化降解含硝基苯废水的特性[J]. 环境科学, 2001, 22(5): 60-64
[4] Sheng H Lin, Chi M Lin, Horng G Leu. Operation characteristics and kinetic studies of surfactant wastewater treatment by Fenton oxidation[J]. Water Research, 1999, 33(7):1735-1741
[5] Malik P K, SaHa S K. Oxidation of direct dyes with hydrogen peroxide using ferrous ion as catalyst[J]. Separation and Purification Technology, 2003, 31(3):241-250

Outlines

/