Effect of some polycarboxylic acids as scale inhibitor on the precipitation and solution of calcium carbonate in aqueous solution

Expand
  • Department of Chemistry, Tongji University, Shanghai 200092, China

Received date: 2000-12-05

  Online published: 2010-10-01

Abstract

The solubility of different forms of calcium carbonate under various conditions has been calculated by using the self-edited computer program .The supersaturated solution system of calcium carbonate has been analyzed with the same program .The effect of four polycarboxylic acid (PAA1 , PAA2 , PMA -AA , PPMA)as scale inhibitors on the precipitation and solution of calcium carbonate in aqueous solution has been studied .From the point of view of the effect on the precipitation forms , the explanations are given out to describe the scale inhibition mechanism and the effect of scale inhibitors on the metastable state of CaCO3 in the supersaturated solution.

Cite this article

ZHU Zhi liang, LI Ji wen, NI Ya ming . Effect of some polycarboxylic acids as scale inhibitor on the precipitation and solution of calcium carbonate in aqueous solution[J]. Industrial Water Treatment, 2001 , 21(6) : 7 -10 . DOI: 10.11894/1005-829x.2001.21(6).7

References

[1] Ljerka Brecevic and Arne Eri c Nielsen .Solubi li ty of Calcium Carbonate Hexahydrat e[J] .Acta Chem .Scand ., 1993 ,(47):668 ~ 673
[2] 朱志平.水处理中碳酸钙最小溶解度预测[J] .水处理技术,1992 , 18(5):343 ~ 348
[3] Jean-Yves , Jean-Claude Bollinger , Henri Tolosa, Nathalie Gache.Calciumcarbonate solubilit y :a reappraisal of scale formation and inhibition[J] .Talanta , 1996 ,(43):1 497 ~ 1 509
[4] Z Amjad and J P Hooley .Ef fect of Antiscalants on the Precipi tationof C alcium Carbonate in Aqueous Solutions[J] .Tensida S urf.Det .,1994 , 31(1):12 ~ 17
[5] Jean-Yves Gal , Jean-Claude Bollinger , Henri Tolosa, et al.Calciumcarbonate solubilit y :a reappraisal of scale formati on and inhibit ion[J].Talanta, 1996 ,(43):1 497 ~ 1 509
[6] 朱志良, 张冰如, 苏耀东, 等.PBTCA 及马丙共聚物对碳酸钙阻垢机理的动力学研究[J] .工业水处理, 2000 , 20(2):20 ~ 23.

Outlines

/