工业水处理 ›› 2012, Vol. 32 ›› Issue (4): 39-42. doi: 10.11894/1005-829x.2012.32(04).39

• 试验研究 • 上一篇    下一篇

一种新型缓蚀阻垢剂的研究

李俊华1, 卞雯2, 李俊莉1, 卢永斌2   

  1. 1. 陕西省石油化工研究设计院, 陕西西安 710054;
    2. 西安石油大学化学化工学院, 陕西西安 710065
  • 收稿日期:2012-02-03 出版日期:2012-04-20 发布日期:2012-04-13
  • 作者简介:李俊华(1964- ),1986 年毕业于西南石油大学,高工,从事油田化学品及油水井增产技术的研究。电话:15339040505,E-mail:junhualigood@163.com。

Study on a new type of corrosion and scale inhibitor

Li Junhua1, Bian Wen2, Li Junli1, Lu Yongbin2   

  1. 1. Shaanxi Research Design Institute of Petroleum and Chemical Industry, Xi’an 710054, China;
    2. College of Chemistry and Chemical Engineering, Xi’an Shiyou University, Xi’an 710065, China
  • Received:2012-02-03 Online:2012-04-20 Published:2012-04-13

摘要:

以水溶性季铵盐、水解聚马来酸酐、聚环氧琥珀酸钠、聚天冬氨酸为原料,复配了一种新型缓蚀阻垢剂BW-3。BW-3具有优异的阻垢性能和良好的缓蚀效果。在所测浓度范围内,BW-3的阻垢和缓蚀效果均明显优于油田常用缓蚀阻垢剂|电化学试验结果表明,BW-3的缓蚀机理属于"负催化效应",是一种以抑制阴极反应过程为主的混合型缓蚀剂。BW-3对CaCO3垢的阻垢机理主要是晶格畸变作用。

关键词: 缓蚀阻垢剂, 水溶性季铵盐, 聚环氧琥珀酸钠, 聚天冬氨酸

Abstract:

A new corrosion inhibitor BW-3 has been prepared by using water-soluble quaternary ammonium salt,hydrolytic polymaleic anhydride,polyethylene succinate,polyaspartic acid as raw materials. BW-3 has excellent anti-scaling performance and good corrosion effect. Anti-scaling performance and corrosion performance of BW-3 are significantly better than the corrosion inhibitors which have frequently used by oilfields. Electrochemical test results show that the corrosion mechanism of BW-3 is a “negative catalytic effect” and a mixed type of corrosion inhibitor which mainly inhibit cathode reaction. The inhibiting mechanism of CaCO3 scale by BW-3 is,mainly lattice distortion function.

Key words: corrosion and scale inhibitors, water-soluble quaternary ammonium salt, polyethylene succinate, polyaspartic acid

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