工业水处理 ›› 2015, Vol. 35 ›› Issue (5): 62-66. doi: 10.11894/1005-829x.2015.35(5).066

• 试验研究 • 上一篇    下一篇

介孔Al2O3/PVDF复合中空纤维膜的制备及其性能

曹志普   

  1. 天津大学化工学院, 天津 300072
  • 收稿日期:2015-04-16 出版日期:2015-05-20 发布日期:2015-05-22
  • 作者简介:曹志普(1989—),硕士。E-mail:caozhipu@sina.cn。

Preparation of mesoporous Al2O3/PVDF composite hollow fiber membrane and its performances

Cao Zhipu   

  1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • Received:2015-04-16 Online:2015-05-20 Published:2015-05-22

摘要:

为了提高PVDF中空纤维膜在处理含油废水过程中的亲水性能、抗压实性能和抗污染性能,实验以介孔Al2O3为无机添加粒子,采用溶液纺丝法制备出介孔Al2O3/PVDF复合中空纤维膜。通过扫描电子显微镜和傅里叶红外光谱观察介孔Al2O3/PVDF复合中空纤维膜的形貌和成分,结果证明介孔Al2O3成功地添加到PVDF中空纤维膜中。通过接触角,纯水和含油废水通量的测试,结果表明介孔Al2O3的添加改善了PVDF膜的亲水性能、抗压实性能和抗污染性能。

关键词: 聚偏氟乙烯, 介孔Al2O3, 中空纤维膜

Abstract:

In order to improve the hydrophilic performance,anti-compaction performance and anti-fouling performance in the process of treating oil-bearing wastewater,mesoporous Al2O3 has been used as inorganic additive particles,and solvent spinning method has been used for the preparation of mesoporous Al2O3/PVDF composite hollow fiber membrane. The morphology and components of mesoporous Al2O3/PVDF composite hollow fiber membrane are observed with SEM and FT-IR. It is demonstrated that mesoporous Al2O3 can successfully be added into PVDF membrane. Through contact angles and the tests of the flux of pure water and oil-bearing wastewater,it is found that the addition of mesoporous Al2O3 has improved the hydrophilic property,anti-compaction property and anti-fouling property of the PVDF hollow fiber membrane.

Key words: PVDF, mesoporous Al2O3, hollow fiber membrane

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