工业水处理 ›› 2018, Vol. 38 ›› Issue (3): 21-24. doi: 10.11894/1005-829x.2018.38(3).021

• 试验研究 • 上一篇    下一篇

CaO2同步氧化Fe(Ⅱ)除磷的研究

徐垚, 李大鹏, 韩菲尔   

  1. 苏州科技大学环境科学与工程学院, 江苏苏州 215009
  • 收稿日期:2017-11-28 出版日期:2018-03-20 发布日期:2018-04-17
  • 通讯作者: 李大鹏,教授。E-mail:ustsldp@163.com。 E-mail:ustsldp@163.com
  • 作者简介:徐垚(1991-),硕士。电话:18862185393,E-mail:sustxuyao@163.com。
  • 基金资助:
    国家自然科学基金项目(51278523);江苏省“六大人才高峰”项目(2013-JNHB-022);水处理技术与材料协同创新中心项目

Research on CaO2 synchronously oxidation Fe(Ⅱ) for phosphate removal

Xu Yao, Li Dapeng, Han Feier   

  1. School of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China
  • Received:2017-11-28 Online:2018-03-20 Published:2018-04-17

摘要: 研究了单独Fe(Ⅱ)、单独CaO2以及CaO2同步氧化Fe(Ⅱ)对人工模拟废水中磷的去除效果。结果表明:Fe(Ⅱ)与磷酸盐反应生成的物质颗粒细小,是导致Fe(Ⅱ)除磷效果不佳的重要原因;CaO2同步氧化Fe(Ⅱ)对磷的去除率显著提高。50 mg/L CaO2同步氧化Fe(Ⅱ)体系90 min后对磷去除率为82.38%,远大于相同时间内单独Fe(Ⅱ)对磷去除率(9.80%)与单独CaO2对磷去除率(24.24%)之和(34.04%)。

关键词: 过氧化钙, 亚铁离子, 磷酸盐, 粒径分布

Abstract: The research on the removing effects of individual ferrous ions,individual calcium peroxide and CaO2 syn-chronously oxided Fe(Ⅱ) on the removal of phosphorus from artificially simulated wastewater has been implemented. The results show that the insoluble particles formed by the reaction of Fe(Ⅱ) with phosphate are tiny,which is the main cause for the poor phosphorus removing effect. The removing rate of phosphorus by CaO2 synchronously oxida-tion Fe(Ⅱ) is significantly improved. After 50 mg/L of CaO2 has synchronously oxided Fe(Ⅱ) for 90 min,the remov-ing rate of phosphorus is 82.38%,which is far higher than the summation of the phosphorus removing rates(34.04%) by individual Fe(Ⅱ)(9.80%),plus the phosphorus removing rate by individual CaO2(24.24%).

Key words: calcuim peroxide, ferrous ion, phosphate, particle size distribution

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