强化电絮凝技术的基础、现状和未来展望

doi:10.19965/j.cnki.iwt.2020-1164

摘要/Abstract

摘要：

电絮凝技术作为一种环境友好型水处理工艺，近年来逐渐成为研究热点。在回顾了电絮凝技术的研究历史基础上，论述了强化电絮凝技术在传统电絮凝技术上的改进与发展，综述了国内外在该方向上的净水机理和新观点。重点介绍了强化电絮凝技术在电源技术、电极技术和集成技术上的研究进展，指出了强化电絮凝技术的未来发展方向，以促进该项技术的推广与应用。

关键词: 强化电絮凝, 净水机理, 电源技术, 电极技术, 集成技术

Abstract:

As an environment⁃friendly water treatment process，electrocoagulation has gradually become a research hotspot in recent years. On the basis of reviewing the historical development of the field of electrocoagulation，the improvement and development of enhanced electrocoagulation based on traditional electrocoagulation was discussed，and the water purification mechanism and new viewpoint were summarized at home and abroad. The research progress of power supply technology，electrode technology and integrated technology in the process of enhanced electrocoagulation were introduced. The future development direction of enhanced electrocoagulation was pointed out，so as to promote the popularization and application of this technology.

Key words: enhanced electrocoagulation, purification mechanism, power supply technology, electrode technology, integrated technology

中图分类号:

X703

戴常超, 陈大宏, 刘峻峰, 黄琳琳, 张杰, 冯玉杰. 强化电絮凝技术的基础、现状和未来展望[J]. 工业水处理, 2022, 42(1): 1-14.

Changchao DAI, Dahong CHEN, Junfeng LIU, Linlin HUANG, Jie ZHANG, Yujie FENG. Foundations，present situations and future expectations of enhanced electrocoagulation[J]. Industrial Water Treatment, 2022, 42(1): 1-14.

https://www.iwt.cn/CN/Y2022/V42/I1/1

图/表 4

图1 电絮凝论文发表情况

Fig. 1 Publication of electrocoagulation papers

图2 强化电絮凝论文发表情况

Fig. 2 Publication of enhanced electrocoagulation papers

图3 电絮凝净水机理

Fig. 3 Mechanism of electrocoagulation

图4 棒状电极（a）、圆柱电极（b）、旋转电极（c）、穿孔电极（d）示意

Fig. 4 Rod electrode（a）， cylindrical electrode（b）， rotating electrode（c）， perforated electrode（d）

参考文献 80

1	GARCIA⁃SEGURA S， EIBAND M， DE MELO J V，et al. Electrocoagulation and advanced electrocoagulation processes：A general review about the fundamentals，emerging applications and its association with other technologies［J］. Journal of Electroanalytical Chemistry，2017，801：267-299. doi:10.1016/j.jelechem.2017.07.047
2	周振，姚吉伦，庞治邦，等. 电絮凝技术在水处理中的研究进展综述［J］. 净水技术，2015，34（5）：9-15. doi:10.3969/j.issn.1009-0177.2015.05.002
	ZHOU Zhen， YAO Jilun， PANG Zhibang，et al. Review of research development in electrocoagulation technology in water treatment［J］. Water Purification Technology，2015，34（5）：9-15. doi:10.3969/j.issn.1009-0177.2015.05.002
3	SINGH T S A， RAMESH S T. New trends in electrocoagulation for the removal of dyes from wastewater：A review［J］. Environmental Engineering Science，2013，30（7）：333-349. doi:10.1089/ees.2012.0417
4	胡承志. 电解制备的聚合铝的形态结构与絮凝特性的研究［D］. 咸阳：西北农林科技大学，2003. doi:10.1016/s0927-7757(02)00542-3
	HU Chengzhi. Study on the species，configuration，and coagulation properties of polyaluminum chloride prepared by electrolysis process［D］. Xianyang： Northwest Sci⁃Tech University of Agriculture and Forestry，2003. doi:10.1016/s0927-7757(02)00542-3
5	LIU Guangjie， QU Jiuhui， TANG Hongxiao. The electrochemical production of highly effective polyaluminum chloride［J］. Water Research，1999，33（3）：807-813. doi:10.1016/s0043-1354(98)00275-9
6	MOLLAH M Y A， SCHENNACH R， PARGA J R，et al. Electrocoagulation（EC）-Science and applications［J］. Journal of Hazardous Materials，2001，84（1）：29-41. doi:10.1016/s0304-3894(01)00176-5
7	AL⁃QODAH Z， TAWALBEH M， AL⁃SHANNAG M，et al. Combined electrocoagulation processed as a novel approach for enhanced pollutants removal：A state⁃of⁃the⁃art review［J］. Science of the Total Environment，2020，744：140806. doi:10.1016/j.scitotenv.2020.140806
8	HOLT P K， BARTON G W， MITCHELL C A. The future for electrocoagulation as a localised water treatment technology［J］. Chemosphere，2005，59（3）：355-367. doi:10.1016/j.chemosphere.2004.10.023
9	KHANDEGAR V， SAROHA A K. Electrocoagulation for the treatment of textile industry effluent-A review［J］. Journal of Environmental Management，2013，128（15）：949-963. doi:10.1016/j.jenvman.2013.06.043
10	张以忱，钱炯，左继成，等. 电絮凝水处理技术阳极优化的研究［J］. 工业水处理，2007，27（3）：4-6. doi:10.3969/j.issn.1005-829X.2007.03.002
	ZHANG Yichen， QIAN Jiong， ZUO Jicheng，et al. Study on the anode optimization of electrocoagulation water treatment［J］. Industrial Water Treatment，2007，27（3）：4-6. doi:10.3969/j.issn.1005-829X.2007.03.002
11	MARKUS I， NAEL Y， EDWARD P L R. Electrode passivation，faradaic efficiency，and performance enhancement strategies in electro⁃coagulation-A review［J］. Water Research，2020，187：116433. doi:10.1016/j.watres.2020.116433
12	EDZWARD J K， TOBIASON J E. Enhanced versus optimized multiple objective coagulation［C］//Chemical Water and Wastewater Treatment Ⅴ. New York：Springer Berlin Heidelberg，1998：113-124. doi:10.1007/978-3-642-72279-0_10
13	EDZWARD J K， TOBIASON J E. Enhanced coagulation：US requirement and a broader view［J］. Water Science & Technology，1999，40（9）：63-70. doi:10.2166/wst.1999.0444
14	王东升，刘海龙，晏明全，等. 强化混凝与优化混凝：必要性、研究进展和发展方向［J］. 环境科学学报，2006，26（4）：544-551. doi:10.3321/j.issn:0253-2468.2006.04.002
	WANG Dongsheng， LIU Hailong， YAN Mingquan，et al. Enhanced coagulation vs optimized coagulation： A critical review［J］. Acta Scientiae Circumstantiae，2006，26（4）：544-551. doi:10.3321/j.issn:0253-2468.2006.04.002
15	SAHSET I， DEMIRCIOGLU N， YILDIZ Y S，et al. The effects of current density and phosphate concentration on phosphate removal from wastewater by electrocoagulation using aluminum and iron plate electrodes［J］. Journal of Hazardous Materials，2006，52（2）：218-223. doi:10.1016/j.seppur.2006.04.008
16	KOBYA M， BAYRAMOGLU M， EYVAZ M. Techno⁃economical evaluation of electrocoagulation for the textile wastewater using different electrode connections［J］. Journal of Hazardous Materials，2007，148（1/2）：311-318. doi:10.1016/j.jhazmat.2007.02.036
17	KILANY A Y， NOSIER S A， HUSSEIN M，et al. Combined oil demulsification and copper removal from copper plating plant effluents by electrocoagulation in a new cell design［J］. Separation and Purification Technology，2020，248：117056. doi:10.1016/j.seppur.2020.117056
18	SERGIO P C， MARCEL J G， LORENA B B T，et al. Optimization of electrocoagulation process for disperse and reactive dyes using the response surface method with reuse application［J］. Journal of Cleaner Production，2020，275：122690. doi:10.1016/j.jclepro.2020.122690
19	LACASA E， CANIZARES P， SAEZ C，et al. Removal of nitrates from groundwater by electrocoagulation［J］. Chemical Engineering Journal，2011，171（3）：1012-1017. doi:10.1016/j.cej.2011.04.053
20	AL⁃SANNAG M， AL⁃QODAH Z， BANI⁃MELHEM K，et al. Heavy metal ions removal from metal plating wastewater using electrocoagulation：Kinetic study and process performance［J］. Chemical Engineering Journal，2015，260：749-756. doi:10.1016/j.cej.2014.09.035
21	HEFFRON J， RYAN D R， MAYER B K. Sequential electrocoagulation⁃electrooxidation for virus mitigation in drinking water［J］. Water Research，2019，160（1）：435-444. doi:10.1016/j.watres.2019.05.078
22	MEUNIER N， DROGUI P， MONTANE C，et al. Comparison between electrocoagulation and chemical precipitation for metals removal from acidic soil leachate［J］. Journal of Hazardous Materials，2006，137（1）：581-590. doi:10.1016/j.jhazmat.2006.02.050
23	EL⁃ASHTOUKHY E S Z， AMIN N K. Removal of acid green dye 50 from wastewater by anodic oxidation and electrocoagulation-A comparative study［J］. Journal of Hazardous Materials，2010，179（1/2/3）：113-119. doi:10.1016/j.jhazmat.2010.02.066
24	ABDURRAHMAN A，CAN O T， DEMIRBAS E，et al. A comparative study of electrocoagulation and electro⁃Fenton for treatment of wastewater from liquid organic fertilizer plant［J］. Separation & Purification Technology，2013，112：11-19. doi:10.1016/j.seppur.2013.03.036
25	BRUGUERA⁃CAASSADA C， ARAUJO R M， BRILLAS E，et al. Advantages of electro⁃Fenton over electrocoagulation for disinfection of dairy wastewater［J］. Chemical Engineering Journal，2019，376：119975. doi:10.1016/j.cej.2018.09.136
26	SONG Peipei， YANG Zhaohui， ZENG Guangming，et al. Electrocoagulation treatment of arsenic in wastewaters：A comprehensive review［J］. Chemical Engineering Journal，2017，317：707-725. doi:10.1016/j.cej.2017.02.086
27	AN Chunjiang， HUANG Gordon， YAO Yao，et al. Emerging usage of electrocoagulation technology for oil removal from wastewater：A review［J］. Science of the Total Environment，2017，579：537-556. doi:10.1016/j.scitotenv.2016.11.062
28	EMAMJOMEH M M， SIVAKUMAR M. Review of pollutants removed by electrocoagulation and electrocoagulation/flotation processes［J］. Journal of Environmental Management，2009，90（5）：1663-1679. doi:10.1016/j.jenvman.2008.12.011
29	KHOSLA N K， VENKATACHALAM S， SOMASUNDARAN P. Pu⁃lsed electrogenearation of bubbles for electroflotation［J］. Journal of Applied Electrochemistry，1991，21（11）：986-990. doi:10.1007/bf01077584
30	NOERSKOV J K， BLIGAARD T， LOGADOTTIR A，et al. Trends in the exchange current for hydrogen evolution［J］. Journal of the Electrochemical Society，2005，152（3）：23-26. doi:10.1149/1.1856988
31	李静波. 电絮凝-微滤（EC-EF）深度处理饮用水的研究［D］. 北京：北京林业大学，2007.
	LI Jingbo. Study on advanced treatment in drinking water by electrocoagulation⁃microfiltration（EC-EF）process［D］. Beijing： Beijing Forestry University，2007.
32	林辉. 脉冲电絮凝处理餐饮废水的研究［D］. 武汉：武汉大学，2004.
	LIN Hui. Study on pulsed current electrocoagulation for restaurant wastewater treatment［D］. Wuhan： Wuhan University，2004.
33	宋佩佩. 电絮凝技术处理砷锑废水机理及多物理场数值模拟的研究［D］. 长沙：湖南大学，2017. doi:10.1016/j.jenvman.2018.09.001
	SONG Peipei. Mechanism study and numerical simulation of multiphysics involved in electrocoagulation process for arsenic and antimony removal from wastewaters［D］. Changsha： Hunan University，2017. doi:10.1016/j.jenvman.2018.09.001
34	HAKIZIMANA J N， GOURICH B， CHAFI M，et al. Electrocoagulation process in water treatment：A review of electrocoagulation modeling approaches［J］. Desalination，2017，404：1-21. doi:10.1016/j.desal.2016.10.011
35	MCBEATH S T， NOURI⁃KHORASANI A，MOHSENIM，et al. In⁃situ determination of current density distribution and fluid modeling of an electrocoagulation process and its effects on natural organic matter removal for drinking water treatment［J］. Water Research，2020，171：115404. doi:10.1016/j.watres.2019.115404
36	GHERNAOUT D. Advanced oxidation phenomena in electrocoagulation process：A myth or a reality？［J］. Desalination & Water Treatment，2013，51（40/41/42）：7536-7554. doi:10.1080/19443994.2013.792520
37	BARAN W， ADAMEK E， JAJKO M，et al. Removal of veterinary antibiotics from wastewater by electrocoagulation［J］. Chemosp⁃here，2018，194：381-389. doi:10.1016/j.chemosphere.2017.11.165
38	高雪，吕建波，苏润西，等. 电絮凝法去除水中四环素的效能及机理［J］. 环境工程学报，2019，13（4）：826-834. doi:10.12030/j.cjee.201810006
	GAO Xue， Jianbo LÜ， Su Runxi，et al. Performance and mechanism of electrocoagulation process for tetracycline removal from water［J］. Chinese Journal of Environmental Engineering，2019，13（4）：826-834. doi:10.12030/j.cjee.201810006
39	张严，魏桃员，符文晶，等. 铁电絮凝产羟基自由基氧化降解地下水中磺胺［J］. 环境工程学报，2019，13（4）：871-877.
	ZHANG Yan， WEI Taoyuan， FU Wenjing，et al. Hydroxyl radical induced by iron electrocoagulation for oxidative degradation of sulfonamide in groundwater［J］. Chinese Journal of Environmental Engineering，2019，13（4）：871-877.
40	钱傲. 电化学水处理体系在特定条件下对污染物的转化新机理［D］. 武汉：中国地质大学，2019.
	QIAN Ao. New mechanisms of contaminants transformation by electrochemical water treatment systems under specific conditions［D］. Wuhan：China University of Geosciences，2019.
41	QUE N H， KAWAMURA Y， WATARI T，et al. Nanosecond pulse used to enhance the electrocoagulation of municipal wastewater treatment with low specific energy consumption［J］. Environmental Technology，2019，42（14）：1-9. doi:10.1080/09593330.2019.1694082
42	王瑶. 脉冲电絮凝处理农村含氟和砷饮用水源水的效能研究［D］. 哈尔滨：哈尔滨工业大学，2019. doi:10.29252/jafm.13.02.30272
	WANG Yao. Study on the efficiency of pulsed electric flocculation for treatment of rural fluoride and arsenite drinking water source water［D］. Harbin： Harbin Institute of Technology，2019. doi:10.29252/jafm.13.02.30272
43	周义文，周义斌，陈丽雯，等. 高压脉冲电絮凝技术在工业废水处理中的应用［J］. 中国环保产业，2016（6）：16-19. doi:10.3969/j.issn.1006-5377.2016.06.004
	ZHOU Yiwen， ZHOU Yibin， CHEN Liwen，et al. Application of high voltage，pulse and electrocoagulation technology in industrial effluent treatment［J］. China Environmental Protection Industry，2016（6）：16-19. doi:10.3969/j.issn.1006-5377.2016.06.004
44	徐国仁，沈天，马莹莹，等. 高压脉冲电凝技术处理化学镀镍废水［J］. 电镀与涂饰，2017，36（23）：1284-1287. doi:10.19289/j.1004-227x.2017.23.009
	XU Guoren， SHEN Tian， MA Yingying，et al. Treatment of wastewater discharged from electrodes nickel plating process by high⁃voltage pulsed electrocoagulation［J］. Electroplating & Finishing，2017，36（23）：1284-1287. doi:10.19289/j.1004-227x.2017.23.009
45	徐国仁，颜真，江博涵. 高压脉冲电絮凝和交变电场水处理技术在电镀企业水资源管理中的应用［J］. 电镀与涂饰，2017，36（4）：216-219.
	XU Guoren， YAN Zhen， JIANG Bohan. Application of high⁃voltage pulsed electrocoagulation and alternating electric field water treatment techniques in water resource management of electroplating plant ［J］. Electroplating & Finishing，2017，36（4）：216-219.
46	VALERO D， ORITZ J M， EDUARDO E，et al. Electrocoagulation of a synthetic textile effluent powered by photovoltaic energy without batteries：Direct connection behaviour［J］. Solar Energy Materials & Solar Cells，2008，92（3）：291-297. doi:10.1016/j.solmat.2007.09.006
47	李俊聪，黄尚雄，吴东亮，等. 电絮凝法去除新农村微污染水体中磷的研究［J］. 广东化工，2012，39（11）：147-148. doi:10.3969/j.issn.1007-1865.2012.11.078
	LI Juncong， HUANG Shangxiong， WU Dongliang，et al. Removal phosphorus from new rural micro⁃contamination water body by electrocoagulation［J］. Guangdong Chemical Industry，2012，39（11）：147-148. doi:10.3969/j.issn.1007-1865.2012.11.078
48	ZHANG Shunxi， YANG Xiaohong， CHENG Qunpeng，et al. Treatment of wastewater containing nickel by electrocoagulation process using photovoltaic energy［J］. Environmental Engineering Science，2017，35（5）：484-492. doi:10.1089/ees.2016.0621
49	王宇航，黄秋阳，卫治安，等. 关于太阳能耦合电絮凝处理沿海油库含油污水的研究［J］. 中国水运，2017，17（8）：173-174.
	WANG Yuhang， HUANG Qiuyang， WEI Zhian，et al. Study on the treatment of oily wastewater from coastal oil depots by solar energy coupled electrocoagulation［J］. China Water Transport，2017，17（8）：173-174.
50	MAITLO H A， KIM J H， KIM K H，et al. Metal⁃air fuel cell electrocoagulation techniques for the treatment of arsenic in water［J］. Journal of Cleaner Production，2019，207：67-84. doi:10.1016/j.jclepro.2018.09.232
51	田雨时. 空气阴极电絮凝系统优化及对污水中林的去除效能研究［D］. 哈尔滨：哈尔滨工业大学，2018.
	TIAN Yushi. Optimization of air⁃cathode electrocoagulation system and removal efficiency of phosphorus in sewage［D］. Harbin： Harbin Institute of Technology，2018.
52	SI Yanxiao， LI Guanghe， ZHANG Fang，et al. Energy⁃efficient oxidation and removal of arsenite from groundwater using air⁃cathode iron electrocoagulation［J］. Environmental Science & Technology Letters，2017，4（2）：71-75. doi:10.1021/acs.estlett.6b00430
53	QI Zhenlian， YOU Shijie， REN Nanqi. Wireless electrocoagulation in water treatment based on bipolar electrochemistry［J］. Electrochimica Acta，2017，229：96-101. doi:10.1016/j.electacta.2017.01.151
54	QI Zhenlian， ZHANG Jinna， YOU Shijie. Effect of placement angles on wireless electrocoagulation for bipolar aluminum electrodes［J］. Frontiers of Environmental Science & Engineering，2018，12（3）：9. doi:10.1007/s11783-018-1034-y
55	LEE S Y， GAGNON G A. Review of the factors relevant to the design and operation of an electrocoagulation system for wastewater treatment［J］. Environmental Reviews，2014，22（28）：421-429. doi:10.1139/er-2014-0009
56	FAJARDO A S， RODRIGUES R F， MARTINS R C，et al. Phenolic wastewaters treatment by electrocoagulation process using Zn anode［J］. Chemical Engineering Journal，2015，275：331-341. doi:10.1016/j.cej.2015.03.116
57	EL⁃GHENYMY A， ALSHEYAB M， KHODARY A，et al. Corrosion behavior of pure titanium anodes in saline medium and their performance for humic acid removal by electrocoagulation［J］. Chemosphere，2020，246：125674. doi:10.1016/j.chemosphere.2019.125674
58	OUMAR D， PATRICK D， GERARDO B，et al. Coupling biofiltration process and electrocoagulation using magnesium⁃based anode for the treatment of landfill leachate［J］. Journal of Environmental Management，2016，181：477-483. doi:10.1016/j.jenvman.2016.06.067
59	SAFWAT M S， AHMED H， EHAB R. Electrocoagulation/electroflotation of real printing wastewater using copper electrodes：A comparative study with aluminum electrodes［J］. Separation Science & Technology，2019，54（1）：183-194. doi:10.1080/01496395.2018.1494744
60	SHON H K， PHUNTSHO S， VIGNESWRAN S，et al. Preparation of titanium dioxide nanoparticles from electrocoagulated sludge using sacrificial titanium electrodes［J］. Environmental Science & Technology，2010，44（14）：5553-5557. doi:10.1021/es100333s
61	ADELAIDE D， CARMEL B B. The removal of phosphates using electrocoagulation with Al-Mg anodes［J］. Journal of Electroanalytical Chemistry，2019，846：113161. doi:10.1016/j.jelechem.2019.05.043
62	EL⁃ASHTOUKHY E S Z， ZEWAIL T M， AMIN N K. Removal of heavy metal ions from aqueous solution by electrocoagulation using a horizontal expanded Al anode［J］. Desalination & Water Treatment，2010，20（1/2/3）：72-79. doi:10.5004/dwt.2010.1127
63	YE Xiaokun， ZHANG Junya， ZHANG Yan，et al. Treatment of Ni-EDTA containing wastewater by electrocoagulation using iron scraps packed-bed anode［J］. Chemosphere，2016，164：304-313. doi:10.1016/j.chemosphere.2016.08.043
64	RAOUL T S， DARCHEN A. Investigation and optimization of a new electrocoagulation reactor with horizontal bipolar electrodes：Effect of electrode structure on the reactor performances［J］. Journal of Environmental Chemical Engineering，2018，6（4）：4546-4554. doi:10.1016/j.jece.2018.06.044
65	UN U T， KOPARAL A S， BAKIR O U. Fluoride removal from water and wastewater with a bach cylindrical electrode using electrocoagulation［J］. Chemical Engineering Journal，2013，223：110-115. doi:10.1016/j.cej.2013.02.126
66	NAJE A S， AJEEL M A， MAHDI R I，et al. Enhancement of ionic mass transfer coefficient using a unique electrocoagulation reactor with rotating impeller anode［J］. Separation Science & Technology，2019，55（6）：1167-1176. doi:10.1080/01496395.2019.1585875
67	AVANCINI D O， PERINI M E， SERGIO D S P P. Electrocoagulation using perforated electrodes：An increase in metalworking fluid removal from wastewater［J］. Chemical Engineering & Processing-Process Intensification，2019，139：113-120. doi:10.1016/j.cep.2019.03.021
68	NARAYANAN N V， GANESAN M. Use of adsorption using granular activated carbon（GAC） for the enhancement of removal of chromium from synthetic wastewater by electrocoagulation［J］. Journal of Hazardous Materials，2009，161（1）：575-580. doi:10.1016/j.jhazmat.2008.03.113
69	MALAKOOTIAN M， MANSOORIAN H J， MOOSAZADEH M. Performance evaluation of electrocoagulation process using iron⁃rod electrodes for removing hardness from drinking water［J］. Desalination，2010，255（1/2/3）：67-71. doi:10.1016/j.desal.2010.01.015
70	NAJE A S， CHELLIAPAN S， ZAKARIA Z，et al. Electrocoagulation by solar energy feed for textile wastewater treatment including mechanism and hydrogen production using a novel reactor design with a rotating anode［J］. RSC Advance，2016，6（12）：10192-10204. doi:10.1039/c5ra26032a
71	LI Jiangping， SONG Chen， SU Yixin，et al. A study on influential factors of high⁃phosphorus wastewater treated by electrocoagulation⁃ultrasound［J］. Environmental Science & Pollution Research International，2013，20（8）：5397-5404. doi:10.1007/s11356-013-1537-9
72	俞晟. 超声-电絮凝联合处理高磷改性酯化淀粉废水［J］. 苏州市职业大学学报，2019，30（3）：39-45.
	YU Sheng. Treatments of electrocoagulation with ultrasonic on wa⁃stewater of esterized starch containing high phosphorus content［J］. Journal of Suzhou Vocational University，2019，30（3）：39-45.
73	HERNANDEZ O M， PONZIAK T， BARRERA D C，et al. Use of a combined electrocoagulation⁃ozone process as a pre⁃treatment for industrial wastewater［J］. Desalination，2010，250（1）：144-149. doi:10.1016/j.desal.2008.11.021
74	何志桥，裘建平，宋爽，等. 臭氧强化电絮凝处理直接耐晒大红4BS模拟染料废水［J］. 化工学报，2007，58（10）：159-165. doi:10.3321/j.issn:0438-1157.2007.10.027
	HE Zhiqiao， QIU Jianping， SONG Shuang，et al. Ozonation⁃enhanced electrocoagulation for removal of C.I. Direct Red 23 in aqueous solution ［J］. Journal of Chemical Industry and Engineering （China），2007，58（10）：159-165. doi:10.3321/j.issn:0438-1157.2007.10.027
75	ASAITHAMBI P， SUSREE M， SARAVNATHAMIZHAN R，et al. Ozone assisted electrocoagulation for the treatment of distillery effluent［J］. Desalination，2012，297：1-7. doi:10.1016/j.desal.2012.04.011
76	LIANG Sheng， ZHENG Wenxiao， ZHU Liuyi，et al. One⁃step treatment of phosphite⁃laden wastewater：A single electrochemical reactor integrating superoxide radical⁃induced oxidation and electrocoagulation［J］. Environmental Science & Technology，2019，53（9）：5328-5336. doi:10.1021/acs.est.9b00841
77	HEFFRON J， RYAN D R， MAYER B K. Sequential electrocoagulation⁃electrooxidation for virus mitigation in drinking water［J］. Water Reaearch，2019，160：435-444. doi:10.1016/j.watres.2019.05.078
78	BOROSKI M， RODRIGUES A C， GARCIAB J C，et al. Combined electrocoagulation and TiO₂ photoassisted treatment applied to wastewater effluents from pharmaceutical and cosmetic industries［J］. Journal of Hazardous Materials，2009，162（1）：448-454. doi:10.1016/j.jhazmat.2008.05.062
79	王祎涵，明月. EC-MBR一体式反应器处理生活污水的试验研究［J］. 节能，2019，38（12）：153-156.
	WANG Yihan， MING Yue. Experimental study on treatment of domestic sewage in EC⁃MBR integrated reactor［J］. Energy Conservation，2019，38（12）：153-156.
80	BANI⁃MELHEM K， SMITH E. Grey water treatment by a continuous process of an electrocoagulation unit and a submerged membrane bioreactor system［J］. Chemical Engineering Journal，2012，198/199：201-210. doi:10.1016/j.cej.2012.05.065

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