工业水处理 ›› 2024, Vol. 44 ›› Issue (3): 184-189. doi: 10.19965/j.cnki.iwt.2023-0203

• 工程实例 • 上一篇    下一篇

内循环脱氮反应器处理炼化反渗透浓水的工程应用

陆彩霞1(), 尉勇2, 赵剑涛2, 师晓光1, 刘来峰2, 邢哲1, 谢陈鑫1, 王连峰1   

  1. 1. 中海油天津化工研究设计院有限公司, 天津 300131
    2. 中国石油天然气股份有限公司长庆石化分公司, 陕西 咸阳 712000
  • 收稿日期:2023-12-20 出版日期:2024-03-20 发布日期:2024-03-21
  • 作者简介:

    陆彩霞(1982— ),博士,高级工程师。E-mail:

  • 基金资助:
    中国海洋石油集团有限公司科技项目(CNOOC-KJ 135 ZDXM 33 TJY 003-2018)

Engineering application of internal circulation denitrification reactor for reverse osmosis concentrated water treatment

Caixia LU1(), Yong WEI2, Jiantao ZHAO2, Xiaoguang SHI1, Laifeng LIU2, Zhe XING1, Chenxin XIE1, Lianfeng WANG1   

  1. 1. CenerTech Tianjin Chemical Research and Design Institute Co. , Ltd. , Tianjin 300131, China
    2. PetroChina Changqing Petrochemical Company, Xianyang 712000, China
  • Received:2023-12-20 Online:2024-03-20 Published:2024-03-21

摘要:

在内循环(Internal circulation,IC)厌氧反应器结构基础上,设计了IC脱氮反应器,并研究了其在炼化反渗透浓水处理中的工程应用。结果表明,IC脱氮反应器启动快、运行稳定。在进水TN为18.7~39.0 mg/L,平均26.6 mg/L条件下,经IC脱氮反应器处理后出水TN为1.89~14.0 mg/L,平均4.65 mg/L,显著低于《陕西省黄河流域污水综合排放标准》(DB 61/224—2018)表1中B标准对于TN≤15 mg/L的排放要求;出水悬浮物质量浓度低,平均为18.6 mg/L;后续内循环曝气生物滤池出水COD平均为35.4 mg/L,可稳定控制在50 mg/L以下,综合处理效果好。同时,该设备占地面积小,工艺简单,水处理直接成本为1.36元/m3,具有显著的经济效益。

关键词: 内循环, 脱氮反应器, 反渗透浓水

Abstract:

Internal circulation(IC) denitrification reactor was designed on the basis of IC anaerobic reactor,and the engineering application was investigated for the reverse osmosis concentrated water treatment. The results showed that the IC denitrification reactor exhibited a rapid start and stable running. The effluent TN ranged from 1.89 mg/L to 14.0 mg/L with an average of 4.65 mg/L when the influent TN were from 18.7 mg/L to 39.0 mg/L with an average of 26.6 mg/L,which was lower than the required 15 mg/L by Standard B of Table1 in Comprehensive Wastewater Discharge Standards for the Yellow River Basin in Shanxi Province(DB 61/224-2018). The effluent suspended solids mass concentration was lower with an average mass concentration of 18.6 mg/L,and the effluent COD of the subsequent recirculation biofilter was 35.4 mg/L,stably controlled below 50 mg/L,which showed a perfect comprehensive treatment effect. Moreover,the IC denitrification reactor had a small footprint,simple process,and a direct water treatment cost of 1.36 yuan/m3,which had significant economic benefits.

Key words: internal circulation, denitrification reactor, reverse osmosis concentrated water

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