工业水处理 ›› 2025, Vol. 45 ›› Issue (1): 179-185. doi: 10.19965/j.cnki.iwt.2024-0313

• 经验交流 • 上一篇    下一篇

某燃煤电厂新型脱硫废水处理系统的调试与分析

刘贵栋1,2(), 胡阳阳3, 王璟2, 陈阳2, 王志勇4, 党雨露5, 徐浩1()   

  1. 1. 西安交通大学能源与动力工程学院,陕西 西安 710049
    2. 西安西热水务环保有限公司高效灵活 煤电及碳捕集利用封存全国重点实验室,陕西 西安 710054
    3. 陕西煤业化工技术研究院 有限责任公司,陕西 西安 710100
    4. 华能长江环保科技有限公司,北京 102209
    5. 西安益通热工技术服务有限责任公司,陕西 西安 710054
  • 收稿日期:2024-11-22 出版日期:2025-01-20 发布日期:2025-01-22
  • 作者简介:

    刘贵栋(1994— ),硕士,中级工程师。E-mail:

    徐浩,教授,博导。E-mail:

  • 基金资助:
    国家自然科学基金项目(52270078)

Commissioning and analysis of new desulfurization wastewater treatment system in a coal-fired power plant

Guidong LIU1,2(), Yangyang HU3, Jing WANG2, Yang CHEN2, Zhiyong WANG4, Yulu DANG5, Hao XU1()   

  1. 1. School of Energy and Power Engineering, Xi’an Jiaotong University, Xi’an 710049, China
    2. State Key Laboratory of High-Efficiency Flexible Coal Power Generation and Carbon Capture Utilization and Storage, Xi’an TPRI Water Management & Environment Protection Co. , Ltd. , Xi’an 710054, China
    3. Shanxi Coal Chemical Industry Technology Research Institute Co. , Ltd. , Xi’an 710100, China
    4. Huaneng Changjiang Envirironment & Technology Co. , Ltd. , Beijing 102209, China
    5. Xi’an Yitong Thermal Technical Service Co. , Ltd. , Xi’an 710054, China
  • Received:2024-11-22 Online:2025-01-20 Published:2025-01-22

摘要:

以山东某燃煤电厂脱硫废水改造项目为背景,采用一体式高效澄清工艺替换原有三联箱工艺,处理SS高达13 650 mg/L、CODCr为350 mg/L、重金属离子浓度超标的脱硫废水。处理前,先通过实验室小试确定基础加药量,缩小调试期间加药量范围;然后通过现场设备调试,优化运行参数,降低设备损坏率。经168 h的调试运行,新型脱硫废水处理系统运行稳定,污染物去除效果良好,出水SS在1.5 mg/L,CODCr在132.2 mg/L,总铅、总镉、总汞、总铬、总锌分别在0.14、0.01、0.01、1.04、1.24 mg/L,出水水质满足《火电厂石灰石-石膏湿法脱硫废水水质控制指标》(DL/T 997—2020)要求。与电厂原三联箱工艺相比,一体式高效澄清工艺不仅对水质有明显提升,而且年运行费用由100多万元降低至50多万元,经济效益显著。

关键词: 燃煤电厂, 脱硫废水, 一体式高效澄清装置, 调试

Abstract:

In a desulfurization wastewater renovation project of a coal-fired power plant in Shandong Province, the original triple-tank process was replaced by integrated high efficiency clarification process to treat the desulfurization wastewater, with suspended solids of 13 650 mg/L, CODCr of 350 mg/L and heavy metal ion concentration exceeding the standard. The basic chemical dosage could be determined by laboratory test. By on-site equipment joint adjustment, the operating parameters could be optimized and equipment damage rate could be reduced. After 168 h commissioning and running, the new process of desulfurization wastewater system was stable and effective. The effluent SS was 1.5 mg/L, CODCr was 132.2 mg/L, total lead, total cadmium, total mercury, total chromium, and total zinc were 0.14, 0.01, 0.01, 1.04, and 1.24 mg/L, respectively. The effluent quality could meet the relevant indicators of the Discharge Standard of Wastewater from Limestone-Gypsum Flue Gas Desulfurization System in Fossil Fuel Power Plants (DL/T 997-2020). Compared with the original triple-tank process in power plants, the integrated high-efficiency clarification process not only significantly improved water quality, but also reduced annual operating costs from over 1 million yuan to over 0.5 million yuan, with significant economic effects.

Key words: coal-fired power plant, desulfurization wastewater, integrated high efficiency clarification equipment, commissioning

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