工业水处理 ›› 2002, Vol. 22 ›› Issue (12): 29-31. doi: 10.11894/1005-829x.2002.22(12).29

• 试验研究 • 上一篇    下一篇

臭氧与Cr(Ⅵ)协同缓蚀作用的研究

王业耀1, 王占生2   

  1. 1. 中国环境科学研究院, 北京 100012;
    2. 清华大学环境科学与工程系, 北京 100084
  • 收稿日期:2002-02-26 出版日期:2002-12-20 发布日期:2010-10-01
  • 作者简介:王业耀(1965- ),1995年9月毕业于清华大学环境工程系,博士,现就职于中国环境科学研究院环境生物工程实验室,副研究员.电话:010-84915176,E-mail:yeyaowang@yahoo.com;yeyaowang@263.net.

Study on synergistic corrosion-inhibition between ozone and Cr(Ⅵ )

WANG Yeyao1, WANG Zhansheng2   

  1. 1. Chinese Research Academy of Environmental Sciences, Beijing 100012, China;
    2. Dept. of Environmental Sci. and Eng., Tsinghua University, Beijing 100084, China
  • Received:2002-02-26 Online:2002-12-20 Published:2010-10-01

摘要:

研究了碳钢在臭氧和Cr(Ⅵ)溶液中的腐蚀速率。试验结果表明,臭氧和Cr(Ⅵ)具有良好的协同缓蚀作用。这种协同缓蚀作用与臭氧质量浓度和Cr(Ⅵ)质量浓度有关,Cr(Ⅵ)质量浓度升高,协同缓蚀效果提高;协同缓蚀作用的最佳臭氧质量浓度范围为0。05~0。1mgL。在最佳臭氧质量浓度范围内,当Cr(Ⅵ)为2。5~5。0mgL时,碳钢可以取得较好的缓蚀效果。采用铬酸盐对碳钢进行预膜,可以有效提高臭氧与Cr(Ⅵ)的协同缓蚀效果。

关键词: 臭氧, Cr(Ⅵ), 协同缓蚀作用

Abstract:

The corrosion rates of carbon-steel in ozone and Cr(Ⅵ )solutions are primarily investigated.The experiments proves that ozone and Cr(Ⅵ )show excellent synergistic corrosion-inhibition.The synergism is affected by the concentrations of ozone and Cr(Ⅵ ).The corrosion rates decrease while the concentrations of Cr(Ⅵ )increase.The optimum range for ozone in aqueous solutions is 0.05 ~ 0.1mg L.Within the range,an excellent corrosion-inhibition for carbon-steel is achieved while Cr(Ⅵ )is 2.5 ~ 5.0 mg L.The synergistic corrosion-inhibition is improved greatly while the carbon-steel is pretreated by potassium chromate solutions.

Key words: ozone, chromium(Ⅵ ), synergistic corrosion-inhibition

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