INDUSTRIAL WATER TREATMENT ›› 2014, Vol. 34 ›› Issue (6): 36-39. doi: 10.11894/1005-829x.2014.34(6).036

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Experimental study on the treatment of paper-making wastewater with magnetic Fe3O4/chitosan composite microspheres

Zhang Wanyou1, Mi Tianpeng1, Pang Xiangrui2, Li Wenguo3, Zhang Lanhe1, Liu Jianhua1   

  1. 1. School of Chemical Engineering, Northeast Electric Power University, Jilin 132012, China;
    2. School of Environmental Engineering, Liaoning University, Shenyang 110036, China;
    3. Ethylene Plant, Jilin Petrochemical Co., Ltd., China Petroleum, Jilin 132012, China
  • Received:2014-02-25 Online:2014-06-20 Published:2014-07-05

磁性Fe3O4/壳聚糖复合微球处理造纸废水实验研究

张万友1, 米天朋1, 庞香蕊2, 李文国3, 张兰河1, 刘建华1   

  1. 1. 东北电力大学化学工程学院, 吉林 132012;
    2. 辽宁大学环境学院, 辽宁沈阳 110036;
    3. 中国石油吉林石化有限责任公司乙烯厂, 吉林 132012
  • 通讯作者: 张兰河,E-mail:zhanglanhe@163.com E-mail:zhanglanhe@163.com
  • 作者简介:张万友(1957-),教授。电话:13804419658
  • 基金资助:

    吉林省科技发展计划项目-社会发展重点项目(20110405);吉林省教育厅“十二五”科学技术研究项目(吉教科合字[2012]第95号);吉林省省校合作技术开发项目(吉工信科技2011-507)

Abstract: In order to improve the treatment effect of paper-making wastewater, magnetic Fe3O4/chitosan composite microspheres have been used as flocculant. After the Fe3O4 particles, which were prepared by hydrolysis method, have been dispersed in chitosan solution, magnetic Fe3O4/chitosan composite microspheres can be prepared. The effects of the dosage of magnetic Fe3O4/chitosan composite microspheres, pH, stirring speed and sedimentation time on COD removing rate of paper-making wastewater are investigated. The results show that the COD removing rate can reach 83.38%, under the following conditions:pH is 8, stirring speed 120 r/min, dosage of composite microspheres 6 mg/L, sedimentation time 8 h, and the influent COD of paper-making wastewater 2549.41 mg/L.

Key words: magnetic Fe3O4, chitosan, paper-making wastewater

摘要: 为了提高对造纸废水的处理效果,采用磁性Fe3O4/壳聚糖复合微球作为絮凝剂对其进行处理。将水解法制备的Fe3O4微粒分散于壳聚糖溶液中,制备成磁性Fe3O4/壳聚糖复合微球,考察了其投加量、pH、搅拌速度及沉降时间对造纸废水COD去除率的影响。结果表明,在pH为8,搅拌速度为120 r/min,复合微球投加量为6 mg/L,沉降时间为8 h的条件下,当进水COD为2549.41 mg/L时, COD去除率可达到83.38%。

关键词: 磁性Fe3O4, 壳聚糖, 造纸废水

CLC Number: