INDUSTRIAL WATER TREATMENT ›› 2018, Vol. 38 ›› Issue (12): 76-80. doi: 10.11894/1005-829x.2018.38(12).076

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Pretreatment of high-concentration lithium battery processing wastewater by Fenton-coagulation precipitation method

Guan Xijun, Qiu Mokai, Xia Lijia, Zhang Minghui, Chen Xiushuo, Liu Xiaoru, Tang Zhen   

  1. School of Environmental and Municipal Engineering, Qingdao University of Technology, Qingdao 266033, China
  • Received:2018-11-20 Online:2018-12-20 Published:2018-12-24

Fenton-混凝沉淀法预处理锂电池加工高浓度废水

管锡珺, 仇模凯, 夏丽佳, 张明辉, 陈修硕, 刘晓茹, 唐振   

  1. 青岛理工大学环境与市政工程学院, 山东青岛 266033
  • 通讯作者: 仇模凯,硕士研究生。E-mail:610948275@qq.com E-mail:610948275@qq.com
  • 作者简介:管锡珺(1964-),教授。E-mail:guanxj@qtech.edu.cn。

Abstract: Fenton-coagulation precipitation method has been used for treating the wastewater from lithium battery cover-board rinsing. The optimal reaction conditions of COD removal by Fenton-coagulation precipitation method have been investigated,and then the influence mechanisms of factors discussed. The results show that the removal rate of COD is 91.81%,at room temperature,in Fenton reaction stage,when the dosage of 30% H2O2 is 12.5 mL/L and the dosage of FeSO4·7H2O 4.0 g/L,pH=2.5 and reaction time 1 h. The effluent from Fenton reaction should be retreated by PAC coagulation sedimentation method. Under the following conditions:pH is neutral or slightly alkaline, and the dosage of PAC 80 mg/L,the removal rate of COD is 93.9%.

Key words: Fenton reagent, coagulation, precipitation, lithium battery processing wastewater

摘要: 采用Fenton-混凝沉淀法处理锂电池盖板冲洗废水,研究其最佳反应条件,并探讨各因素的影响机理。结果表明:室温条件下,在Fenton反应阶段,30% H2O2投加量为12.5 mL/L、FeSO4·7H2O投加量为4.0 g/L、pH为2.5、反应时间为1 h时,COD去除率可达91.81%;Fenton反应出水用PAC混凝沉淀法进行再处理,pH为中性或偏碱性、PAC投加量为80 mg/L条件下,最终出水COD去除率可达93.9%。

关键词: Fenton试剂, 混凝, 沉淀, 锂电池加工废水

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