Study on the flocculation capacity of QARBC-modified cationic acrylamine terpolymer

doi:10.11894/1005-829x.2014.34(9).044

INDUSTRIAL WATER TREATMENT ›› 2014, Vol. 34 ›› Issue (9): 44-46,50. doi: 10.11894/1005-829x.2014.34(9).044

Previous Articles Next Articles

Study on the flocculation capacity of QARBC-modified cationic acrylamine terpolymer

Wang Guixia^1,2, Kong Xiangfei^1,2

1. Guangxi Mining and Environmental Sciences Laboratory Center, Guilin 541004, China;
2. College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China

Received:2014-07-12 Online:2014-09-20 Published:2014-09-25

QARBC改性阳离子型丙烯酰胺三元共聚物的絮凝性能

王桂霞^1,2, 孔翔飞^1,2

1. 广西矿冶与环境科学实验中心, 广西桂林 541004;
2. 桂林理工大学化学与生物工程学院, 广西桂林 541004

通讯作者: 孔翔飞，博士，副教授。E-mail：xiangfei.kong@glut.edu.cn。 E-mail:xiangfei.kong@glut.edu.cn
作者简介:王桂霞（1976- ），博士，副教授。E-mail：2010033@glut.edu.cn。
基金资助:
桂林理工大学博士启动基金（KH2013ZD003）

Abstract

Abstract:

A series of surfmer QARBC-modified cationic acrylamine terpolymer have been prepared by ordinary solution copolymerization method. The flocculation tests on kaolin simulated wastewater system and the decoloration test on sun-set yellow dye system show that surfmer P(AM-DMC-QARBC) compared with ordinary cationic acrylamine copolymer P(AM-DMC) reflects better flocculation capability. The introduction of surfmer QARBC has raised the flocculation effect of P(AM-SMX-QARBC) on kaolin, and increased the removing rate of anion dye sun-set yellow.

Key words: solution polymerizaiton, surfmer, cationic, flocculation capability, removing rate

摘要：

采用普通溶液共聚合方法合成了一系列表活性单体QARBC改性的阳离子型丙烯酰胺三元共聚物P（AM-DMC-QARBC）。通过对高岭土模拟污水体系的絮凝实验和对日落黄染料体系的脱色实验表明：P（AM-DMC-QARBC）与普通的阳离子型丙烯酰胺共聚物P（AM-DMC）相比体现出很好的絮凝性能，表活性单体QARBC的引入改善了P（AM-DMC-QARBC）对高岭土的絮凝效果，提高了对阴离子染料日落黄的脱除率。

关键词: 溶液共聚合, 表活性单体, 阳离子型, 絮凝性能, 脱除率

CLC Number:

X703

Wang Guixia, Kong Xiangfei. Study on the flocculation capacity of QARBC-modified cationic acrylamine terpolymer[J]. INDUSTRIAL WATER TREATMENT, 2014, 34(9): 44-46,50.

王桂霞, 孔翔飞. QARBC改性阳离子型丙烯酰胺三元共聚物的絮凝性能[J]. 工业水处理, 2014, 34(9): 44-46,50.

/ / Recommend / Download Citations

URL: https://www.iwt.cn/EN/10.11894/1005-829x.2014.34(9).044

https://www.iwt.cn/EN/Y2014/V34/I9/44

References

[1] 刘明华. 有机高分子絮凝剂制备及应用[M]. 北京:化学工业出版社, 2006:43-78.
[2] 徐晓军. 化学絮凝剂作用原理[M]. 北京:科学出版社, 2005:13-19.
[3] Lu Guiqian, Wu Dingcai, Fu Ruowen. Studies on the synthesis and antibacterial activities of polymeric quaternary ammonium salts from dimethylaminoethyl methacrylate[J]. Reactive & Functional Polymers, 2007, 67(4):355-366.
[4] Candau F, Selb J. Hydrophobically-modified polyacrylamides prepared by micellar polymerization[J]. Advances in Colloid and Interface Science, 1999, 79(2/3):149-172.
[5] Wang Guixia, Zhang Yuxi, Wu Feipeng. A Series of cationic surfmers with benzyl group: synthesizing characterization and copolymerization with acrylamide[J]. Chinese Journal of Polymer Science, 2001, 29(3):352-359.
[6] GB 12005.1—1989 聚丙烯酰胺特性粘度测定方法[S].
[7] Biggs S, Hill A, Selb J, et al. Copolymerization of acrylamide and a hydrophobic monomer in an aqueous micellar medium:effect of the surfactant on the copolymer microstructure[J]. J. Phys. Chem., 1992, 96(3):1505-1511.
[8] Wang Jianping, Chen Yongzhen, Ge X W, et al. Gamma radiation-induced grafting of a cationic monomer onto chitosan as a flocculant[J]. Chemosphere, 2007, 66(9):1752-1757.
[9] 李殊静. 新型功能性环糊精包结络合物及高分子方面的应用[D]. 北京:中国科学院理化技术研究所, 2007.
[10] Kulicke W M, Kniewske R, Klein J. Preparation, characterization, solution properties and rheological behavior of polyacrylamide[J]. Prog. Polym. Sci., 1982(8):373-468.
[11] Río F, José R, Ochoa G. Synthesis of cationic flocculants based on acrylamide and[2-(acryloyloxy)ethyl]trimethylammonium chloride:copolymers by semicontinuous inverse microemulsion polymerization. Part Ⅲ:influence of HLB and surfactant blend concentration on flocculating performance[J]. e-Polymers, 2007(59):1-13.

[1]	Jinghao HUANG, Ying YANG, Xiaoyan HE, Xiang BAI. Adsorption performance of pyridine-based carbon nanocages for cationic dyes [J]. Industrial Water Treatment, 2022, 42(9): 109-116.
[2]	Jiao CHEN, Huan LIU, Haolin LIU, Huafeng LIN, Xiaoyuan LI, Yixin LU. Research progress on the adsorption property of biochar for cationic dyes [J]. Industrial Water Treatment, 2022, 42(8): 27-33.
[3]	Yizhi LIU, Xiantao ZHOU, Tong YANG. Study on improving sludge dewatering performance by combining biological shell powder with CPAM [J]. Industrial Water Treatment, 2022, 42(12): 154-159.
[4]	Dexi Zhao. Study on the treatment of oily sludge water with high-content cationic detergent [J]. Industrial Water Treatment, 2021, 41(5): 135-139.
[5]	Luming Zeng,Yongping Zhao,Yongcai Guo,Jing Wang. Application of nonionic water clarifier in Bohai L oilfield [J]. Industrial Water Treatment, 2021, 41(1): 122-125.
[6]	Cheng He,Yang Yu,Zhihuang Fang. Research on preparation and coagulation performance of PFS-CS composite coagulant [J]. Industrial Water Treatment, 2020, 40(10): 72-76.
[7]	Jiajun Li,Yu Qi. Synthesis and application of a water clarifier for oilfield [J]. Industrial Water Treatment, 2020, 40(1): 66-68.
[8]	Lingmin Cai,Xizi Luo,Min Zhou,Junhu Li,Lihua Zhang,Haitao Zhang. Research on CPAM and CPAM coupled with FeCl₃ for the improvement of sludge dewatering capability [J]. Industrial Water Treatment, 2019, 39(6): 81-85.
[9]	Wang Jiankun, Guo Jing, Zhang Hao, Fan Xinyu, Zheng Guo. Research on the adsorption capability of cross-linked cationic starch for reactive dyes [J]. INDUSTRIAL WATER TREATMENT, 2018, 38(6): 17-21.
[10]	Liu Xueqi, Zhou Hong, Mei Yongjun, Zhang Yuan, Cui Aijun, Gao Qiuyue. Research on the removal of thickeners from aircraft deicing wastewater with PAC/PI/PAM [J]. INDUSTRIAL WATER TREATMENT, 2018, 38(3): 77-80.
[11]	Ma Chao, Zhu Qianqian, Pan Minglei, Su Chao, Zhou Chao. Discussion on the flocculation effect of the temperature-sensitive polymer in thick oil wastewater [J]. INDUSTRIAL WATER TREATMENT, 2017, 37(5): 50-52,53.
[12]	Yuan Li, Chen Cheng, Zhao Xiaolei. Research on the flocculation decolorization effects of P(DMC-AM) on reactive dye wastewater [J]. INDUSTRIAL WATER TREATMENT, 2017, 37(11): 78-82.
[13]	Zheng Huaili, Shou Qianying, Li Xiang, Zhou Yuhao, Liu Bingzhi, Zhao Chuanliang, Jiang Jiaxian. Research progress in the polymerization and application of cationic polyacrylamide [J]. INDUSTRIAL WATER TREATMENT, 2016, 36(12): 12-15.
[14]	Wang Xuechuan, Pan Bo, Qiang Taotao, Zhang Feifei. Study on the application of cationic collagen flocculant to the improvement of sludge dewaterability [J]. INDUSTRIAL WATER TREATMENT, 2015, 35(7): 19-23.
[15]	Li Guoke, Geng Renyong, Cao Hui, Gao Xiaohan, Lü Xuechuan, Fan Zhiping. Research progress in cationic organic flocculants of quaternary ammonium salts [J]. INDUSTRIAL WATER TREATMENT, 2015, 35(11): 1-4.

Please choose a citation manager

Content to export

Study on the flocculation capacity of QARBC-modified cationic acrylamine terpolymer

QARBC改性阳离子型丙烯酰胺三元共聚物的絮凝性能

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

模态框（Modal）标题

Please choose a citation manager

Content to export

Study on the flocculation capacity of QARBC-modified cationic acrylamine terpolymer

QARBC改性阳离子型丙烯酰胺三元共聚物的絮凝性能

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments