INDUSTRIAL WATER TREATMENT ›› 2018, Vol. 38 ›› Issue (3): 25-29. doi: 10.11894/1005-829x.2018.38(3).025

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Research on the adsorption capability of iron-carbon co-precipitant for cadmium in water

Guan Yuli, Zhao Zhuanjun, Zhao Lifang, Zhang Zhaohu, Ben Hexin   

  1. College of Ecology and Environmental, Lanzhou University, Lanzhou 730000, China
  • Received:2017-11-13 Online:2018-03-20 Published:2018-04-17

碳铁共沉物对水中镉的吸附性能

管宇立, 赵转军, 赵立芳, 张兆虎, 贲贺新   

  1. 兰州大学环境与资源学院, 甘肃兰州 730000
  • 通讯作者: 赵转军,副教授,E-mail:zhj_zhao@lzu.edu.cn。 E-mail:zhj_zhao@lzu.edu.cn
  • 作者简介:管宇立(1993-),硕士。电话:18394420010,E-mail:guanyl15@lzu.edu.cn。
  • 基金资助:
    中央高校基本科研业务费专项资金(lzujbky-2015-144/223000—861952)

Abstract: Under laboratory conditions,ferrihydrite has been prepared,and humic acid-ferrihydrite co-precipitants prepared by adding humic acid in the synthetic process. Using the humic acid-ferrihydrite co-precipitants as adsorbing materials,the adsorption and desorption characteristics of the co-precipitants for Cd(Ⅱ) in water has been researched. The results show that under the best conditions,the maximum removing rate of Cd(Ⅱ) by the co-precipitants can reach 99.76%. The adsorption for Cd(Ⅱ) is relatively firm,and the adsorbed heavy metals are hard to be desorbed. The adsorption and desorption rules of co-precipitants for Cd(Ⅱ) in water can be described by Langmuir isotherm adsorption model,while the adsorption process complies with Lagergren second order kinetics equation.

Key words: ferrihydrite, humic acid, isothermal adsorption

摘要: 在实验室条件下制备水铁矿,并在合成过程中加入腐殖酸制得水铁矿-腐殖酸共沉物。以水铁矿-腐殖酸共沉物为吸附材料,研究其对水中镉的吸附-解吸特征。结果表明,最佳条件下,水铁矿-腐殖酸共沉物对镉的去除率最高可达99.76%;其对镉的吸附较为牢固,吸附后的重金属不易解吸;镉在水铁矿-腐殖酸共沉物上的吸附-解吸规律可用Langmuir等温吸附模型描述,吸附过程符合Lagergren二级动力学方程。

关键词: 水铁矿, 腐殖酸, 等温吸附

CLC Number: