Industrial Water Treatment ›› 2019, Vol. 39 ›› Issue (1): 110-112. doi: 10.11894/1005-829x.2019.39(1).110

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Application research on the reuse of deeply treated petrochemical wastewater

Xu Haibo1, Sun Jian2, Cheng Xin3, Shi Lei2   

  1. 1. CenerTech Tianjin Chemical Research and Design Institute Co., Ltd., Tianjin 300131, China;
    2. Acrylonitrile Plant of PetroChina Jilin Petrochemical Company, Jilin 132022, China;
    3. Daqing Petrochemical Corp., Heilongjiang 163714, China
  • Received:2018-11-24 Published:2019-01-30

石化废水深度处理回用的应用研究

徐海波1, 孙健2, 程鑫3, 施雷2   

  1. 1. 中海油天津化工研究设计院有限公司, 天津 300131;
    2. 中石油吉林石化公司丙烯腈厂, 吉林市 132022;
    3. 大庆石化公司, 黑龙江大庆 163714
  • 作者简介:徐海波(1978-),工程师。电话:022-26689359,E-mail:13920421190@126.com。

Abstract: The ozone oxidation+multimedium filter+UF+RO process has been used for the advanced treatment of biochemically treated wastewater in a wastewater workshop,and its treatment scale is 500 m3/h. The running results show that the membrane system works steadily,COD removing rate by ozone advanced oxidation is 67.0%,suspended solid removing rate by UF 83.3%,pollutant removing effect by RO is significant,electrical conductivity reduced to 86 μS/cm,hardness removing rate 98.1%, chlorine ion removing rate 95.1%, COD removing rate 98.3%, and total phosphorus, ammonia nitrogen and suspended solids are almost removed completely. Its effluent meets the second-level RO influent requirements.

Key words: petrochemical wastewater, ozone, ultra-fitration, reverse osmosis

摘要: 利用臭氧高级氧化+多介质过滤+超滤(UF)+反渗透(RO)工艺将污水车间已生化处理后的污水进行深度处理,处理规模为500 m3/h,运行结果表明:膜系统稳定,臭氧高级氧化对COD的去除率为67.0%,UF对悬浮物的去除率为83.3%,RO对污染物的去除效果显著,电导率降低至86 μS/cm,硬度去除率为98.1%,氯离子去除率为95.1%,COD去除率为98.3%,总磷、氨氮、悬浮物基本完全去除,出水达到了二级反渗透的进水要求。

关键词: 石化废水, 臭氧, 超滤, 反渗透

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