Construction of thiol-functionalized magnesium phyllosilicate contained nanocomposite and investigation of its catalytic reduction performance

doi:10.19965/j.cnki.iwt.2022-0796

Abstract

Key words: thiol-functionalized magnesium phyllosilicate, 4-nitrophenol, catalytic reduction

CLC Number:

X703.1

Beibei HE, Yuhuan YUAN, Rui LÜ. Construction of thiol-functionalized magnesium phyllosilicate contained nanocomposite and investigation of its catalytic reduction performance[J]. Industrial Water Treatment, 2023, 43(7): 70-77.

何贝贝, 袁玉环, 吕瑞. 巯基功能化镁层状硅酸盐复合材料的构筑及其催化还原性能研究[J]. 工业水处理, 2023, 43(7): 70-77.

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https://www.iwt.cn/EN/Y2023/V43/I7/70

Figures/Tables 6

Fig.1 Characterization of Fe₃O₄@MgSH/Ag and its related components

Fig.2 UV-vis spectra of the catalytic reduction systems

Fig. 3 Kinetics（a） and quasi first-order kinetic model fitting curve（b）of catalytic reduction of 4-NP by Fe₃O₄@MgSH/Ag

Table 1 Quasi first-order kinetic apparent rate constants of catalytic reduction of 4-NP with different catalysts

催化剂	k _app	参考文献
C-Pt NPs	0.03 min^-1	〔16〕
Au	0.126 min^-1	〔17〕
Ag-NP/C	0.101 min^-1	〔18〕
Pd/CS-2	0.138 min^-1	〔19〕
Pd	1.02×10^-3 s^-1	〔20〕
Pd NPs@black tea	5.9×10^-4 s^-1	〔21〕
Pt	1.98×10^-3 s^-1	〔22〕
Au/RGO	0.9×10^-3 s^-1	〔23〕
Fe₃O₄@MgSH/Ag	0.160 8 min^-1	本研究

Fig.4 The effect of each parameter in the catalytic reduction of 4-NP by Fe₃O₄@MgSH/Ag

Fig.5 Recyclability and stability of Fe₃O₄@MgSH/Ag

References 23

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