微波强化催化H<sub>2</sub>O<sub>2</sub>处理印染生化出水及有机物去除

doi:10.11894/iwt.2018-0773

工业水处理 ›› 2019, Vol. 39 ›› Issue (8): 65-68. doi: 10.11894/iwt.2018-0773

微波强化催化H₂O₂处理印染生化出水及有机物去除

章波(),姚立荣,程寒飞,仲鑫

中冶华天工程技术有限公司水环境技术研究院, 江苏南京 210019

收稿日期:2019-06-18 出版日期:2019-08-20 发布日期:2019-08-21
作者简介:章波(1984-),博士,工程师。电话:15895875397, E-mail:zhangbovivi@163.com
基金资助:
南京市科技计划(201805015);中华全国总工会职工创新补助资金(2017-1203)

Degradation of biochemical treated effluent of dyeing wastewater and its organics removal by microwave-enhanced catalytic H₂O₂

Bo Zhang(),Lirong Yao,Hanfei Cheng,Xin Zhong

Water Environmental Technology Research Institute, MCC Huatian Engineering & Technology Corporation, Nanjing 210019, China

Received:2019-06-18 Online:2019-08-20 Published:2019-08-21
Supported by:
南京市科技计划(201805015);中华全国总工会职工创新补助资金(2017-1203)

摘要/Abstract

摘要：

采用微波强化催化H₂O₂的组合工艺处理印染废水生化处理出水，考察微波功率、温度、H₂O₂投加量及pH对反应效果的影响。最佳反应条件：微波输出功率为500 W、温度60 ℃、H₂O₂浓度为0.095 mol/L、水力停留时间18 min，此时COD去除率为79.89%。此外，在最佳反应条件下，采用XAD-8/XAD-4树脂联用技术分析进出水中疏水酸、非酸疏水物质、弱疏水物质及亲水物质的去除情况，结果表明，微波强化催化H₂O₂能有效去除这4类物质。

关键词: 微波, H₂O₂, 印染废水, 高级氧化

Abstract:

The biochemical treated effluent of dyeing wastewater is degraded by microwave enhanced catalytic H₂O₂ combined process, and the influences of microwave power, temperature, H₂O₂ dosage and initial pH on the reaction are investigated. The optimal reaction conditions are as follows:microwave output power of 500 W, temperature of 60℃, H₂O₂ concentration of 0.095 mol/L and hydraulic retention time of 18 min, the COD removal rate could reach 79.89%. In addition, under the optimal reaction conditions, the removal of hydrophobic acid, non-acid hydrophobic substance, weak hydrophobic substance and hydrophilic substance in the influent and effluent is analyzed by XAD-8/XAD-4 resin combination technology. The results show that microwave-enhanced catalytic H₂O₂ could effectively remove these four kinds of substances.

Key words: microwave, H₂O₂, dyeing wastewater, advanced oxidation

中图分类号:

X703

章波,姚立荣,程寒飞,仲鑫. 微波强化催化H₂O₂处理印染生化出水及有机物去除[J]. 工业水处理, 2019, 39(8): 65-68.

Bo Zhang,Lirong Yao,Hanfei Cheng,Xin Zhong. Degradation of biochemical treated effluent of dyeing wastewater and its organics removal by microwave-enhanced catalytic H₂O₂[J]. Industrial Water Treatment, 2019, 39(8): 65-68.

https://www.iwt.cn/CN/Y2019/V39/I8/65

图/表 6

图1 反应器装置

图2 树脂联用对水中有机物的分离过程

图3 不同工艺对印染废水生化出水的去除效果

图4 温度对COD去除效果的影响

图5 微波功率对COD去除效果的影响

图6 H₂O₂投加量对COD去除效果的影响

参考文献 19

1	吴娜娜, 钱虹, 郑璐, 等. 超声强化三维电极/电-Fenton处理孔雀石绿印染废水[J]. 水处理技术, 2018, 44 (4): 116- 121. URL
2	Liew R K , Azwar E , Yek P N Y , et al. Microwave pyrolysis with KOH/NaOH mixture activation:A new approach to produce micro-mesopo-rous activated carbon for textile dye adsorption[J]. Bioresource Tech-nology, 2018, 266:1- 10. doi: 10.1016/j.biortech.2018.06.051
3	杨晶, 黄瑞敏, 谢春生, 等. 负载型纳米CuO/MnO₂催化剂的制备及催化氧化深度处理印染废水[J]. 环境工程学报, 2018, 12 (1): 34- 40. URL
4	李暮, 钱飞跃, 李欣珏, 等. 印染废水生化出水中有机污染物特性及在硫酸镁混凝过程中的去除行为[J]. 环境化学, 2012, 31 (1): 88- 93. URL
5	Zhang B , You H , Wang F , et al. Influence of nickel incorporation on the structure and catalytic behavior of Cu-catalyst for heterogeneous catalytic wet peroxide oxidation of quinoline under microwave irradia-tion[J]. Catalysis Communications, 2017, 88:56- 59. doi: 10.1016/j.catcom.2016.09.032
6	杨中喆.微波强化催化湿式H₂O₂氧化深度处理煤化工废水[D].哈尔滨:哈尔滨工业大学, 2016. URL
7	Kao C M , Chou M S , Fang W , et al. Regulating colored textile waste-water by 3/31 wavelength ADMI methods in Taiwan[J]. Chemosphere, 2001, 44 (5): 1055- 1063. doi: 10.1016/S0045-6535(00)00502-6
8	Zhang B , You H , Yang Z , et al. A highly active bimetallic oxide ca-talyst supported on γ-Al₂O₃/TiO₂ for catalytic wet peroxide oxidation of quinoline solutions under microwave irradiation[J]. RSC Advan-ces, 2016, 6 (70): 66027- 66036. doi: 10.1039/C6RA08576H
9	Zazo J A , Pliego G , García-Munoz P , et al. UV-LED assisted cataly-tic wet peroxide oxidation with a Fe(Ⅱ)-Fe(Ⅲ)/activated carbon catalyst[J]. Applied Catalysis B:Environmental, 2016, 192:350- 356. doi: 10.1016/j.apcatb.2016.04.010
10	Zhang B , You H , Wang F . Microwave-enhanced catalytic wet pero-xide oxidation of quinoline:the influence of pH and H₂O₂ dosage and identification of reactive oxygen species[J]. RSC Advances, 2017, 7 (24): 14769- 14775. doi: 10.1039/C7RA01350G
11	Zhang Z , Yu F , Huang L , et al. Confirmation of hydroxyl radicals (·OH) generated in the presence of TiO₂ supported on AC under microwave irradiation[J]. Journal of Hazardous Materials, 2014, 278:152- 157. doi: 10.1016/j.jhazmat.2014.05.064
12	Ahmed A B , Jibril B , Danwittayakul S , et al. Microwave-enhanced degradation of phenol over Ni-loaded ZnO nanorods catalyst[J]. Applied Catalysis B:Environmental, 2014, 156/157:456- 465. doi: 10.1016/j.apcatb.2014.03.032
13	Temel N K , Sokmen M . New catalyst systems for the degradation of chlorophenols[J]. Desalination, 2011, 281:209- 214. doi: 10.1016/j.desal.2011.07.066
14	Pan W , Zhang G , Zheng T , et al. Degradation of p-nitrophenol using CuO/Al₂O₃ as a Fenton-like catalyst under microwave irradiation[J]. RSC Advances, 2015, 5 (34): 27043- 27051. doi: 10.1039/C4RA14516J
15	Yan Y , Wu X , Zhang H . Catalytic wet peroxide oxidation of phenol over Fe₂O₃/MCM-41 in a fixed bed reactor[J]. Separation and Puri-fication Technology, 2016, 171:52- 61. doi: 10.1016/j.seppur.2016.06.047
16	Ye W , Zhao B , Gao H , et al. Preparation of highly efficient and stable Fe, Zn, Al-pillared montmorillonite as heterogeneous catalyst for ca-talytic wet peroxide oxidation of Orange Ⅱ[J]. Journal of Porous Materials, 2016, 23 (2): 301- 310. doi: 10.1007/s10934-015-0082-y
17	Georgi A , Velasco Polo M , Crincoli K , et al. Accelerated catalytic fenton reaction with traces of iron:an Fe-Pd-multicatalysis app-roach[J]. Environmental Science & Technology, 2016, 50 (11): 5882- 5891. URL
18	Zhao S , Duan Y , Tan H , et al. Migration and emission characteristi-cs of trace elements in a 660 MW coal-fired power plant of China[J]. Energy & Fuels, 2016, 30 (7): 5937- 5944. URL
19	Ge X , Wu Z , Wu Z , et al. Microwave-assisted modification of activa-ted carbon with ammonia for efficient pyrene adsorption[J]. Journal of Industrial and Engineering Chemistry, 2016, 39:27- 36. doi: 10.1016/j.jiec.2016.05.003

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微波强化催化H₂O₂处理印染生化出水及有机物去除

Degradation of biochemical treated effluent of dyeing wastewater and its organics removal by microwave-enhanced catalytic H₂O₂