工业水处理 ›› 2012, Vol. 32 ›› Issue (3): 77-79,80. doi: 10.11894/1005-829x.2012.32(3).77

• 油气田水处理 • 上一篇    下一篇

聚合物驱含油污水的聚集特性研究

陈武1, 靖波2,3, 张健2,3, 尹先清1, 孟凡雪2,3, 王大勇1   

  1. 1. 长江大学化学与环境工程学院, 湖北荆州 434023;
    2. 海洋石油高效开发国家重点实验室, 北京 100027;
    3. 中海油研究总院, 北京 100027
  • 收稿日期:2011-12-16 出版日期:2012-03-20 发布日期:2012-03-19
  • 作者简介:陈武(1967-),1990年毕业于湖北药检高等专科学校,博士,教授,主要从事油气田环境保护的科研和教学工作.电话:13872413398,E-mail:ccww98@126.com.
  • 基金资助:

    国家科技重大专项(2011ZX05024-004)

Study on the aggregative properties of polymer-flooding oil-bearing wastewater

Chen Wu1, Jing Bo2,3, Zhang Jian2,3, Yin Xianqing1, Meng Fanxue2,3, Wang Dayong1   

  1. 1. College of Chemical and Environmental Engineering, Yangtze University, Jingzhou 434023, China;
    2. State Key Laboratory of Offshore Oil Exploitation, Beijing 100027, China;
    3. CNOOC Research Institute, Beijing 100027, China
  • Received:2011-12-16 Online:2012-03-20 Published:2012-03-19

摘要:

通过测定聚合物驱含油污水中油珠、絮体及Zeta电位的大小,研究了污水油含量、固体悬浮物含量、聚合物浓度对油珠及悬浮物的亚微观聚集形态、表面电荷及污水稳定性的影响。结果表明,随聚合物浓度或油含量的增加,污水中的油珠、絮体均有变大的趋势;随固体悬浮物浓度的增加,污水中的油珠、絮体不仅有变大的趋势,且大尺寸的絮体数量显著增加。聚合物浓度对带电颗粒的Zeta电位有显著的影响,聚合物浓度越高,带电颗粒的Zeta电位绝对值越高。表明聚合物是聚合物驱采油污水处理低效的原因。

关键词: 聚合物驱, 含油污水, 聚集特性

Abstract:

The effects of oil content,solid suspend(SS) content and polymer concentration on oil-droplet,SS submicrocosmic aggregative form,surface charge and stability of wastewater have been studied by means of determining oil-droplet size,floc size and Zeta potential.The results show that the sizes of oil-droplets and flocs in wastewater tend to become bigger with the increase of oil content and polymer concentration;and with the increase of SS content,flocs and oil-droplet sizes in wastewater not only tend to become bigger,but the amount of big-size flocs increases obviously.The polymer concentration has obvious effect on the Zeta potential of charged particles.The higher the polymer concentration is,the higher the Zeta potential absolute value of charged particles are.It demonstrates that the polymer in wastewater is the cause of low efficiency for polymer-flooding oil-bearing wastewater treatment.

Key words: polymer-flooding, oil-bearing wastewater, aggregative properties

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