工业水处理 ›› 2012, Vol. 32 ›› Issue (1): 21-24. doi: 10.11894/1005-829x.2012.32.(1).21

• 试验研究 • 上一篇    下一篇

高收率黏胶基活性炭纤维的制备及其净水效果

吴明铂1, 朱文慧1, 张建2, 曹溪禄2, 郑经堂1, 顾学林2, 李清方2, 任杰2   

  1. 1. 中国石油大学(华东)重质油国家重点实验室, 山东青岛 266555;
    2. 中国石化集团胜利石油管理局, 山东东营 257026
  • 收稿日期:2011-10-11 修回日期:2011-10-11 出版日期:2012-01-20 发布日期:2014-10-08
  • 作者简介:吴明铂(1972- ),2003 年毕业于大连理工大学,博士, 副教授。电话:0546 -7810288,E-mail:wmbpeter@yahoo.com.cn。
  • 基金资助:

    教育部新世纪优秀人才支持计划(NCET-10-0768);国家自然科学基金面上项目(20876176, 51172285);教育部科学技术研究重点项目(109100);中央高校基本科研业务费专项资金(09CX04037A);山东省博士基金(2008BS09013)

Preparation of viscose rayon based activated carbon fiber with high yield and its water purification effectiveness

Wu Mingbo1, Zhu Wenhui1, Zhang Jian2, Cao Xilu2, Zheng Jingtang1, Gu Xuelin2, Li Qingfang2, Ren Jie2   

  1. 1. State Key Laboratory of Heavy Oil Processing, China University of Petroleum(East China), Qingdao 266555, China;
    2. Shengli Oilfield, China Petrochemical Corporation, Dongying 257026, China
  • Received:2011-10-11 Revised:2011-10-11 Online:2012-01-20 Published:2014-10-08

摘要:

以黏胶纤维为原料制备了高收率活性炭纤维。磷酸氢二铵预处理可使黏胶纤维的炭化收率由20%提高到44%,提出了磷酸氢二铵预处理提高黏胶纤维炭化收率的机理。以水蒸气为活化剂,当活化温度为950 ℃,活化时间为30 min 时,所制活性炭纤维的比表面积可达1 680 m2/g。开发了活性炭纤维净水器,并考察了其净化效果,研究结果表明: 该活性炭纤维净水器具有很好的净水效果, 出水CODMn为0.88 mg/L, 远优于GB 5749—2006 规定的CODMn≤3 mg/L 的要求。 [

关键词: 黏胶纤维, 活性炭纤维, 水质净化

Abstract:

Activated carbon fiber(ACF)with high yield has been prepared from viscose rayon fiber. The carbonization yield of viscose rayon fiber can be greatly increased from 20% to 44% by the pretreatmen of adding (NH42HPO4 to rayon fiber. And the mechanism of increasing the carbonization yield of viscose rayon fiber by (NH42HPO4 pretreatment has been put forward. Steam is used as activator. When the activating temperature is 950 ℃ and activating time 30 min,the ACF specific surface area of the prepared activated carbon fiber can reach l 680 m2/g. The prepared ACF can be used as adsorbent in water purifier. Thus,the activated carbon fiber purifier has been developed, and its purification effect investigated. The results show that water purifier based on ACF shows good effect on water purification,and the CODMn of effluent can reach 0.88 mg/L,far less than 3 mg/L of the requirement prescribed in the Standard GB 5749—2006.

Key words: viscose rayon fiber, activated carbon fiber, water purification

中图分类号: