工业水处理 ›› 2017, Vol. 37 ›› Issue (9): 48-52. doi: 10.11894/1005-829x.2017.37(9).048

• 试验研究 • 上一篇    下一篇

负载Al2O3的活性炭纤维电吸附除盐研究

李谦, 刘志英, 许海辉, 赵宗锋, 徐炎华, 赵贤广   

  1. 南京工业大学环境科学与工程学院, 江苏南京 211816
  • 修回日期:2017-06-16 出版日期:2017-09-20 发布日期:2017-09-28
  • 通讯作者: 赵贤广。E-mail:zxg174@163.com。 E-mail:zxg174@163.com
  • 作者简介:李谦(1992-),硕士。E-mail:245807656@qq.com。
  • 基金资助:
    江苏省高校自然科学研究重大项目(16KJA610002)

Research on Al2O3-loaded activated carbon fiber for the electro-adsorptive desalination

Li Qian, Liu Zhiying, Xu Haihui, Zhao Zongfeng, Xu Yanhua, Zhao Xianguang   

  1. College of Environmental Science and Engineering, Nanjing Tech University, Nanjing 211816, China
  • Revised:2017-06-16 Online:2017-09-20 Published:2017-09-28

摘要: 采用浸渍煅烧法对活性炭纤维进行Al2O3负载改性,对改性前后活性炭纤维的微观结构、电化学性能和除盐性能进行分析比较,并探讨了影响其电吸附除盐效果的影响因素,结果表明:改性后活性炭纤维电吸附除盐性能得到极大增强,除盐能力为改性前的2.68倍。且电极具备很好的再生性;其表面出现了絮状和颗粒状的Al2O3,比表面积减小,中孔增加,孔径分布更加合理,比电容提高了2.1倍。当电压为2.0 V,极板间距为1 cm,NaCl质量浓度为500 mg/L时,除盐效率可达到64.6%。

关键词: 电吸附, 活性炭纤维, Al2O3负载, 除盐

Abstract: Activated carbon fiber has been modified by Al2O3-loaded dipping calcination method. The micro-struc-ture,electrochemical performance and desalination performance of the activated carbon fiber before and after the modification are analyzed and compared,and the influencing factors that affecting electro-adsorption desalination efficiency are discussed. The results show that the electro-adsorption desalination performance of the modified acti-vated carbon fiber are enhanced greatly. The desalination capability is 2.68 times of that before the modification. In addition,the electrodes have very good reproducibility. Flocculent and granular Al2O3 has appeared on its sur-faces,having smaller specific surface and more middle-size mesopores. The pore-size distribution gets more rea-sonable and specific capacitance has increased by 2.1 times. When the voltage is 2.0 V,the distance between the electrodes is 1 cm and NaCl mass concentration is 500 mg/L,the desalination efficiency of the modified activated carbon fiber can reach 64.6%.

Key words: electro-adsorption, activated carbon fiber, Al2O3-loaded, desalination

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