零价铁还原催化臭氧氧化靛蓝二磺酸钠的研究

doi:10.11894/1005-829x.2017.37(7).021

工业水处理 ›› 2017, Vol. 37 ›› Issue (7): 21-25. doi: 10.11894/1005-829x.2017.37(7).021

零价铁还原催化臭氧氧化靛蓝二磺酸钠的研究

杨丽¹, 廖伟¹, 袁向娟¹, 徐海明¹, 李东亚¹, 孙磊¹, 施银桃¹, 夏东升^1,2

1. 武汉纺织大学环境工程学院, 湖北武汉 430200;
2. 武汉纺织大学纺织印染清洁生产教育部工程中心, 湖北武汉 430200

收稿日期:2017-03-07 出版日期:2017-07-20 发布日期:2017-07-31
作者简介:杨丽(1992—),硕士。电话:15629067759,E-mail:1439231391@qq.com。
基金资助:
国家科技支撑计划（2014BAC13B02）

Research on the reduction,catalysis and ozonation of Indigo disulfonate with zero-valent iron

Yang Li¹, Liao Wei¹, Yuan Xiangjuan¹, Xu Haiming¹, Li Dongya¹, Sun Lei¹, Shi Yintao¹, Xia Dongsheng^1,2

1. Institute of Environmental Engineering, Wuhan Textile University, Wuhan 430200, China;
2. Textile, Printing & Dyeing Clean Production Engineering Centre of Ministry of Education, Wuhan Textile University, Wuhan 430200, China

Received:2017-03-07 Online:2017-07-20 Published:2017-07-31

摘要/Abstract

摘要： 建立了零价铁还原催化臭氧氧化靛蓝二磺酸钠的体系，通过一级动力学分析分别考察了零价铁粒径、底物初始浓度、零价铁的投加量、pH、温度以及废水中常见的阴离子（Cl^-、NO₃^-、SO₄^2-）等条件对反应速率的影响。通过自由基抑制试验与电子自旋共振法（ESR）以及离子阱质谱等实验分析来进一步探讨零价铁还原催化臭氧氧化体系的反应机理。

关键词: 零价铁, 臭氧, 催化氧化

Abstract: A system for the reduction,catalysis and ozonation of Indigo disulfonate with zero-valent iron has been established. The influences of the grain diameter of zero-valent iron,substrate initial concentration,dosage,pH,and temperature,along with common anions,such as Cl^-,NO₃^-,SO₄^2- etc. in wastewater on reaction rates are investigated,respectively,by the first-order kinetics analysis. The reaction mechanisms of reduction,catalysis and ozonation systems of Indigo disulfonate with zero-valent iron are further discussed,by means of experiments and analysis,such as radical inhibition test,electron spin resonance(ESR)and ion trap mass spectrometry,etc.

Key words: zero-valent iron, ozone, catalytic oxidation

中图分类号:

X703.1

杨丽, 廖伟, 袁向娟, 徐海明, 李东亚, 孙磊, 施银桃, 夏东升. 零价铁还原催化臭氧氧化靛蓝二磺酸钠的研究[J]. 工业水处理, 2017, 37(7): 21-25.

Yang Li, Liao Wei, Yuan Xiangjuan, Xu Haiming, Li Dongya, Sun Lei, Shi Yintao, Xia Dongsheng. Research on the reduction,catalysis and ozonation of Indigo disulfonate with zero-valent iron[J]. INDUSTRIAL WATER TREATMENT, 2017, 37(7): 21-25.

https://www.iwt.cn/CN/Y2017/V37/I7/21

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零价铁还原催化臭氧氧化靛蓝二磺酸钠的研究

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