工业水处理 ›› 2017, Vol. 37 ›› Issue (8): 70-73,104. doi: 10.11894/1005-829x.2017.37(8).070

• 试验研究 • 上一篇    下一篇

电解法处理电镀含镍浓缩废液的试验研究

熊正为1, 陈齐玮1, 王劲松1, 张炜铭2, 虢清伟3, 朱雷4   

  1. 1. 南华大学土木工程学院, 湖南衡阳 421001;
    2. 南京大学环境学院, 江苏南京 210046;
    3. 环境保护部华南环境科学研究所, 广东广州 510655;
    4. 湖南大学土木工程学院, 湖南长沙 410000
  • 收稿日期:2017-06-26 出版日期:2017-08-20 发布日期:2017-09-04
  • 通讯作者: 王劲松,博士,教授。E-mail:xhwjs@163.com。 E-mail:xhwjs@163.com
  • 作者简介:熊正为(1963-),教授。E-mail:xiongzhw@163.com。
  • 基金资助:
    国家科技重大专项项目(2012ZX07206-003)

Experimental study on the treatment of highly concentrated electroplating nickel-containing waste liquid by electrolytic method

Xiong Zhengwei1, Chen Qiwei1, Wang Jinsong1, Zhang Weiming2, Guo Qingwei3, Zhu Lei4   

  1. 1. School of Civil Engineering, University of South China, Hengyang 421001, China;
    2. School of the Environment, Nanjing University, Nanjing 210046, China;
    3. South China Institute of Environmental Science, MEP, Guangzhou 510655, China;
    4. School of Civil Engineering, Hunan University, Changsha 410000, China
  • Received:2017-06-26 Online:2017-08-20 Published:2017-09-04

摘要: 以电解法处理含镍浓缩液并回收镍,考察了电流强度、镍离子浓度、温度、pH和缓冲溶液对镍回收效果的影响。结果显示,以钌铱涂层钛板为阳极,在极距为20 mm、电流15 A、温度50℃、镍离子质量浓度为20 g/L并通气搅拌的条件下,镍回收率最高达到85.1%,相应的电流效率为51.8%。正交试验结果表明,镍回收率影响因素的大小顺序是电流>镍离子浓度> pH >温度。

关键词: 电镀废水, 镍, 电解法, 回收

Abstract: The concentrated nickel-containing solution has been treated by electrolytic method,and the nickel re-covered. The influences of current intensity,concentration of nickel ions,temperature,initial pH and buffer solu-tion on the recovery of nickel are investigated. The results show that under the following conditions:using Ru-Ir coated titanium plate as anode,plate distance 20 mm,electric current 15 A,temperature 50℃,the initial mass concentration of nickel ions 20 g/L,and by aeration and agitation,the nickel recovery rate can be as high as 85.1%,and the corresponding current efficiency is 51.8%. The orthogonal experiments show that the sequence of influential factors on recovery rate is electric current > concentration of nickel ion > pH > temperature.

Key words: electroplating wastewater, nickel, electrolytic method, recovery

中图分类号: