工业水处理 ›› 2018, Vol. 38 ›› Issue (8): 28-32. doi: 10.11894/1005-829x.2018.38(8).028

• 试验研究 • 上一篇    下一篇

火电厂脱硫废水氨氮去除工艺试验研究

薛丹1, 曹红梅2, 王璟1, 王永前3, 焦绪常3, 陆奥运1, 刘亚鹏1   

  1. 1. 西安热工研究院有限公司, 陕西西安 710032;
    2. 华能山东发电有限公司, 山东济南 250014;
    3. 华能济宁运河发电有限公司, 山东济宁 272057
  • 收稿日期:2018-06-21 出版日期:2018-08-20 发布日期:2018-08-23
  • 作者简介:薛丹(1991-),硕士,工程师。电话:15129076109,E-mail:377919876@qq.com。
  • 基金资助:
    华能山东发电有限公司科技项目(TL-CA-128-2016A)

Experimental research on the ammonia nitrogen removing process from desulfurization wastewater in a thermal power plant

Xue Dan1, Cao Hongmei2, Wang Jing1, Wang Yongqian3, Jiao Xuchang3, Lu Aoyun1, Liu Yapeng1   

  1. 1. Xi'an Thermal Power Research Institute Co., Ltd., Xi'an 710032, China;
    2. Huaneng Shandong Power Generation Co., Ltd., Ji'nan 250014, China;
    3. Huaneng Jining Canal Power Generation Co., Ltd., Jining 272057, China
  • Received:2018-06-21 Online:2018-08-20 Published:2018-08-23

摘要: 介绍了火电厂脱硫废水的水质特点,分析其氨超标现状,阐述了化学沉淀工艺去除脱硫废水中氨氮的优势,并论证其可行性。结果表明,当pH为8.5、n(Mg):n(N)为5.0:1、n(P):n(N)为2.0:1、反应温度为25~30℃、搅拌速度为150 r/min、搅拌时间为20 min时,该工艺对某火电厂脱硫废水中氨氮的去除率能达到90%以上,最终投加少量NaClO可使废水中氨氮达标排放。XRD及SEM结果显示,反应中产生的沉淀物为磷酸铵镁盐。

关键词: 火电厂, 脱硫废水, 氨氮, 化学沉淀

Abstract: The characteristics of desulfurization wastewater in a thermal power plant is introduced,the ammonia ni-trogen over-proof situation of desulfurization wastewater analyzed,the advantages of chemical precipitation process for removing ammonia nitrogen from desulfurization wastewater expounded,and its feasibility demonstrated. The re-sults show that the ammonia nitrogen removing rate from the desulfurization wastewater of a thermal power plant by this process can be above 90%,when pH=8.5,n(Mg):n(N)=5.0:1,n(P):n(N)=2.0:1,reaction temperature 25-30℃,stirring speed 150 r/min,and stirring time 20 min. At the end,the dosing of a small amount of NaClO can make am-monia nitrogen in the wastewater reach the discharge standard. The XRD and SEM results show that the precipitate produced in the reaction is magnesium ammonium phosphate.

Key words: thermal power plant, desulfurization wastewater, ammonia nitrogen, chemical precipitation

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