工业水处理 ›› 2008, Vol. 28 ›› Issue (9): 85-88. doi: 10.11894/1005-829x.2008.28(9).85

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微漏状态下含硫循环水治理试验研究

唐安中1, 付晓萍2, 李本高2   

  1. 1. 中石化股份有限公司九江分公司机动处, 江西九江 332004;
    2. 中石化石油化工科学研究院水处理中心, 北京 100001
  • 收稿日期:2008-05-08 修回日期:2008-05-08 出版日期:2008-09-20 发布日期:2010-10-01
  • 作者简介:唐安中(1968- ),毕业于南昌大学环境工程系,硕士,现就职于中石化九江分公司机动处,高级工程师,动力副科长。电话:0792-8871187,E-mail:jdc-taz@jjsh.com.cn。

Test and research of the anticorrosion caused by sulfur containing circulating water under pinhole leaking condition

Tang Anzhong1, Fu Xiaoping2, Li Bengao2   

  1. 1. Mechanical Division, Jiujiang Branch of China Petrochemical Co., Ltd., Jiujiang 332004, China;
    2. Water Treatment Center, Institute of Petroleum Chemical Engineering Science, China Petrochemical Co., Ltd., Beijing 100001, China
  • Received:2008-05-08 Revised:2008-05-08 Online:2008-09-20 Published:2010-10-01

摘要:

对炼油装置泄漏物进入循环水中造成设备严重腐蚀的机理进行了分析与研究。通过实验与筛选,开发出一种处理微漏状态下含硫循环水的新工艺,该工艺采用在投加常规药剂基础上适当提高碱度,并添加一定量的缓蚀阻垢增效剂RP-49,可以较好地解决含硫泄漏物质对碳钢的腐蚀。RP-49主要是抑制硫化物进入缓蚀膜,从而保证磷酸盐和锌盐在碳钢表面形成完整的保护膜,能有效延缓碳钢设备在微漏状态下含硫循环水中的腐蚀速度。

关键词: 循环水, 硫化物, 防腐

Abstract:

The mechanism of the serious equipment corrosion caused by the divulging material of refinery installment entering into the circulating water has been analyzed and studied. A new technology has been developed to process sulfur-containing circulating water under pinhole leaking condition. This new technology is to increase the alkalinity in the conventional medicament foundation suitably, and add a certain amount of corrosion and scale inhibition synergist RP 49. It is observed that it can nicely solve the carbon steel corrosion problem caused by sulfur divulging materials. RP 49 mainly is to suppress the sulfide from entering the sloweclipsing membrane so as to guarantee the phosphate and zinc salt to form the integrated protective film on the surface of carbon steel. Thus the corrosion rate of carbon steel equipment under pinhole leaking sulfur-containing circulating water can be effectively decreased.

Key words: circulating water, sulfide, anticorrosion

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