水滑石基固体双氧水处理水体中金属络合染料研究

doi:10.11894/1005-829x.2019.39(3).025

工业水处理 ›› 2019, Vol. 39 ›› Issue (3): 25-29. doi: 10.11894/1005-829x.2019.39(3).025

水滑石基固体双氧水处理水体中金属络合染料研究

石春蕾¹, 王倩¹, 李宗翰¹, 韩婷¹, 许玲¹, 王昕¹, 王晓飞²

1. 西安工业大学材料与化工学院, 陕西西安 710021;
2. 陕西科技大学材料科学与工程学院, 陕西西安 710021

收稿日期:2018-12-13 出版日期:2019-03-20 发布日期:2019-03-26
通讯作者: 王倩,讲师。E-mail:drifting_leaf@126.com。 E-mail:drifting_leaf@126.com
作者简介:石春蕾(1994-),本科在读。E-mail:xatutougao@163.com。
基金资助:
国家自然科学基金青年基金（51608412，61704133）；陕西省自然科学基础研究计划（2016JQ2034）；陕西省教育厅专项项目（17JK0086）；大学生创新创业训练计划（201710702A014，201710702A024）

Research on hydrotalcite-based solid hydrogen peroxide for the treatment of metal complex dyes in water

Shi Chunlei¹, Wang Qian¹, Li Zonghan¹, Han Ting¹, Xu Ling¹, Wang Xin¹, Wang Xiaofei²

1. School of Materials Science and Chemical Engineering, Xi'an University of Technology, Xi'an 710021, China;
2. School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China

Received:2018-12-13 Online:2019-03-20 Published:2019-03-26

摘要/Abstract

摘要： 采用改良的低温结晶法制备基于碳酸根插层的MgAl-LDH的固体双氧水（LDHPC），对其进行表征并作为氧化剂构建类Fenton体系降解中性蓝（BNL）。结果表明，所得LDHPC纯度较高，其中MgAl-LDH与双氧水通过氢键结合，H₂O₂质量分数为13.55%。以LDHPC为氧化剂的非均相类Fenton体系适用pH范围为2~10。该体系可同时实现BNL有机部分的降解和对产生的铜离子的吸附去除，120 min后，铜离子的剩余率为26.93%。

关键词: 中性蓝, 基于水滑石的固体双氧水, 非均相类Fenton体系, 金属络合染料

Abstract: The carbonate interlayered MgAl-LDH solid hydrogen peroxide(LDHPC) has been prepared by modified low temperature crystallization method,and characterized. As a kind of oxidant,it has been used for the construction of Fenton-like system in order to degrade neutral blue(BNL). The results show that the purity of the prepared LDHPC is high. Through the hydrogen bonding,MgAl-LDH is hydrogenated with hydrogen peroxide,and the mass fraction of H₂O₂ is 13.55%. The adequate pH range of the heterogeneous Fenton-like system using LDHPC as oxidant is 2-10. This system can simultaneously realize the degradation of the organic part of BNL and the adsorptive removal of the produced copper ions. The residual rate of copper ions is 26.93% in 120 min.

Key words: neutral blue, hydrotalcite-based solid hydrogen peroxide, heterogeneous Fenton-like system, metal complex dyes

中图分类号:

X703.1
TQ424

石春蕾, 王倩, 李宗翰, 韩婷, 许玲, 王昕, 王晓飞. 水滑石基固体双氧水处理水体中金属络合染料研究[J]. 工业水处理, 2019, 39(3): 25-29.

Shi Chunlei, Wang Qian, Li Zonghan, Han Ting, Xu Ling, Wang Xin, Wang Xiaofei. Research on hydrotalcite-based solid hydrogen peroxide for the treatment of metal complex dyes in water[J]. INDUSTRIAL WATER TREATMENT, 2019, 39(3): 25-29.

https://www.iwt.cn/CN/Y2019/V39/I3/25

参考文献

[1] Kesraoui A,Mabrouk A,Seffen M. Valuation of biomaterial:in the retention of metal-complexed dyes[J]. American Journal of Environmental Sciences,2017,13(3):266-276.
[2] Bayramoglu G,Akbulut A,Liman G,et al. Removal of metal complexed azo dyes from aqueous solution using tris(2-aminoethyl)amine ligand modified magnetic p(GMA-EGDMA) cationic resin:Adsorption,isotherm and kinetic studies[J]. Chemicla Engineering Research & Design,2017,124:85-97.
[3] El-Wakiel N A,Rizk H F,Ibrahim S A. Synthesis and characterization of metal complexes of azo dye based on 5-nitro-8-hydroxyquinoline and their applications in dyeing polyester fabrics[J]. Applied Organometallic Chemistry,2017,31(10):e3723.
[4] Mofrad M R,Akbari H,Miranzadeh M B,et al. Evaluation of efficacy of advanced oxidation processes Fenton,Fenton-like and photo-Fenton for removal of phenol from aqueous solutions[J]. Journal Chemical Society of Pakistan,2015,37(2):266-271.
[5] Garzacampos B,Brillas E,Hernández R A,et al. Salicylic acid degradation by advanced oxidation processes. Coupling of solar photoelectro-Fenton and solar heterogeneous photocatalysis[J]. Journal of Hazardous Materials,2016,319:34-42.
[6] Mikhailov I,Komarov S,Levina V,et al. Nanosized zero-valent iron as Fenton-like reagent for ultrasonic-assisted leaching of zinc from blast furnace sludge[J]. Journal of Hazardous Materials,2017,321:557-565.
[7] Wang Leiqing,Shi Zhongfen,Bi Xianjun. Preparation of copper doped TiO₂ photo-catalysts with microwave irradiation in ionic liquid and microwave enhanced photo-catalytic activity[J]. Applied Chemical Industry,2014,41:1187-1192.
[8] Park M,Anumol T,Daniels K D,et al. Predicting trace organic compound attenuation by ozone oxidation:Development of indicator and surrogate models[J]. Water Research,2017,119:21-32.
[9] Lu Mingchun,Chen J N,Chang C P. Oxidation of dichlorvos with hydrogen peroxide using ferrous ion as catalyst[J]. Journal of Hazardous Materials,1999,65(3):277-288.
[10] Ma Jiahai,Song Wenjing,Chen Chuncheng,et al. Fenton degradation of organic compounds promoted by dyes under visible irradiation[J]. Environmental Science & Technology,2005,39(15):5810.
[11] Wang Qian,Tian Senlin,Long Jian,et al. Use of Fe(Ⅱ)Fe(Ⅲ)-LDHs prepared by co-precipitation method in a heterogeneous-Fenton process for degradation of Methylene Blue[J]. Catalysis Today,2014,224(4):41-48.
[12] Zhang Hui,Fei Chengzhi,Zhang Daobin,et al. Degradation of 4-nitrophenol in aqueous medium by electro-Fenton method[J]. Journal of Hazardous Materials,2007,145(1/2):227-232.
[13] Zhao Ce,Zeng Hongyan,Huang Yan,et al. Preparation of MgFe-hydrotalcites and their catalytic performance in synthesis of biodiesel oil from chlorella protothecoides oil[J]. Journal of Fuel Chemistry & Technology,2012,114(15):6869-6877.

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