热解法合成增强光催化活性的In2O3-TiO2纳米管

doi:10.11894/1005-829x.2019.39(3).021

工业水处理 ›› 2019, Vol. 39 ›› Issue (3): 21-24. doi: 10.11894/1005-829x.2019.39(3).021

热解法合成增强光催化活性的In₂O₃-TiO₂纳米管

肖昌仁¹, 谭子俊¹, 张国庆^1,2, 杜青平³, 潘华耿²

1. 广东工业大学材料与能源学院, 广东广州 510006;
2. 佛山市顺德区都围科技环保工程有限公司, 广东顺德 528300;
3. 广东工业大学环境科学与工程学院, 广东广州 510006

收稿日期:2018-12-22 出版日期:2019-03-20 发布日期:2019-03-26
作者简介:肖昌仁(1994-),硕士。电话:15626445337,E-mail:X5330277@foxmail.com。
基金资助:
国际科技合作计划（2011DFB91560）；广东省科技计划（2012B050200002，2013B020600007，2015A020215031）

Pyrolysis for the synthesis of In₂O₃-TiO₂ nanotube with enhanced photo-catalytic activity

Xiao Changren¹, Tan Zijun¹, Zhang Guoqing^1,2, Du Qingping³, Pan Huageng²

1. School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China;
2. Shunde Dowell Technological & Environmental Engineering Co., Ltd., Shunde 528300, China;
3. School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, China

Received:2018-12-22 Online:2019-03-20 Published:2019-03-26

摘要/Abstract

摘要： 通过热解法分解InCl₃形成In₂O₃并均匀沉积于通过阳极氧化法制备的TiO₂纳米管（TNAs）表面，并通过光催化降解罗丹明B（RhB）来测试In₂O₃-TNAs的光催化活性。结果表明，复合In₂O₃后TNAs的光催化活性显著提升。此外热解沉积工艺简单、成本低，有利于光催化剂的批量、工业化生产，为金属氧化物半导体的沉积提供了新思路。

关键词: 光催化, 阳极氧化, TiO₂纳米管, 热解法, In₂O₃

Abstract: The pyrolysis method has been used for decomposing InCl₃ so as to form In₂O₃,and depositing uniformly on the surface of TiO₂ nanotube(TNAs) which was prepared by anodic oxidation method,and the photo-catalytic activity of In₂O₃-TNAs was tested by the photo-catalytic degradation of Rodamine B(RhB). The results show that after combined with In₂O₃,the photo-catalytic activity of In₂O₃-TNAs binary system is enhanced dramatically compared with that of pure TNAs. In addition,pyrolysis deposition is characterized by simple process,low costs,and advantageous to volume production and industrial production of photo-catalysts,providing a new concept for the deposition of metallic oxidant semi-conductors.

Key words: photo-catalysis, anodic oxidation, TiO₂ nanotube, pyrolysis, In₂O₃

中图分类号:

X703

肖昌仁, 谭子俊, 张国庆, 杜青平, 潘华耿. 热解法合成增强光催化活性的In₂O₃-TiO₂纳米管[J]. 工业水处理, 2019, 39(3): 21-24.

Xiao Changren, Tan Zijun, Zhang Guoqing, Du Qingping, Pan Huageng. Pyrolysis for the synthesis of In₂O₃-TiO₂ nanotube with enhanced photo-catalytic activity[J]. INDUSTRIAL WATER TREATMENT, 2019, 39(3): 21-24.

https://www.iwt.cn/CN/Y2019/V39/I3/21

参考文献

[1] Pelaez M,Nolan N T,Pillai S C,et al. A review on the visible light active titanium dioxide photocatalysts for environmental applications[J]. Applied Catalysis B Environmental,2012,125:331-349.
[2] Macak J M,Martin Z,Josef K,et al. Self-organized TiO₂ nanotube layers as highly efficient photocatalysts[J]. Small,2010,3(2):300-304.
[3] Ahmed E R M,Rohani S. Modified TiO₂ nanotube arrays(TNTAs):progressive strategies towards visible light responsive photoanode:areview[J]. Energy & Environmental Science,2011,4(4):1065-1086.
[4] Xiao Fangxing. Construction of highly ordered ZnO-TiO₂,nanotube arrays(ZnO/TNTs) heterostructure for photocatalytic application[J]. ACS Applied Materials & Interfaces,2012,4(12):7055-7063.
[5] Ge M,Cao C,Li S,et al. Enhanced photocatalytic performance of n-TiO₂ nanotubes by uniform creation of p-n heterjunctions with p-Bi₂O₃ quantum dots[J]. Nanoscale,2015,7(27):11552-11560.
[6] Hou Yang,Li Xinyong,Zou Xuejun,et al. Photoeletrocatalytic activity of a Cu₂O-loaded self-organized highly oriented TiO₂ nanotube array electrode for 4-chlorophenol degradation[J]. Environmental Science & Technology,2009,43(3):858-863.
[7] Liu Qiang,Ding Dongyan,Ning Congqin,et al. Nonstoichiometric In₂O₃ nanorods/black Ti-Ni-O nanotubes heterojunction photoanode for high-efficiency photoelectrochemical water splitting[J]. Solar Energy Materials and Solar Cells,2016,145:382-390.
[8] Wei Na,Cui Hongzhi,Wang Xinzhen,et al. Hierarchical assembly of In₂O₃,nanoparticles on ZnO hollow nanotubes using carbon fibers as templates:Enhanced photocatalytic and gas-sensing properties[J]. Journal of Colloid and Interface Science,2017,498:263-270.
[9] Wang Zeyan,Huang Baibiao,Dai Ying,et al. Highly photocatalytic ZnO/In₂O₃ heteronanostructures synthesized by a coprecipitation method[J]. Journal of Physical Chemistry C,2014,113(11):4612-4617.
[10] Yang Xia,Wang Yonghui,Xu Leilei,et al. Silver and indium oxide codoped TiO₂ nanocomposites with enhanced photocatalytic activity[J]. Journal of Physical Chemistry C,2008,112(30):5448-5452.
[11] Mu Jingbo,Chen Bin,Zhang Mingyi,et al. Enhancement of the visible-light photocatalytic activity of In₂O₃-TiO₂ nanofiber heteroarchitectures[J]. ACS Applied Materials & Interfaces,2012,4(1):424-430.
[12] Rodríguez-González V,Moreno-Rodríguez,May M,et al. Slurry photodegradation of 2,4-dichlorophenoxyacetic acid:A comparativestudy of impregnated and sol-gel In₂O₃-TiO₂ mixed oxide catalysts[J]. Journal of Photochemistry & Photobiology A Chemistry, 2008,193(2/3):266-270.
[13] Yang Hongru,Tian Jian,Bo Yanyan,et al. Visible photocatalytic and photoelectrochemical activities of TiO₂ nanobelts modified by In₂O₃ nanoparticles[J]. J. Colloid Interface Sci.,2017,487:258-265.

[1]	靳亚斌, 徐甜甜, 赵德中, 张乐, 万振杰, 张高明. Bi₂O₃基复合光催化剂的制备及其在水处理中的应用进展[J]. 工业水处理, 2025, 45(3): 10-21.
[2]	周朝云, 令玉林, 蒋文雪, 周建红. WO₃/rGO/BiOBr的制备及其光催化降解环丙沙星废水的性能研究[J]. 工业水处理, 2025, 45(1): 73-78.
[3]	代佳汐, 姜建辉, 韩宇凡, 张文涛, 田明霞, 张园. Cd（OH）₂/BiOCl复合材料的制备及其光催化性能[J]. 工业水处理, 2024, 44(9): 136-142.
[4]	董玮, 林莉, 顾怀章, 罗云强, 马平, 李向阳. 双Z型异质结Bi₂MoO₆/Bi₂WO₆/Ag₃PO₄的光催化研究[J]. 工业水处理, 2024, 44(8): 81-89.
[5]	张宏伟, 席晓晶, 田文杰, 张慧盈, 马晓梦, 魏敏洁, 陈华军. 易回收碳纤维/g-C₃N₄纳米片阵列制备及光催化和光电催化研究[J]. 工业水处理, 2024, 44(8): 99-106.
[6]	毕付英, 孙浩然, 刘彦彦, 陈峻峰. 改性TiO₂/膨胀珍珠岩光催化剂对赤潮微藻的抑制[J]. 工业水处理, 2024, 44(7): 113-118.
[7]	郎明娇, 杨朝美, 曾广勇. 光催化膜的构筑及其在废水处理中的研究进展[J]. 工业水处理, 2024, 44(7): 47-56.
[8]	谭斌, 郝慧茹, 向宇桐, 刘宇宁, 张倩. 基于BC-BiOI/PMS的光催化体系降解恩诺沙星的研究[J]. 工业水处理, 2024, 44(6): 143-150.
[9]	黄宏森, 郑欣钰, 林振锋, 郭永福. Z型异质结BiO_2- _x /ZnWO₄对水中抗生素的光催化研究[J]. 工业水处理, 2024, 44(4): 138-146.
[10]	王宁, 林家一, 李涛, 薛安, 陈璐, 黎阳. 石墨烯基/半导体金属氧化物复合光催化剂制备工艺研究进展[J]. 工业水处理, 2024, 44(2): 63-72.
[11]	安宁, 郝玉莹, 胡绍伟, 陈鹏, 王飞, 王永, 刘芳, 李函霏. 二氧化铈/氮掺杂氮化碳光催化处理焦化废水[J]. 工业水处理, 2024, 44(12): 184-191.
[12]	解鹤, 唐彬, 陈兵兵, 李佳利, 詹海鹃. 掺杂型钴基钙钛矿的合成及光催化降解有机废水[J]. 工业水处理, 2024, 44(12): 131-137.
[13]	王钧, 付双, 侯鹏, 刘军, 孙春雪, 张洪光. S型TiO₂/CoPc异质结的构筑及光催化降解四环素的研究[J]. 工业水处理, 2024, 44(12): 118-122.
[14]	姚有智, 华飞, 吴康, 叶舟, 张忠亮, 钱程. 石墨烯基复合材料光催化降解废水有机污染物的研究进展[J]. 工业水处理, 2024, 44(11): 1-8.
[15]	刘国煜, 曹向禹, 郑建华. 钴基氧化物光催化剂在降解有机污染物中的研究进展[J]. 工业水处理, 2024, 44(11): 27-34.

选择文件类型/文献管理软件名称

选择包含的内容

热解法合成增强光催化活性的In₂O₃-TiO₂纳米管

Pyrolysis for the synthesis of In₂O₃-TiO₂ nanotube with enhanced photo-catalytic activity

RichHTML

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

模态框（Modal）标题

选择文件类型/文献管理软件名称

选择包含的内容