Status and greenization of corrosion inhibitors used in circulating cooling water system

doi:10.11894/1005-829x.2004.24(6).1

Abstract

Abstract:

The concentration，the temperature variation，the dissolved oxygen and some other factors of circulating cooling water make the tubing and pumps corroded severely，inuence the cooling efficiency，even shut the system down. Corrosion inhibitor is one of the measures inhibiting corrosion. The properties，status and development of the corrosion inhibitor used in circulating cooling water system are summarized，and some novel corrolion inhibitors and developing prospects for green corrosion inhibitor are introduced.

Key words: circulating cooling water system, corrosion inhibitor, greenization

摘要：

循环冷却水的浓缩、温度变化、溶解氧的存在以及其他一些因素,使得系统的管道、水泵等腐蚀严重,影响冷却效率,甚至停机。投加缓蚀剂是重要的防腐蚀措施。通过综述循环冷却水处理常用缓蚀剂以及目前出现的一些新型缓蚀剂的性能特点、现状及其发展,明确了这一领域的绿色化发展方向。

关键词: 循环冷却水, 缓蚀剂, 绿色化

CLC Number:

TQ085+.411

Tang Jun, Xu Zhangfa, Xu Boxing, Qu Jianguo. Status and greenization of corrosion inhibitors used in circulating cooling water system[J]. INDUSTRIAL WATER TREATMENT, 2004, 24(6): 1-4,5.

唐俊, 徐章法, 徐伯兴, 瞿建国. 循环冷却水系统缓蚀剂的现状及绿色化进展[J]. 工业水处理, 2004, 24(6): 1-4,5.

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References

[1] 胡上国. 水处理缓蚀剂应用现状及发展方向[J]. 化工科技市场, 2000, 23(4):5-7
[2] 杨文庆. 钼酸盐系缓蚀剂的进展[J]. 润滑与密封, 1996, (1):2-6
[3] 陆柱. 绿色化学及其技术在腐蚀防护中的应用[J]. 腐蚀与防护, 1999, 20(5):201-205
[4] Iovchev M. Aluminium-thiourea mixtures as corrosion inhibitors for mild steel in 1.0% NaCl[J]. British Corrosion Journal, 1983, 18(3):148-151
[5] 林上珍. 加藤正义. 铝离子与C₂O₄^2-复配对水中碳钢的缓蚀作用及其机理[J]. 中国腐蚀与防护学报, 1992, 12(1):56-62
[6] 周本省. 工业水处理[M]. 北京:化学工业出版社, 2002. 247
[7] Diana Darling, Ram Rakshpal. Green Chemistry Applied to Corrosion and Scale Inhibitors[J]. Chemical Treatment, 1998, (9):42-45
[8] 王新龙, 等. 有机磷缓蚀剂研究进展[J]. 腐蚀与防护, 2000, 21(8):356-358, 369
[9] Sugii N, Yam Auchi T. A Multi-function Corrosion Inhibitor[P]. JP02117683, 2002
[10] 张泰山, 等. 麟羧酸共聚化合物[P] 中国专利93112895, 1993
[11] Yang Bo Reed, et al. Corrosion Inhibitors for Aqueous Systems[P]. US 6572789, 2003
[12] 李凡修, 等. 共聚物类阻垢剂的研制进展[J]. 工业水处理, 2000, 20(3):7-10
[13] 杨文忠, 等. AA/IPPA/AMPS聚合物的合成及性能的研究[J]. 工业水处理, 1998, 18(5):7-8
[14] 郭军科, 扬洪民. 磷系和含磷缓蚀阻垢剂的现状及展望[J]. 天津电力技术, 2002, (1):15-18
[15] 徐丽英. 低膦酸型缓蚀阻垢剂的研究[J]. 精细化工, 2000, 17(11):646-648
[16] 李良如. 长链脂肪胺--二(2, 3-二甲基)丁烯三胺介绍[DB/OL]. 慧聪水工业商务网, www. water. sinobnet. com/technic/index-tech4-4. asp
[17] 胡雁, 等. 高效含氮有机缓蚀剂BIEA的研究[J]. 腐蚀与防护, 2003, 24(3):93-95
[18] Hoots John E, et al. Composition of Corrosion Inhibitors for Cooling Water Systems Using Chemically Modified Acrylamide or Methacrylamide Polymers[P]. US 4756881, 1998
[19] Valmore Rodriguze, Elias Perozo. Coating Application and Evaluation for Heavy Wall Thickness, Temperature and Pressure Pipeline[J]. Materials Performance, 1998, 37(2):44-48
[20] Schmitt G, Scaleh A O. Evaluation of Environmentally Friendly Corrosion Inhibitors for Sour Service[J]. Materials Performance, 2000, 39(8):62-65
[21] 杨文治. 缓蚀剂[M]. 北京:化学工业出版社, 1989. 137
[22] 杨巍. 美国水处理化学品市场现状与展望[J]. 工业水处理, 1998, 18(2):7-11
[23] 周达江, 等. 改性腐植酸-膦基丙烯酸阻垢缓蚀剂的制备及性能研究[J]. 化学研究与应用, 2003, 15(2):194-196
[24] Pataland S, Nicol A J. The Development of a Cooling Water Inhibitor with Multifunctional Deposit Control Properties[J]. Manchester, UK Corrosion, 1995, 42(3):481-484
[25] Penninger Josef, et al. Dicarboxylic Aoid Mono-(2-hydroxydo-decyl)-esters, Their Salts and Their Use as Corrosion Inhibitors in Aqueous Systems[P]. US 4902443, 1990
[26] Fikentscher Rolf, et al. Use of Salts of Sulfonamidocarboxylic Aoides as Corrosion Inhibitors in Aqueous Systems[P]. US 4911888, 1990
[27] Farooqi I H, Quraishi M A. Natural Compounds as Corrosion Inhibitors for Mild Steel in Industrial Cooling Systems[C]. Eurocorr'97, Trondheim, Norwav, 1997. 347-351
[28] 王慧龙. 环境友好缓蚀剂的研究进展[J]. 腐蚀科学与防护技术, 2002, 14(5):275-279
[29] 张世超, 等. 具有多吸附中心的缓蚀剂的合成及性能研究[J]. 腐蚀科学与防护技术, 2003, 15(2):79-81
[30] Bentise F, Lagrenee M, Traisnel M. The corrosion inhihition of mild steel in acidic media by a new triazolc derivative[J]. Corrosion Science, 1999, 41(4):789-803
[31] Quraishi M A, et al. Corrosion inhibition of N-80 steel and mild steel in 15% boiling hydrochloric acid by a triazole compound-SAHMT[J]. Materials Chemistry and Physics, 2001, 68(3):283-287
[32] 曾涵, 等. N-咪唑基乙酸乙酯的合成及其缓蚀性能[J]. 应用化学, 2003, 20(5):487-490

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