Study on the synthesis and scale inhibiting performance of glycine dimethyl phosphonic acid

doi:10.11894/1005-829x.2009.29(8).59

INDUSTRIAL WATER TREATMENT ›› 2009, Vol. 29 ›› Issue (8): 59-61. doi: 10.11894/1005-829x.2009.29(8).59

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Study on the synthesis and scale inhibiting performance of glycine dimethyl phosphonic acid

Nan Zi-long, Yin Hao, Liu Zhi-yong

Institute of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China

Received:2009-03-19 Revised:2009-03-19 Online:2009-08-20 Published:2010-10-01

新型阻垢剂GDMP的合成及其阻垢性能的研究

南子龙, 殷昊, 刘智勇

河北工业大学化工学院, 天津 300130

通讯作者: 刘智勇,教授,河北工业大学化工学院.电话：022-60202047,Email：liuzhiyong@hebut.edu.cn. E-mail:liuzhiyong@hebut.edu.cn
作者简介:南子龙（1981- ）,2009年毕业于河北工业大学,硕士研究生,E-mail：nanzilong1981@163.com

Abstract

Abstract:

The scale inhibitor glycine dimethyl phosphonic acid （GDMP） has been synthesized with glycine, formaldehyde and phosphonic acid.The scale inhibiting effects of its binary complexes of GDMP and HEDP, PBTCA, ATMP, PESA, PASP are studied.The carbonate precipitation method is used for determining the scale inhibiting effects, and the result shows that GDMP and other frequently used scale inhibitor have synergistic effect, and they can be used for improving the prescriptions of scale inhibitors in cooling water systems.Their inhibiting mechanisms are discussed preliminarily as well.

Key words: scale inhibitor, glycine dimethyl phosphonic acid, complexes

摘要：

用甘氨酸、甲醛、亚磷酸合成了新型阻垢剂甘氨酸二亚甲基膦酸(GDMP),并将其与其他常用阻垢剂HEDP、PBTCA、ATMP、PESA、PASP进行二元复配.用碳酸钙沉淀法对GDMP单剂及其二元复配物的阻垢性能进行分析,结果表明,GDMP与其他常用阻垢剂复配有一定的协同效应,可用于改进现有工业冷却水阻垢剂配方.并对其阻垢机理进行了初步讨论.

关键词: 阻垢剂, 甘氨酸二亚甲基膦酸, 复配物

CLC Number:

TQ085.4

Nan Zi-long, Yin Hao, Liu Zhi-yong. Study on the synthesis and scale inhibiting performance of glycine dimethyl phosphonic acid[J]. INDUSTRIAL WATER TREATMENT, 2009, 29(8): 59-61.

南子龙, 殷昊, 刘智勇. 新型阻垢剂GDMP的合成及其阻垢性能的研究[J]. 工业水处理, 2009, 29(8): 59-61.

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References

［1］唐受印, 戴友芝, 荆国华,等. 废水处理工程［M］. 2 版,北京: 化学工业出版社,2004:1－2.
［2］王德宇. 磺化苯乙烯－马来酸酐共聚物的合成及其阻垢性能研究［J］. 工业水处理, 1994, 14（5）: 12－16.
［3］ Boffardi B P, Schweitzer G W. Advances in the chemistry of alkaline cooling water treatment［C］. National Association of Corrosion Engineers, Huston, Texas, 1985：132.
［4］ Masler W F, Amjad Z. Advances in the control of calcium phosphonate with a noval polymeric inhibitor［C］. National Association of Corrosion Engineers, Huston, Texas, 1988：11.
［5］张伟,郦和生, 王岽,等. 高效水处理剂GDMP 的合成及性能评价［J］. 石化技术,2004,11（3）：27－29.
［6］张军, 周本省, 杨文忠. 新型缓蚀阻垢剂GDMP 性能的研究［J］. 工业水处理,1998,18（6）:14－15.
［7］ Moedritzer K, Irani R R. The direct synthesis of α-aminomethylphosphonic acids mannich-type reactions with orthophorous acid［J］. Organic Chemistry, 1966,31（5）: 1603-1606.
［8］ GB/T 16632—1996 水处理剂阻垢性能的测定———碳酸钙沉积法［S］.
［9］梅平, 肖俊霞. 膦基聚羧酸与其他水处理剂的协同效应研究［J］. 油气田环境保护,2004,14（12）:26－28.
［10］ Suitor J W, Marner W J, Ritter R B. The history and status of research in fouling of heat exchangers in cooling water service［J］. Can. J. Chem. Eng.,1977,55:374.
［11］郑邦乾, 朱清泉. 高分子阻垢剂及其阻垢机理［J］. 油田化学, 1984（2）:181-188.
［12］李裕芳. 阻垢剂分散剂控制沉积机理探讨［J］. 工业水处理, 1984,4（3）：6-10.
［13］ Gill J S, Anderson C D, Varsanik R G. Mechanism of scale inhibition by phosphonates［C］// Proc 44th Int.Water Conf., Pittsburgh: Pa（USA）, 1983,4:26.

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新型阻垢剂GDMP的合成及其阻垢性能的研究

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Study on the synthesis and scale inhibiting performance of glycine dimethyl phosphonic acid

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