Synthesis and characterization of the copolymer scale inhibitor, phosphino IA/SAS

doi:10.11894/1005-829x.2014.34(8).051

INDUSTRIAL WATER TREATMENT ›› 2014, Vol. 34 ›› Issue (8): 51-53. doi: 10.11894/1005-829x.2014.34(8).051

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Synthesis and characterization of the copolymer scale inhibitor, phosphino IA/SAS

Fu Haolin^1,2, Liu Zhenfa^2,3, Liu Xuan^1,2, Zhang Lihui^2,3, Li Xiaohui^2,3

1. School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China;
2. Hebei Engineering Research Center of Water Saving in Industry, Shijiazhuang 050081, China;
3. Institute of Energy Sources, Hebei Academy of Science, Shijiazhuang 050081, China

Received:2014-07-03 Online:2014-08-20 Published:2014-08-25

膦基衣康酸/丙烯磺酸钠共聚物阻垢剂的合成及表征

付浩林^1,2, 刘振法^2,3, 刘璇^1,2, 张利辉^2,3, 李晓辉^2,3

1. 河北工业大学化工学院, 天津 300130;
2. 河北省工业节水工程技术研究中心, 河北石家庄 050081;
3. 河北省科学院能源研究所, 河北石家庄 050081

通讯作者: 刘振法，研究员，博士，E-mail：lzf63@sohu.com E-mail:lzf63@sohu.com
作者简介:付浩林（1987-），在读硕士研究生。
基金资助:
国家自然科学基金项目（21376062）；河北省自然科学基金（B2012302006）

Abstract

Abstract:

A water dissolved copolymer integrating carboxylic group,sulfonic group and phosphino has been synthesized,by using itaconic acid(IA) and sodium allylsulfonate(SAS) as monomers,and hydrogen peroxide-NaH₂PO₂ as initiator. The influences of reaction temperature,reaction time,NaH₂PO₂ dosage and the mass ratio of monomers on the scale inhibition capacity are discussed. The optimum conditions of the synthesis process are determined. The structure of the copolymer is characterized by means of FTIR.

Key words: itaconic acid, sodium allylsulfonate, copolymer, scale inhibitor

摘要：

以衣康酸和丙烯磺酸钠为单体，采用双氧水-次亚磷酸钠氧化还原类引发体系，合成了集羧酸基、磺酸基和膦基于一体的水溶性共聚物。讨论了反应温度、反应时间、次亚磷酸钠用量及单体质量比对共聚物阻垢性能的影响，确定了最佳合成工艺条件，采用红外光谱对共聚物进行了表征。

关键词: 衣康酸, 丙烯磺酸钠, 共聚物, 阻垢剂

CLC Number:

TQ085+.4

Fu Haolin, Liu Zhenfa, Liu Xuan, Zhang Lihui, Li Xiaohui. Synthesis and characterization of the copolymer scale inhibitor, phosphino IA/SAS[J]. INDUSTRIAL WATER TREATMENT, 2014, 34(8): 51-53.

付浩林, 刘振法, 刘璇, 张利辉, 李晓辉. 膦基衣康酸/丙烯磺酸钠共聚物阻垢剂的合成及表征[J]. 工业水处理, 2014, 34(8): 51-53.

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Synthesis and characterization of the copolymer scale inhibitor, phosphino IA/SAS

膦基衣康酸/丙烯磺酸钠共聚物阻垢剂的合成及表征

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Synthesis and characterization of the copolymer scale inhibitor, phosphino IA/SAS

膦基衣康酸/丙烯磺酸钠共聚物阻垢剂的合成及表征

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