Research progress of electrodialysis technology in the field of resourceful utilization of high salt industrial wastewater

doi:10.19965/j.cnki.iwt.2020-1002

Abstract

Abstract:

With the accelerating process of global industrialization，the discharge of high salt industrial wastewater is increasing. It has become a development trend to recycle the high salt industrial wastewater by electrodialysis process. The research status of electrodialysis technology in the field of resourceful utilization of high salt industrial wastewater were reviewed from two aspects of process optimization and coupling process development，and the research focus of electrodialysis technology in the future were prospected.

Key words: high salt industrial wastewater, electrodialysis, resourceful utilization, coupling process

摘要：

随着全球工业化进程的不断加快，高盐工业废水的排放量越来越大，采用电渗析技术将高盐工业废水进行资源化利用已成为一种发展趋势。从工艺优化及耦合工艺开发两个方面对电渗析技术在高盐工业废水资源化利用领域的研究状况进行综述，并对未来电渗析技术研究重点进行展望。

关键词: 高盐工业废水, 电渗析, 资源化利用, 耦合工艺

CLC Number:

X703

Ming ZHU, Yongzhi CHI, Fuqiang CHEN, Bo WANG, Sufeng TIAN, Muzhi LIU. Research progress of electrodialysis technology in the field of resourceful utilization of high salt industrial wastewater[J]. Industrial Water Treatment, 2022, 42(1): 21-28.

朱铭, 池勇志, 陈富强, 王波, 田素凤, 刘沐之. 高盐工业废水资源化利用领域电渗析技术的研究进展[J]. 工业水处理, 2022, 42(1): 21-28.

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Figures/Tables 9

References 58

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项目	新型ED	传统ED
能耗/（kW·h·m^-3）	1.5	2.0
膜堆电阻/Ω	40~100	50~120
脱盐效率/%	56	42
Na⁺迁移率/（mmol·m^-2·s^-1）	0.8	0.3
淡水回收率/%	50	50
操作性	简易	复杂

项目	新型ED	传统ED
能耗/（kW·h·m^-3）	1.5	2.0
膜堆电阻/Ω	40~100	50~120
脱盐效率/%	56	42
Na⁺迁移率/（mmol·m^-2·s^-1）	0.8	0.3
淡水回收率/%	50	50
操作性	简易	复杂

项目	新型镁阳极ED	镁阳极电解法
磷酸盐去除率/%	90	93
能耗/（kW·h·m^-3）	1	1.5
运行成本/（美元·kg^-1）（以P计）	31.27	81.57
投资费用	投资小	投资大
运行效果	运行稳定	膜易受污染，影响运行效果

项目	新型镁阳极ED	镁阳极电解法
磷酸盐去除率/%	90	93
能耗/（kW·h·m^-3）	1	1.5
运行成本/（美元·kg^-1）（以P计）	31.27	81.57
投资费用	投资小	投资大
运行效果	运行稳定	膜易受污染，影响运行效果

方法	操作条件	进料溶液性质	Li去除率/%
NF^〔38〕	298 K，3.5 MPa	MgCl₂·6H₂O（580 mg/L）； LiCl（1 250 mg/L）	99
CDI^〔39〕	2 V，25 ℃	15.7 mg/L（以Li计）	73
BMED^〔40〕	26 V	LiMn₂O₄（6 g）； LiCl（500 mg/L）	70
BMED^〔41〕	10 mmol/L HCl， 10 mmol/L NaOH， 30 V，AHA BP-1E膜	340 mg/L（以Li计）	97.8
BMED^〔42〕	3 mmol/L HCl， 3 mmol/L NaOH， 25 V，50 L/h溶液流速	（256±33.11） mg/L（以Li计）	99

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