Degradation of Rhodamine B by manganese residue activated peroxymonosulfate

doi:10.19965/j.cnki.iwt.2023-1263

Abstract

Abstract:

Manganese residue was used to activate peroxymonosulfate(PMS) for Rhodamine B(RhB) degradation. The physichemical properties of manganese residue were analyzed by X-ray diffractometer, specific surface area and porosity analyzer and Fourier transform infrared spectrometer. The effects of manganese residue dosage, PMS concentration, temperature, pH, and RhB concentration of the solution on RhB degradation were studied. The reusability of manganese residue and mechanism of RhB degradation using PMS activated by manganese residue were also investigated. The results showed that manganese residue used in this study contained abundant Fe₃O₄, with a saturation magnetization of 8.67 emu/g and a specific surface area of 29.95 m²/g. The pores in manganese residue were predominantly mesoporous. The removal rate of RhB could reach 97.6% at 120 min under the conditions of temperature of 25 ℃, RhB concentration of 20 mg/L, manganese residue dosage of 2.0 g/L, PMS concentration of 0.50 mmol/L, pH of 4.9, and still could maintain 84.2% after 5 cycles. In the degradation process, ¹O₂, O₂ ^·- and ·OH were all involved in the reaction, with ¹O₂ playing a dominant role.

Key words: manganese residue, Rhodamine B, peroxymonosulfate, advanced oxidation process, catalytic degradation

摘要：

将锰渣用于活化过一硫酸盐（PMS）降解罗丹明B（RhB）。采用X射线衍射仪、振动样品磁强计、比表面积及孔隙度分析仪、傅里叶红外光谱仪分析了锰渣的理化性质，研究了锰渣投加量、PMS浓度、反应温度、溶液初始pH及RhB浓度等工艺条件对RhB降解效果的影响，考察了锰渣的循环使用性能，同时探讨了锰渣活化PMS降解RhB的机理。结果表明，所用锰渣富含Fe₃O₄，饱和磁化强度为8.67 emu/g，比表面积为29.95 m²/g，且锰渣中的孔以介孔为主。在反应温度为25 ℃，RhB初始质量浓度为20 mg/L，锰渣投加量为2.0 g/L，PMS浓度为0.50 mmol/L，pH=4.9条件下，反应120 min时体系对RhB的去除率为97.6%，且循环使用5次后，RhB去除率依然可达84.2%。在锰渣活化PMS降解RhB的过程中，¹O₂、O₂ ^·-和·OH均参与了反应，其中¹O₂起主导作用。

关键词: 锰渣, 罗丹明B, 过一硫酸盐, 高级氧化, 催化降解

CLC Number:

X703.1

Guoqing ZHENG, Yukun HUANG, Yaocong HAN, Xingyong XUE, Yanyue LU, Lihong LAN, Zhennan CHEN. Degradation of Rhodamine B by manganese residue activated peroxymonosulfate[J]. Industrial Water Treatment, 2025, 45(1): 79-86.

郑国庆, 黄煜坤, 韩要丛, 薛兴勇, 卢彦越, 蓝丽红, 陈贞南. 锰渣活化过一硫酸盐降解罗丹明B[J]. 工业水处理, 2025, 45(1): 79-86.

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URL: https://www.iwt.cn/EN/10.19965/j.cnki.iwt.2023-1263

https://www.iwt.cn/EN/Y2025/V45/I1/79

Figures/Tables 12

Table 1 Main components and mass fraction of manganese residue

项目	Al₂O₃	Fe₂O₃	SO₃	MnO	SiO₂	K₂O
质量分数/%	25.53	21.81	17.28	15.90	12.70	2.37

Fig.1 XRD（a）， magnetic hysteresis loop（b） and N₂ isothermal adsorption/desorption curve（c） of manganese residue

Fig.2 Degradation effect of RhB under different catalytic systems（a） and corresponding kinetic fitting curves（b）

Fig.3 Effect of manganese residue dosage on RhB degradation

Fig.4 Effect of PMS concentration on RhB degradation

Fig.5 Effect of initial solution pH on RhB degradation

Fig.6 Effect of reaction temperature on RhB degradation

Fig.7 Effect of initial solution concentration on RhB degradation

Fig.8 Cyclical performance of manganese residue to activate PMS for RhB degradation

Fig.9 UV-Vis absorption spectra of RhB during degradation process

Fig.10 FT-IR spectra of manganese residue before and after reaction

Fig.11 Effect of quenching agents on RhB degradation

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