Degradation of sulfonamide antibiotic wastewater by Co@α-MnO2 activated peroxymonosulfate

doi:10.19965/j.cnki.iwt.2022-0801

Abstract

Key words: sulfamethoxazole, MnO₂, peroxymonosulfate, reaction kinetics, active oxygen

CLC Number:

X703.1

Chao WANG, Hanwei CAI, Su XU, Wenchao LIAO, Han LIU, Fangfang CHENG. Degradation of sulfonamide antibiotic wastewater by Co@α-MnO₂ activated peroxymonosulfate[J]. Industrial Water Treatment, 2023, 43(7): 104-112.

王超, 蔡晗薇, 徐苏, 廖文超, 刘涵, 程芳芳. Co@α-MnO₂活化过硫酸盐降解磺胺类抗生素废水的研究[J]. 工业水处理, 2023, 43(7): 104-112.

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URL: https://www.iwt.cn/EN/10.19965/j.cnki.iwt.2022-0801

https://www.iwt.cn/EN/Y2023/V43/I7/104

Figures/Tables 13

Fig.1 Characterization of α-MnO₂ and Co@α-MnO₂

Table 1 Specific surface areas and pore sizes of α-MnO₂ and Co@α-MnO₂

样品	比表面积/（m² $∙$ g^-1）	孔径/nm
α-MnO₂	47.20	19.4~1 499.3
Co@α-MnO₂	45.21	12.9~345

Table 1 Specific surface areas and pore sizes of α-MnO₂ and Co@α-MnO₂

样品	比表面积/（m² $∙$ g^-1）	孔径/nm
α-MnO₂	47.20	19.4~1 499.3
Co@α-MnO₂	45.21	12.9~345

Fig. 2 Degradation effects of different degradation systems on SMX

Fig. 3 Effect of MnO₂ dosage on the degradation effect of SMX

Fig. 4 Effect of PMS dosage on the degradation effect of SMX

Fig. 5 Effect of initial SMX mass concentration on the degradation effect of SMX

Fig. 6 Effect of temperature on the degradation effect of SMX

Fig. 7 Effect of pH of solution on the degradation effect of SMX

Fig. 8 Effect of mass concentrations of HA on the degradation effect of SMX

Fig. 9 Effects of different quenchers on the degradation effect of SMX

Fig.10 Fitting curves of kinetic equations for SMX degradation by Co@α-MnO₂/PMS

Fig. 11 Leaching of Co and Mn in catalysts

Fig. 12 Effect of reaction time on TOC

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Degradation of sulfonamide antibiotic wastewater by Co@α-MnO₂ activated peroxymonosulfate

Co@α-MnO₂活化过硫酸盐降解磺胺类抗生素废水的研究

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