INDUSTRIAL WATER TREATMENT ›› 2016, Vol. 36 ›› Issue (2): 47-50. doi: 10.11894/1005-829x.2016.36(2).047

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Research on the synthesis of acrylic acid copolymer containing coumarin labeling group and its performance

Bai Xiaocheng, Zhang Guanghua, Wang Penglong   

  1. Key Laboratory of Additives Chemistry & Technology for Light Chemical Industry, Ministry of Education, Shanxi University of Science & Technology, Xi'an 710021, China
  • Received:2015-11-04 Online:2016-02-20 Published:2016-02-26

香豆素标记丙烯酸共聚物的合成及其性能研究

白晓成, 张光华, 王鹏龙   

  1. 陕西科技大学教育部轻化工助剂化学与技术重点实验室, 陕西西安 710021
  • 作者简介:白晓成(1991-),陕西科技大学硕士研究生。电话:15029045079,E-mail:yichenbai@163.com。
  • 基金资助:

    陕西省自然科学基金项目(2009JM2010)

Abstract:

A new kind of coumarin fluorescent monomer,N-(4-methyl-2-oxo-2H-chromen-7-yl)acrylamide (FM),has been synthesized by two steps,using 3-aminophenol and ethylene ethyl acetate as raw materials. A new type of fluorescent labeling copolymer FM-AA has been prepared from FM and acrylic acid(AA). The prepared FM-AA is characterized by IR and TG-DTA,and its scale inhibiting capacity studied. The results show that the synthesized FM-AA has better scale inhibiting effect. When its dosage is 20 mg/L,the scale inhibiting rate against CaCO3 can reach 81.3%.

Key words: coumarin, acrylic acid, fluorescent labeling copolymer, scale inhibitor

摘要:

以3-氨基酚和乙酰乙酸乙酯为原料,经过两步合成得到一种新型香豆素荧光单体--N-(4-甲基-2-氧代-2H-苯并吡喃-7-基)丙烯酰胺(FM);以FM与丙烯酸(AA)共聚制备了新型荧光示踪型共聚物FM-AA。通过红外光谱和热分析等方法对合成的FM-AA进行了表征,并对FM-AA的阻垢性能进行了研究。结果表明,合成的FM-AA对碳酸钙盐具有较好的阻垢效果,当其投加量为20 mg/L时,对碳酸钙的阻垢率可达81.3%。

关键词: 香豆素, 丙烯酸, 示踪型共聚物, 阻垢剂

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