Research progress on bismuth molybdate heterojunction of photocatalytic materials

doi:10.11894/iwt.2020-0242

Abstract

Abstract:

Human beings are facing with two major problems: energy shortage and environmental pollution. The development of photocatalysis technology plays a crucial role in solving these two problems. The core of photocatalytic technology is photocatalyst. Among most photocatalysts, bismuth molybdate has attracted much attention in recent years due to its unique layered structure and excellent visible light photocatalytic performance. This paper focus to summarize the construction methods and typical heterojunction systems of bismuth molybdate based heterojunction photocatalysis materials, and the catalytic activities and application fields of various bismuth molybdate based heterojunction materials are outlined systematically. Finally, the future development of bismuth molybdate based heterojunction photocatalytic materials is prospected.

Key words: bismuth molybdate, heterojunction, construction method, photocatalysis, research progress

摘要：

人类面临着能源短缺和环境污染两大难题，而光催化技术的发展对于这两大问题的解决具有重要意义。光催化技术的核心是光催化剂。在众多的光催化剂中，钼酸铋由于具有独特的钙钛片层状结构和优良的可见光催化性能，近年来引起了研究者的广泛关注。重点概述了钼酸铋基异质结光催化材料的构建方法和典型的钼酸铋基异质结体系，系统地归纳了各种钼酸铋基异质结型光催化材料的催化活性和应用领域，并对钼酸铋基异质结型光催化材料的发展方向进行了展望。

关键词: 钼酸铋, 异质结, 构建方法, 光催化, 研究进展

CLC Number:

X703

Changquan Jiao,Junhui Yi,Huimei Mo,Zhilin Li,Huibin Zhao. Research progress on bismuth molybdate heterojunction of photocatalytic materials[J]. Industrial Water Treatment, 2021, 41(2): 1-7, 14.

焦长泉,易均辉,莫惠媚,李芝霖,赵汇斌. 钼酸铋基异质结型光催化材料的研究进展[J]. 工业水处理, 2021, 41(2): 1-7, 14.

/ / Recommend / Download Citations

URL: https://www.iwt.cn/EN/10.11894/iwt.2020-0242

https://www.iwt.cn/EN/Y2021/V41/I2/1

Figures/Tables 4

References 39

1	Li Haibo , Zhao Fengyi , Zhang Jincheng , et al. A g-C₃N₄/WO₃ photoanode with exceptional ability for photoelectrochemical water splitting[J]. Materials Chemistry Frontiers, 2017, 1, 338- 342. doi: 10.1039/C6QM00009F
2	Wang Lu , Ghoussoub M , Wang Hong , et al. Photocatalytic hydrogenation of carbon dioxide with high selectivity to methanol at atmospheric pressure[J]. Joule, 2018, 2 (7): 1369- 1381. doi: 10.1016/j.joule.2018.03.007
3	Song Yanfang , Chen Wei , Zhao Chengcheng , et al. Metal-free nitrogen-doped mesoporous carbon for electroreduction of CO₂ to ethanol[J]. Angewandte Chemie International Edition, 2017, 56 (36): 10840- 10844. doi: 10.1002/anie.201706777
4	Zhang Shuai , Zhao Yunxuan , Shi Run , et al. Photocatalytic ammonia synthesis: Recent progress and future[J]. EnergyChem, 2019, 1 (2): 100013. doi: 10.1016/j.enchem.2019.100013
5	Fujishima A , Honda K . Electrochemical photolysis of water at a semiconductor electrode[J]. Nature, 1972, 238 (5358): 37- 38. doi: 10.1038/238037a0
6	Yan S C , Li Z S , Zou Z G . Photodegradation performance of g-C₃N₄ fabricated by directly heating melamine[J]. Langmuir, 2009, 25 (17): 10397- 10401. doi: 10.1021/la900923z
7	莫惠媚, 周开欣, 刘伟涛, 等. 不同前驱体对g-C₃N₄微观结构及光催化性能的影响[J]. 广东石油化工学院学报, 2019, 29 (1): 23- 27. URL
8	Yi Junhui , Song Jiaxing , Mo Huimei , et al. One step pyridine-assisted synthesis of visible-light-driven photocatalyst Ag/AgVO₃[J]. Advanced Powder Technology, 2018, 29 (2): 319- 324. doi: 10.1016/j.apt.2017.11.018
9	Yu Changlin , Li Gao , Kumar S , et al. Phase transformation synthesis of novel Ag₂O/Ag₂CO₃ heterostructures with high visible light efficiency in photocatalytic degradation of pollutants[J]. Advanced Materials, 2014, 26 (6): 892- 898. doi: 10.1002/adma.201304173 URL
10	Huang Yongchao , Fan Wenjie , Long Bei , et al. Visible light Bi₂S₃/Bi₂O₃/Bi₂O₂CO₃ photocatalyst for effective degradation of organic pollutions[J]. Applied Catalysis B: Environmental, 2016, 185, 68- 76. doi: 10.1016/j.apcatb.2015.11.043
11	Yi Junhui , Jiao Changquan , Mo Huimei , et al. In situ synthesis of Bi₂O₃/Bi₂MoO₆ heterostructured microspheres for efficiently removal of acid orange 7[J]. Ceramics International, 2018, 44 (18): 22102- 22107. doi: 10.1016/j.ceramint.2018.08.320
12	Yu Jianqiang , Akihiko K . Hydrothermal synthesis and photocatalytic property of 2-dimensional bismuth molybdate nanoplates[J]. Chemistry Letters, 2005, 34 (11): 1528- 1529. doi: 10.1246/cl.2005.1528
13	Long Jinlin , Wang Shuchao , Chang Hongjin , et al. Bi₂MoO₆ nanobelts for crystal facet-enhanced photocatalysis[J]. Small, 2014, 10 (14): 2791- 2795. doi: 10.1002/smll.201302950 URL
14	Alemi A A , Kashfi R , Shabani B . Preparation and characterization of novel Ln(Gd³⁺, Ho³⁺ and Yb³⁺)-doped Bi₂MoO₆ with Aurivillius layered structures and photocatalytic activities under visible light irradiation[J]. Journal of Molecular Catalysis A: Chemical, 2014, 392, 290- 298. doi: 10.1016/j.molcata.2014.05.029 URL
15	Du Hong , Liu Yanan , Shen Congcong , et al. Nanoheterostructured photocatalysts for improving photocatalytic hydrogen production[J]. Chinese Journal of Catalysis, 2017, 38, 1295- 1306. doi: 10.1016/S1872-2067(17)62866-3
16	韩成, 雷永鹏, 王应德, 等. 纳米异质结光催化材料制取太阳能燃料研究进展[J]. 无机材料学报, 2015, 30 (11): 1121- 1128. URL
17	Liu Tongxuan , Li Benxia , Hao Yonggan , et al. MoO₃-nanowire membrane and Bi₂Mo₃O₁₂/MoO₃ nano-heterostructural photocatalyst for wastewater treatment[J]. Chemical Engineering Journal, 2014, 244, 382- 390. doi: 10.1016/j.cej.2014.01.070 URL
18	Zhang Junlei , Liu Huan , Ma Zhen . Flower-like Ag₂O/Bi₂MoO₆ p-n heterojunction with enhanced photocatalytic activity under visible light irradiation[J]. Journal of Molecular Catalysis A: Chemical, 2016, 424, 37- 44. doi: 10.1016/j.molcata.2016.08.009
19	Zhang Li , Teng Hongcheng , Zhou Jiancheng , et al. Synthesis of AgI/Bi₂MoO₆ nano-heterostructure with enhanced visible-light photocatalytic property[J]. Progress in Natural Science: Materials International, 2018, 28 (2): 235- 241. doi: 10.1016/j.pnsc.2018.02.008
20	Zhang Guping , Chen Dongyun , Li Najun , et al. Fabrication of Bi₂MoO₆/ZnO hierarchical heterostructures with enhanced visible-light photocatalytic activity[J]. Applied Catalysis B: Environmental, 2019, 250, 313- 324. doi: 10.1016/j.apcatb.2019.03.055
21	张俊磊, 张丽莎, 鞠小逖, 等. Bi₂MoO₆-Pt异质结的制备及其光催化性能研究[J]. 环境科学学报, 2016, 36 (6): 2050- 2058. URL
22	Yi Junhui , Mo Huimei , Zhang Bangliang , et al. CeO₂/Bi₂MoO₆ heterostructured microspheres with synergistic effect for accelerating photogenerated charge separation[J]. Separation and Purification Technology, 2019, 211, 474- 480. doi: 10.1016/j.seppur.2018.10.022
23	Jonjana S , Phuruangrat A , Thongtem S , et al. Preparation and enhanced photocatalytic performance of AgCl/Bi₂MoO₆ heterojunction[J]. Materials Letters, 2016, 179, 162- 165. doi: 10.1016/j.matlet.2016.05.080
24	Jonjana S , Phuruangrat A , Thongtem T , et al. Synthesis, analysis and photocatalysis of AgBr/Bi₂MoO₆ nanocomposites[J]. Materials Letters, 2016, 172, 11- 14. doi: 10.1016/j.matlet.2016.02.125
25	Jonjana S , Phuruangrat A , Thongtem S , et al. Synthesis of AgI/Bi₂MoO₆ heterojunctions and their photoactivity enhancement driven by visible light[J]. Materials Letters, 2016, 175, 75- 78. doi: 10.1016/j.matlet.2016.03.125
26	Liang Jialiang , Liu Fuyang , Deng Jun , et al. Efficient bacterial inactivation with Z-scheme AgI/Bi₂MoO₆ under visible light irradiation[J]. Water Research, 2017, 123, 632- 641. doi: 10.1016/j.watres.2017.06.060
27	Yue Du , Chen Daimei , Wang Zhihong , et al. Enhancement of visible photocatalytic performances of a Bi₂MoO₆-BiOCl nanocomposite with plate-on-plate heterojunction structure[J]. Physical Chemistry Chemical Physics, 2014, 16 (47): 26314- 26321. doi: 10.1039/C4CP03865G URL
28	Wang Shengyao , Yang Xianglong , Zhang Xuehao , et al. A plate-onplate sandwiched Z-scheme heterojunction photocatalyst: BiOBr-Bi₂MoO₆ with enhanced photocatalytic performance[J]. Applied Surface Science, 2017, 391, 194- 201. doi: 10.1016/j.apsusc.2016.07.070
29	Yan Tao , Sun Meng , Liu Hongye , et al. Fabrication of hierarchical BiOI/Bi₂MoO₆ heterojunction for degradation of bisphenol A and dye under visible light irradiation[J]. Journal of Alloys and Compounds, 2015, 634, 223- 231. doi: 10.1016/j.jallcom.2015.02.064
30	Du Xiao , Wan Jun , Jia Jia , et al. Photocatalystic degradation of RhB over highly visible-light-active Ag₃PO₄-Bi₂MoO₆ heterojunction using H₂O₂ electron capturer[J]. Materials & Design, 2017, 119, 113- 123. URL
31	Zhang Junlei , Ma Zhen . Flower-like Ag₂MoO₄/Bi₂MoO₆ heterojunctions with enhanced photocatalytic activity under visible light irradiation[J]. Journal of the Taiwan Institute of Chemical Engineers, 2017, 71, 156- 164. doi: 10.1016/j.jtice.2016.11.030
32	Feng Yi , Yan Xu , Liu Chunbo , et al. Hydrothermal synthesis of CdS/Bi₂MoO₆ heterojunction photocatalysts with excellent visible-lightdriven photocatalytic performance[J]. Applied Surface Science, 2015, 353, 87- 94. doi: 10.1016/j.apsusc.2015.06.061
33	Shi Huanxian , Fan Jun , Zhao Yanyan , et al. Visible light driven CuBi₂O₄/Bi₂MoO₆ p-n heterojunction with enhanced photocatalytic inactivation of E. coli and mechanism insight[J]. Journal of Hazardous Materials, 2020, 381, 121006. doi: 10.1016/j.jhazmat.2019.121006
34	Jia Jia , Du Xiao , Zhang Qiqi , et al. Z-scheme MgFe₂O₄/Bi₂MoO₆ heterojunction photocatalyst with enhanced visible light photocatalytic activity for malachite green removal[J]. Applied Surface Science, 2019, 492, 527- 539. doi: 10.1016/j.apsusc.2019.06.258
35	Wang Yin , Niu Chenggang , Zhang Lei , et al. High-efficiency visible-light AgI/Ag/Bi₂MoO₆ as a Z-scheme photocatalyst for environmental applications[J]. RSC Advances, 2016, 6 (13): 10221- 10228. doi: 10.1039/C5RA23736J
36	Tian Guohui , Chen Yajie , Meng Xiangying , et al. Hierarchical composite of Ag/AgBr nanoparticles supported on Bi₂MoO₆ hollow spheres for enhanced visible-light photocatalytic performance[J]. ChemPlusChem, 2013, 78 (1): 117- 123. doi: 10.1002/cplu.201200198
37	Yan Qing , Sun Meng , Yan Tao , et al. Fabrication of a heterostructured Ag/AgCl/Bi₂MoO₆ plasmonic photocatalyst with efficient visible light activity towards dyes[J]. RSC Advances, 2015, 5 (22): 17245- 17252. doi: 10.1039/C4RA15821K
38	Li Haiping , Liu Jingyi , Hou Wanguo , et al. Synthesis and characterization of g-C₃N₄/Bi₂MoO₆ heterojunctions with enhanced visible light photocatalytic activity[J]. Applied Catalysis B: Environmental, 2014, 160/161, 89- 97. doi: 10.1016/j.apcatb.2014.05.019
39	Li Ning , Gao Hang , Wang Xin , et al. Novel indirect Z-scheme g-C₃N₄/Bi₂MoO₆/Bi hollow microsphere heterojunctions with SPR-promoted visible absorption and highly enhanced photocatalytic performance[J]. Chinese Journal of Catalysis, 2020, 41 (3): 426- 434. doi: 10.1016/S1872-2067(19)63478-9

复合材料及其异质结类型	构建方法	形貌	应用领域	光催化活性	参考文献
AgCl/Bi₂MoO₆ （Ⅰ型异质结）	溶剂热沉淀法	薄片状	降解1.0×10^-5 mol/L 罗丹明B（RhB）	无异质结（纯相单一钼酸铋，下同）：降解率40.5%（100 min）有异质结：降解率92%（60 min）	〔23〕
AgCl/Ag/Bi₂MoO₆ （Z型异质结）	溶剂热光还原法	花状微球	降解2.0×10^-5 mol/L 罗丹明B（RhB）	无异质结：降解率 < 20%（45 min）有异质结：降解率100%（45 min）	〔37〕
AgBr/Bi₂MoO₆ （Ⅰ型异质结）	溶剂热沉淀法	薄片状	降解1.0×10^-5 mol/L 罗丹明B（RhB）	无异质结：降解率18%（40 min）有异质结：降解率97%（40 min）	〔24〕
AgBr/Ag/Bi₂MoO₆ （Z型异质结）	溶剂热光还原法	空心微球	降解20 mg/L 茜素红S（ARS）	无异质结：降解率30%（60 min）有异质结：降解率89%（60 min）	〔36〕
AgI/Bi₂MoO₆ （Ⅰ型异质结）	溶剂热沉淀法	薄片状	降解1.0×10^-5 mol/L 罗丹明B（RhB）	无异质结：降解率17.21%（40 min）有异质结：降解率92.89%（40 min）	〔25〕
AgI/Ag/Bi₂MoO₆ （Z型异质结）	溶剂热光还原法	片块状	降解20 mg/L 罗丹明B（RhB）	无异质结：降解率2.5%（15 min）有异质结：降解率93.6%（15 min）	〔35〕
g-C3N4/Bi₂MoO₆ （Ⅰ型异质结）	溶剂热法	团聚块状	降解10 mg/L 罗丹明B（RhB）	无异质结：降解率 < 60%（70 min）有异质结：降解率98%（70 min）	〔38〕
g-C3N4/Bi₂MoO₆/Bi （Z型异质结）	溶剂热原位法	空心微球	降解罗丹明B（RhB）	无异质结：降解率 < 10%（60 min）有异质结：降解率90%（60 min）	〔39〕

复合材料及其异质结类型	构建方法	形貌	应用领域	光催化活性	参考文献
AgCl/Bi₂MoO₆ （Ⅰ型异质结）	溶剂热沉淀法	薄片状	降解1.0×10^-5 mol/L 罗丹明B（RhB）	无异质结（纯相单一钼酸铋，下同）：降解率40.5%（100 min）有异质结：降解率92%（60 min）	〔23〕
AgCl/Ag/Bi₂MoO₆ （Z型异质结）	溶剂热光还原法	花状微球	降解2.0×10^-5 mol/L 罗丹明B（RhB）	无异质结：降解率 < 20%（45 min）有异质结：降解率100%（45 min）	〔37〕
AgBr/Bi₂MoO₆ （Ⅰ型异质结）	溶剂热沉淀法	薄片状	降解1.0×10^-5 mol/L 罗丹明B（RhB）	无异质结：降解率18%（40 min）有异质结：降解率97%（40 min）	〔24〕
AgBr/Ag/Bi₂MoO₆ （Z型异质结）	溶剂热光还原法	空心微球	降解20 mg/L 茜素红S（ARS）	无异质结：降解率30%（60 min）有异质结：降解率89%（60 min）	〔36〕
AgI/Bi₂MoO₆ （Ⅰ型异质结）	溶剂热沉淀法	薄片状	降解1.0×10^-5 mol/L 罗丹明B（RhB）	无异质结：降解率17.21%（40 min）有异质结：降解率92.89%（40 min）	〔25〕
AgI/Ag/Bi₂MoO₆ （Z型异质结）	溶剂热光还原法	片块状	降解20 mg/L 罗丹明B（RhB）	无异质结：降解率2.5%（15 min）有异质结：降解率93.6%（15 min）	〔35〕
g-C3N4/Bi₂MoO₆ （Ⅰ型异质结）	溶剂热法	团聚块状	降解10 mg/L 罗丹明B（RhB）	无异质结：降解率 < 60%（70 min）有异质结：降解率98%（70 min）	〔38〕
g-C3N4/Bi₂MoO₆/Bi （Z型异质结）	溶剂热原位法	空心微球	降解罗丹明B（RhB）	无异质结：降解率 < 10%（60 min）有异质结：降解率90%（60 min）	〔39〕

[1]	Yabin JIN, Tiantian XU, Dezhong ZHAO, Le ZHANG, Zhenjie WAN, Gaoming ZHANG. Advances in the synthesis of Bi₂O₃-based composite photocatalysts and the applications in water treatment [J]. Industrial Water Treatment, 2025, 45(3): 10-21.
[2]	Wei DONG, Li LIN, Huaizhang GU, Yunqiang LUO, Ping MA, Xiangyang LI. Photocatalytic properties of dual Z-scheme Bi₂MoO₆/Bi₂WO₆/Ag₃PO₄ heterojunction [J]. Industrial Water Treatment, 2024, 44(8): 81-89.
[3]	Bin TAN, Huiru HAO, Yutong XIANG, Yuning LIU, Qian ZHANG. Degradation of Enrofloxacin by photocatalytic system based on BC-BiOI/PMS [J]. Industrial Water Treatment, 2024, 44(6): 143-150.
[4]	Hongsen HUANG, Xinyu ZHENG, Zhenfeng LIN, Yongfu GUO. Photocatalytic properties of Z-scheme heterojunction BiO_2- _x /ZnWO₄ on antibiotics in water [J]. Industrial Water Treatment, 2024, 44(4): 138-146.
[5]	Jun WANG, Shuang FU, Peng HOU, Jun LIU, Chunxue SUN, Hongguang ZHANG. Construction of S-type TiO₂/CoPc heterojunction and photocatalytic degradation of tetracycline [J]. Industrial Water Treatment, 2024, 44(12): 118-122.
[6]	Youzhi YAO, Fei HUA, Kang WU, Zhou YE, Zhongliang ZHANG, Cheng QIAN. Research progress on photocatalytic degradation of organic pollutants in wastewater by graphene-based composites [J]. Industrial Water Treatment, 2024, 44(11): 1-8.
[7]	Guoyu LIU, Xiangyu CAO, Jianhua ZHENG. Research progress on cobalt-based oxide photocatalysts for degradation of organic pollutants [J]. Industrial Water Treatment, 2024, 44(11): 27-34.
[8]	Guohui WANG, Jiaguo YAN, Yanli Li, Xin WANG, Mei CHEN. Research progress of fouling mitigation in photocatalysis coupled membrane filtration systems [J]. Industrial Water Treatment, 2024, 44(10): 82-91.
[9]	Chuanxi YANG, Xiaoguang LIU, Chang GAO, Xiaoning WANG, Yonglin LIU, Wenping DONG, Lin LIU, Haofen SUN, Changqing LIU, Weiliang WANG. Research progress of novel two-dimensional layered nanomaterials MXene-based photocatalyst in water treatment [J]. Industrial Water Treatment, 2024, 44(1): 22-31.
[10]	Zhen WANG, Xiaohuan ZHENG, Yi YUAN, Kai ZHU, Yang WEI, Li XU, Gaoping XU. Progress of photocatalysis for the removal of natural organic matter from water [J]. Industrial Water Treatment, 2023, 43(9): 43-50.
[11]	Yun YANG, Yuanyuan ZHOU, Hao HU, Shuijin YANG. Preparation and photocatalytic properties of MOF-808/MIL-101（Fe） [J]. Industrial Water Treatment, 2023, 43(8): 97-103.
[12]	Wei CHEN, Wenli HU, Yumin CUI. Preparation and performance for ZrO₂-CNB composite photocatalysts [J]. Industrial Water Treatment, 2023, 43(7): 113-119.
[13]	Lihua LIU, Shan ZHONG, Lishan ZHANG, Baojiang LIU. Preparation of Ti-doped BiOCl nanosheets and its piezoelectric photocatalytic performance [J]. Industrial Water Treatment, 2023, 43(5): 101-106.
[14]	Ruilin PANG, Chuangrong MO, Xuetang XU, Jie PAN. Degradation of orange Ⅱ by Bi₂WO₆ photocatalyisis combined with peroxymonosulfate [J]. Industrial Water Treatment, 2023, 43(4): 71-77.
[15]	Longli LIN, Guoguang LIU, Lihua SHI, Simei LIU, Jingyong LIU. Study on photocatalytic degradation of naproxen in water by improved TiO₂ [J]. Industrial Water Treatment, 2023, 43(4): 85-91.

Please choose a citation manager

Content to export